Combined heat and power system

• US 20060199051A1
• Filed: 03/07/2005
• Published: 09/07/2006
• Est. Priority Date: 03/07/2005
• Status: Abandoned Application

• Current Assignee: Hyteon Inc.
• Original Assignee: Hyteon Inc.
• Inventors: Bai, Dingrong, Chouinard, Jean-Guy, Elkaim, David
• Application Number:
  US11/072,646
• Publication Number:
  US 20060199051A1
• Time in Patent Office: Days
• US Class Current: 429/425
• CPC Class Codes: H01M 2008/1095 Fuel cells with polymeric electrolytes
• CPC Class Codes: H01M 2250/405 Cogeneration of heat or hot water
• CPC Class Codes: H01M 8/04007 related to heat exchange
• CPC Class Codes: H01M 8/04014 Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
• CPC Class Codes: H01M 8/04022 Heating by combustion
• CPC Class Codes: H01M 8/04037 Electrical heating
• CPC Class Codes: H01M 8/04074 Heat exchange unit structures specially adapted for fuel cell
• CPC Class Codes: H01M 8/04268 Heating of fuel cells during the start-up of the fuel cells
• CPC Class Codes: H01M 8/04328 of anode reactants at the inlet or inside the fuel cell
• CPC Class Codes: H01M 8/04335 of cathode reactants at the inlet or inside the fuel cell
• CPC Class Codes: H01M 8/04395 of cathode reactants at the inlet or inside the fuel cell
• CPC Class Codes: H01M 8/04425 at auxiliary devices, e.g. reformers, compressors, burners
• CPC Class Codes: H01M 8/04708 of fuel cell reactants
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: H01M 8/0618 Reforming processes, e.g. autothermal, partial oxidation or steam reforming
• CPC Class Codes: H01M 8/0662 Treatment of gaseous reactants or gaseous residues, e.g. cleaning
• CPC Class Codes: H01M 8/0668 Removal of carbon monoxide or carbon dioxide
• CPC Class Codes: H01M 8/0675 Removal of sulfur
• CPC Class Codes: Y02B 90/10 Applications of fuel cells in buildings
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 90/40 : Fuel cell technologies in production processes

Abstract

There is described a combined heat and power, or cogeneration, system combining a fuel cell for generating electrical power with a thermal power source, the system comprising: a fuel processor for converting a hydrocarbon fuel into hydrogen in an output stream, the hydrogen rich output stream containing a low content of carbon monoxide; a high temperature hydrogen fuel cell system tolerant to low content of carbon monoxide of up to 5% receiving the output stream and an oxidant fluid stream; and a heat exchange system having a first module associated with the fuel processor and a second module associated with the fuel cell system connected at least in part in series to provide a thermal output.

Claims

1. A method of initiating operation of a fuel cell system having a fuel processor for generating hydrogen from a hydrocarbon fuel, and a high temperature hydrogen fuel cell, the method comprising:

preheating the fuel processor to perform without risk of catalyst damage and deactivation due to reasons including water condensation and CO poisoning using electric heaters and a gas burner;

preheating a fuel cell stack of said fuel cell to a first preferred temperature by electric heaters, above which water in reformate will not be condensed over high temperature membrane electrode assemblies (MEA) of said fuel cell stack to cause acid washout;

operating said fuel processor to begin hydrogen generation while feeding hydrogen back into said gas burner as required;

feeding hydrogen gas from said fuel processor at a second preferred temperature to preheat said fuel cell stack while drawing no substantial current from said fuel cell stack by operating said fuel processor under self-sustainable conditions, said second temperature being a temperature above which current can be safely drawn without damaging said high temperature MEA;

preheating said fuel cell stack to its operation temperature by stack self-preheating; and

subjecting said fuel cell to normal operation after reaching said operation temperature.

2. The method as claimed in claim 1, wherein said fuel cell system is a combined heat and power (CHP) or cogeneration system and further comprises a heat recovery system to provide thermal output from one or both of the fuel processor and the fuel cell system, the method further comprising providing said thermal output.

3. The method as claimed in claim 1, wherein said first preferred temperature is above 55°

C.

4. The method as claimed in claim 1, wherein said second preferred temperature is above 120°

C.

5. The method as claimed in claim 1, wherein said operation temperature is between 160 and 200°

C.

6. The method as claimed in claim 1, wherein said hydrogen gas fed through said fuel cell during preheat to said second preferred temperature is returned to said burner for combustion.

7. The method as claimed in claim 1, wherein:

said burner normally consumes a variable mixture of hydrocarbon fuel fed to said fuel processor and available hydrogen gas produced by said fuel processor and unconsumed by said fuel cell stack to meet the heating needs of said fuel processor;

during initial operation, the hydrocarbon fuel is directed to said burner entirely until said fuel cell stack reaches a third temperature above said first temperature;

when said third temperature is reached, hydrogen gas produced from said fuel processor is fed to said fuel cell stack up to a maximum desired flow rate for preheating said fuel cell stack to said first temperature with essentially all of said hydrogen gas being unconsumed by said fuel cell stack being fed to said burner;

during normal operation, hydrogen gas is controlled to be fed entirely to said fuel cell stack with any hydrogen gas unconsumed by said fuel cell stack being fed to said burner.

8. The method as claimed in claim 1, wherein said feeding hydrogen gas from said fuel processor at a second preferred temperature to preheat said fuel cell stack comprises said fuel processor operating at between 15% and 35% of normal capacity.

9. The method as claimed in claim 1, wherein cogeneration of heat from said fuel cell system only begins after said preheating of said fuel cell stack to its operation temperature.

10. The method as claimed in claim 1, wherein quick steam generation is accomplished by supplying two heating sources.

11. The method as claimed in claim 1, further comprising operating the gas burner in the fuel processor to accelerate fuel processor warm up and steam generation.

12. The method as claimed in claim 1, wherein incoming cathode air is preheated to close to stack temperature

13. The method as claimed in claim 12, wherein said incoming cathode air is preheated by cathode exhaust.

14. The method as claimed in claim 12, wherein said incoming cathode air is preheated by coolant in a heat exchanger.

15. The method as claimed in claim 12, wherein said incoming cathode air is preheated in-cell by coolant and transported by a transportation manifold in said fuel cell stack.

16. The method as claimed in claim 12, wherein said incoming cathode air is preheated by anode residual gas.

17. The method as claimed in claim 1, wherein said fuel processor and fuel cell are mechanically integrated by providing components of high temperature centrally and components of low temperature on a periphery of a package.

18. A combined heat and power, or cogeneration, system combining a fuel cell for generating electrical power with a thermal power source, the system comprising:

a fuel processor for converting a hydrocarbon fuel into hydrogen in an output stream, the hydrogen rich output stream containing a low content of carbon monoxide;

a high temperature hydrogen fuel cell system tolerant to carbon monoxide of up to 5% receiving said output stream and an oxidant fluid stream; and

a heat exchange system having a first module associated with said fuel processor and a second module associated with said fuel cell system connected at least in part in series to provide a thermal output.

19. The combined system as claimed in claim 18, wherein:

at least one of said fuel processor and said fuel cell system comprise a dual purpose electric heater for warming up a component of the combined system;

said heat exchange system comprises a heat exchanger able to extract heat from said component and adapted to receive heat from said dual purpose electric heater;

the combined system further comprising;

a control circuit for directing surplus electrical power from said fuel cell system to said dual purpose electric heater to convert said surplus electrical power into additional thermal output of said heat exchange system.

20. The combined system as claimed in claim 19, wherein said heat exchange system provides hot water.

21. The combined system as claimed in claim 18, wherein said fuel cell system comprises a fuel cell stack having a plurality of plates compressed together and having inlet and outlet manifolds for distributing incoming and outgoing fluids and air into said stack.

22. The combined system as claimed in claim 21, wherein said fuel cell stack comprises at least one anode plate having an active zone for a fuel to be distributed to a membrane electrode assembly and a preheating zone for preheating cathode air, said active zone and said preheating zone being separate from each other.

23. The combined system as claimed in claim 21, wherein said fuel cell stack comprises at least one anode plate having an active zone for a fuel to be distributed to a membrane electrode assembly and a preheating zone for preheating cathode air, said active zone and said preheating zone in fluid communication with each other.