Carbon dioxide gas absorbent and method of manufacturing the same

• US 20060211570A1
• Filed: 03/16/2006
• Published: 09/21/2006
• Est. Priority Date: 03/18/2005
• Status: Active Grant

• Current Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Original Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Inventors: Kato, Masahiro, Essaki, Kenji, Imada, Toshihiro
• Granted Patent: US 7,538,068 B2
• Time in Patent Office: Days
• US Class Current: 502/400
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2253/112 Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
• CPC Class Codes: B01D 2253/308 Pore size
• CPC Class Codes: B01D 2253/311 Porosity, e.g. pore volume
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01J 20/041 Oxides or hydroxides
• CPC Class Codes: B01J 20/043 Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
• CPC Class Codes: B01J 20/10 comprising silica or silicate
• CPC Class Codes: B01J 20/28004 Sorbent size or size distribution, e.g. particle size
• CPC Class Codes: B01J 20/28078 Pore diameter
• CPC Class Codes: B01J 20/28085 being more than 50 nm, i.e. macropores
• CPC Class Codes: B01J 20/28092 Bimodal, polymodal, different types of pores or different pore size distributions in different parts of the sorbent
• CPC Class Codes: B01J 20/3007 Moulding, shaping or extruding
• CPC Class Codes: B01J 20/3078 Thermal treatment, e.g. calcining or pyrolizing
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A carbon dioxide gas absorbent includes a porous body containing a lithium complex oxide. The porous body includes pores having a pore diameter distribution such that main pores which consist of first pores with a diameter of 10 to 100 μm and second pores with a diameter larger than 100 μm and 500 μm or smaller occupy 80 to 100%, third pores with a diameter smaller than 10 μm occupy 0 to 10% and fourth pores with a diameter larger than 500 μm occupy 0 to 10%, the main pores have a pore diameter distribution such that the first pores occupy 15 to 85% and second pores occupy 15 to 85%.

Claims

1. A carbon dioxide gas absorbent comprising a porous body containing a lithium complex oxide, wherein the porous body includes pores having a pore diameter distribution such that main pores which consist of first pores with a diameter of 10 to 100 μ

m and second pores with a diameter larger than 100 μ

m and 500 μ

m or smaller occupy 80 to 100%, third pores with a diameter smaller than 10 μ

m occupy 0 to 10% and fourth pores with a diameter larger than 500 μ

m occupy 0 to 10%, the main pores have a pore diameter distribution such that the first pores occupy 15 to 85% and second pores occupy 15 to 85%.

2. The carbon dioxide gas absorbent according to claim 1, wherein the lithium complex oxide is lithium silicate.

3. The carbon dioxide gas absorbent according to claim 1, wherein the lithium complex oxide is lithium orthosilicate.

4. The carbon dioxide gas absorbent according to claim 1, wherein the first pores have a pore distribution such that pores with a diameter of 30 to 70 μ

m occupy 50% or more based on the total amount of the first pores.

5. The carbon dioxide gas absorbent according to claim 1, wherein the second pores have a pore distribution such that pores with a diameter of 100 to 300 μ

m occupy 50% or more based on the total amount of the second pores.

6. The carbon dioxide gas absorbent according to claim 1, wherein the porous body has a porosity of 30 to 70% by volume.

7. The carbon dioxide gas absorbent according to claim 1, wherein the main pores have a pore diameter distribution such that the first pores occupy 35 to 65% and second pores occupy 35 to 65%.

8. The carbon dioxide gas absorbent according to claim 1, wherein the main pores have a pore diameter distribution such that the first pores occupy 35 to 50% and second pores occupy 50 to 65%.

9. The carbon dioxide gas absorbent according to claim 1 further containing at least one alkali metal carbonate selected from the group consisting of lithium carbonate, sodium carbonate, and potassium carbonate.

10. The carbon dioxide gas absorbent according to claim 8, wherein the alkali metal carbonate is contained in an amount of 0.5 to 10% by mole based on the total amount of the lithium complex oxide and the alkali metal carbonates.

11. A method of manufacturing a carbon dioxide gas absorbent, comprising:

preparing mixed powders by mixing lithium carbonate powders and silicon dioxide powders, the lithium carbonate powders have a grain size distribution such that main powders which consist of first powders with a diameter of 1 to 10 μ

m and second powders with a diameter larger than 10 μ

m and 300 μ

m or smaller occupy 80 to 100% by weight, third powders with a diameter smaller than 1 μ

m occupy 0 to 10% by weight and fourth powders with a diameter larger than 300 μ

m occupy 0 to 10% by weight, the main powders have a grain size distribution such that the first powders occupy 15 to 85% by weight and second powders occupy 15 to 85% by weight, the silicon dioxide powders have the same grain size distribution of the lithium carbonate powders;

molding the mixed powders; and

heating the molded body to 700°

C. or higher.

12. The method according to claim 11, wherein the first powders have a grain size distribution such that powders with a diameter of 1 to 5 μ

m occupy 50% by weight or more based on the total amount of the first powders.

13. The method according to claim 11, wherein the second powders have a grain size distribution such that powders with a diameter of 50 to 300 μ

m occupy 50% by weight or more based on the total amount of the second powders.

14. The method according to claim 11, wherein the main powders of the lithium carbonate powders and silicon dioxide powders have a grain size distribution such that the first powders occupy 35 to 65% by weight and second powders 35 to 65% by weight, respectively.

15. The method according to claim 11, wherein the main powders of the lithium carbonate powders and silicon dioxide powders have a grain size distribution such that the first powders occupy 35 to 50% by weight and second powders 50 to 65% by weight, respectively.

16. The method according to claim 11, wherein at least one alkali metal carbonate selected from the group consisting of lithium carbonate, sodium carbonate, and potassium carbonate is further mixed with the mixed powders.

17. The method according to claim 16, wherein the alkali metal carbonate is mixed in an amount of 0.5 to 10% by mole based on the total amount of lithium carbonate powders, the silicon dioxide powders and the alkali metal carbonate powders.