Electrochemical detection of explosives in air

• US 20060193750A1
• Filed: 02/28/2005
• Published: 08/31/2006
• Est. Priority Date: 02/28/2005
• Status: Abandoned Application

• Current Assignee: Medis El Ltd. (Medis Technologies Ltd.)
• Original Assignee: Medis El Ltd. (Medis Technologies Ltd.)
• Inventors: Sakin, Alexander, Hiterer, Jacob, Filanovsky, Boris
• Application Number:
  US11/066,213
• Publication Number:
  US 20060193750A1
• Time in Patent Office: Days
• US Class Current: 422/94
• CPC Class Codes: G01N 27/4045 for gases other than oxygen
• CPC Class Codes: G01N 33/0057 for warfare agents or explosives properties of explosives G01N33/227

Abstract

A portable device for detecting an explosive substance present in air, the device including: (a) a mechanism for drawing an air sample into the device; (b) a solid trapping material having a surface for trapping explosive particles in the air sample; (c) a collector for containing a solvent, the collector associated with the surface, the solvent for producing dissolved explosive material by: (i) removing and dissolving the portion of particles from the surface, and (ii) directly dissolving a remainder of the particles of the explosive material, (d) an electrode unit, associated with the collector, for producing a signal corresponding to a presence of the dissolved explosive material, and (e) circuitry for determining the presence of the dissolved explosive material based on the signal produced by the electrode unit.

Claims

1. A portable device for detecting at least one explosive substance present in air, the device comprising:

(a) a mechanism for drawing an air sample into the device;

(b) a solid trapping material having a surface for trapping a portion of particles of an explosive material in said air sample;

(c) a collector for containing a solvent, said collector associated with said surface, said solvent for producing dissolved explosive material by;

(i) removing and dissolving said portion of particles from said surface, and

(ii) directly dissolving a remainder of said particles of said explosive material,

(d) an electrode unit, associated with said collector, for producing a signal corresponding to a presence of said dissolved explosive material, and

(e) circuitry for determining said presence of said dissolved explosive material based on said signal produced by said electrode unit.

2. The device of claim 1, wherein said trapping material is a reversibly trapping material.

3. The device of claim 2, wherein said trapping material includes a material selected from the group of materials consisting of polytetrafluoroethylene, cross-linked polyethylene, and polypropylene.

4. The device of claim 1, wherein said trap is associated with said collector by direct fluid communication.

5. The device of claim 1, further comprising an electrochemical mechanism, designed and configured to be in fluid communication with said collector, upon demand, for electrochemically regenerating said solvent.

6. The device of claim 5, further comprising a control device for enabling fluid communication between said electrochemical mechanism and said collector, upon demand.

7. The device of claim 2, wherein said surface of said solid trapping material has a reversibility factor (R), characterized by:

$\mathrm{Reversibility}<br><br>\text{\hspace{1em}<br><br>}<br><br>\mathrm{Factor}<br><br>\text{\hspace{1em}<br><br>}<br><br>\left(R\right)=\frac{\mathrm{Weight}<br><br>\text{\hspace{1em}<br><br>}<br><br>\mathrm{of}<br><br>\text{\hspace{1em}<br><br>}<br><br>\mathrm{explosive}<br><br>\text{\hspace{1em}<br><br>}<br><br>\mathrm{material}<br><br>\text{\hspace{1em}<br><br>}<br><br>\mathrm{removed}}{\left(\mathrm{Volume}<br><br>\text{\hspace{1em}<br><br>}<br><br>\mathrm{of}<br><br>\text{\hspace{1em}<br><br>}<br><br>\mathrm{Solvent}\right)\times <br><br>\left(\mathrm{Time}\right)}$

wherein said explosive material is trinitrotoluene, said solvent is ethylene glycol, said weight is measured in micrograms, said volume is measured in milliliters, and said time is measured in seconds,

and wherein R is at least 0.03.

8. The device of claim 7, wherein R is at least 0.05.

9. The device of claim 7, wherein R is at least 0.10.

10. The device of claim 1, wherein said solvent includes a solvent selected from the group of solvents consisting of ethylene glycol, propylene glycol, diethylene glycol dimethyl ether, triethylene glycol dimethyl ether, alcohols having a carbon chain length of 2 to 3, and mixtures thereof.

11. The device of claim 1, wherein said electrode unit includes an electrode material modified by treatment thereof with at least one chemical modifier that increases electron transfer kinetics of nitro-aromatic compounds.

12. The device of claim 11, wherein said at least one chemical modifier includes an aromatic organic compound.

13. The device of claim 11, wherein said at least one chemical modifier includes a compound selected from the group of compounds consisting of amine, sulfanilamide, amino-naphthalene and aromatic derivatives thereof, and a para-aminobenzenesulfonylamine having the structure NH₂—

C₆H₄—

SO₂—

NR′

R″

, wherein said amine has R′ and

R″

moieties selected from the group of radicals consisting of H, X, CH₃, CH₂X, and CHX₂, where H is hydrogen and X is a halogen or a halogen-containing moiety.

14. The device of claim 11, wherein said at least one chemical modifier includes a compound selected from the group of compounds consisting of amino-aromatic compounds, alkyl-aniline compounds, halide derivatives of alkyl aniline compounds and hydroxyl-aniline compounds.

15. The device of claim 11, wherein said at least one chemical modifier includes a compound selected from the group of compounds consisting of phenylene-diamine, diphenylene-diamine, and diphenylene-triamine.

16. The device of claim 11, wherein said at least one chemical modifier includes aniline.

17. The device of claim 1, wherein said electrode unit includes an electrode material selected from the group consisting of carbon and gold.

18. The device of claim 1, wherein said electrode unit includes an electrode material modified by treatment thereof with at least one chemical modifier, so as to produce, in a presence of said explosive material in said solvent, a current peak, said peak occurring within a potential range of 0.0 to minus 1.1 Volts.

19. The device of claim 18, wherein said current peak occurs within a potential range of minus 0.4 to minus 0.65 Volts.

20. The device of claim 18, wherein said current peak occurs within a potential range of minus 0.48 to minus 0.60 Volts.

21. The device of claim 1, wherein said circuitry includes a direct current pulse generator for registering at least 2 potential steps, wherein a duration of each of said potential steps is in a range of 0.1 to 2.5 seconds.

22. The device of claim 21, wherein said potential steps are in a cathode range that occurs minus 200 to minus 250 millivolts after a peak potential.

23. A portable device for detecting at least one explosive substance present in air, the device comprising:

(a) a mechanism for drawing an air sample into the device;

(b) a solid trapping material having a surface for trapping a portion of particles of an explosive material in said air sample;

(c) a collector for containing a solvent, said collector associated with said surface, said solvent for producing dissolved explosive material by removal of said portion of particles from said surface;

(d) a contacting mechanism for contacting said solvent with said surface so as to effect said removal;

(d) an electrode unit, associated with said collector, for producing a signal corresponding to a presence of said dissolved explosive material, and

(e) circuitry for determining said presence of said dissolved explosive material based on said signal produced by said electrode unit.

24. The device of claim 23, wherein said trapping material is a reversibly trapping material.

25. A method for detecting at least one explosive substance in air, the method comprising the steps of:

(a) providing a device including;

(i) a mechanism for drawing an air sample into the device;

(ii) a solid trapping material having a surface for trapping particles of an explosive material in said air sample;

(iii) a solvent for removing said particles from said surface and for dissolving said particles;

(iv) a collector for receiving said solvent, said collector associated with said surface, and

(v) an electrode unit, associated with said collector, for producing a signal corresponding to a presence of a dissolved explosive material;

(b) drawing an air sample into said device using said mechanism, so as to trap said particles on said surface;

(c) removing said particles from said surface into said solvent;

(d) dissolving said particles in said solvent to produce said dissolved explosive material, and

(e) producing said signal corresponding to said presence of said dissolved explosive material.

26. The method of claim 25, wherein said solid trapping material is a reversibly-trapping material.

27. The method of claim 26, the method further comprising:

(f) determining, automatically, said presence of said dissolved explosive material based on said signal produced by said electrode unit.

28. The method of claim 25, wherein said removing of said particles from said surface into said solvent is performed by automatically circulating said solvent, upon demand, so as to fluidly contact said surface.

29. The method of claim 25, the method further comprising:

(f) regenerating said solvent within said device.

30. The method of claim 29, wherein said regenerating is performed using regeneration electrodes.