Fluid quality control using broad spectrum impedance spectroscopy

• US 20060214671A1
• Filed: 05/02/2006
• Published: 09/28/2006
• Est. Priority Date: 02/16/2004
• Status: Active Grant

• Current Assignee: David Lee Wooton, Martin Arthur Seitz, Richard Walter Hirthe
• Original Assignee: David Lee Wooton, Martin Arthur Seitz, Richard Walter Hirthe
• Inventors: Hirthe, Richard Walter, Seitz, Martin Arthur, Wooton, David Lee
• Granted Patent: US 7,199,595 B2
• Time in Patent Office: Days
• US Class Current: 324/698
• CPC Class Codes: G01N 27/026 Dielectric impedance spectroscopy electrochemical impedance spectroscopy for measuring corrosion G01N17/02
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

A system and method for monitoring and controlling the properties of fluids is disclosed. The inventive concept employs impedance spectroscopy (IS) measurements, and is suitable for real-time, in situ, monitoring and quality control operations, such as quality control during the manufacture of blended lubricants. IS data are obtained for three or more frequencies, where the lowest frequency is less than 1 Hz and the highest frequency is greater than 1 Hz. These data may be interpreted according to statistical techniques such as Principal Component Regression, analytical techniques such as equivalent circuit modeling, or by a combination thereof. The data analysis provides characteristics, or IS signatures, relating to the properties of the fluid. IS signatures for a test fluid are compared to IS signatures for calibration fluids to determine whether the properties of the test fluid fall within specified limits. Quality control adjustments to the test fluid properties may be performed based on the IS signatures.

Claims

1. A fluid property quality control method, comprising the steps of:

a) obtaining a set of calibration fluids representative of a manufacturing process;

b) performing impedance measurements on each of the calibration fluids to obtain first impedance spectroscopy (IS) data, wherein the first IS data include data for at least three frequencies;

c) using an at least one statistical technique to analyze the first IS data providing first IS signatures indicative of properties for each of the calibration fluids;

d) performing impedance measurements on a test fluid providing second IS data, wherein the second IS data include data for at least three frequencies;

e) using the at least one statistical technique to analyze the second IS data providing second IS signatures indicative of properties of the test fluid;

f) comparing the first IS signatures and the second IS signatures providing quality control information relating to the properties of the test fluid; and

g) modifying the manufacturing process responsive to the quality control information;

wherein the at least one statistical technique includes at least one of the following statistical techniques;

Principal Component Analysis, Multivariate Least Squares Regression, Principal Component Regression, Pattern Recognition analysis, Cluster analysis, Neural Net analysis, and Group Methods of Data Handling.

2. The fluid property quality control method of claim 1, wherein the first IS signatures and the second IS signatures include principal components.

3. The fluid property quality control method of claim 1, wherein the set of calibration fluids include calibration fluids having selected concentrations of at least one additive in a base fluid, and wherein the selected concentrations are representative of desired concentration limits for the at least one additive.

4. The fluid property quality control method of claim 3, wherein the base fluid includes at least one component from the following categories:

mineral base oil and synthetic base oil.

5. The fluid property quality control method of claim 4, wherein the at least one additive includes at least one component selected from the following categories:

viscosity modifiers, pour point depressants, stabilizers, seal swell agents, anti-static additives, antioxidants, metal deactivators, anti-foam agents, detergents, dispersants, anti-wear additives, and corrosion inhibitors.

6. The fluid property quality control method of claim 1 wherein the at least three frequencies of steps b) and d) each include at least one frequency less than one Hertz, and at least one frequency greater than one Hertz.

7. The fluid property quality control method of claim 1, wherein the test fluid is a lubricant, and wherein the lubricant includes concentrations of additives.

8. The fluid property quality control method of claim 7, wherein the step g) of modifying the manufacturing process includes modifying the concentrations of additives to the lubricant.

9. The fluid property quality control method of claim 1, wherein the test fluid is a lubricant additive package, and wherein the lubricant additive package has concentrations of components.

10. The fluid property quality control method of claim 9, wherein the step g) of modifying the manufacturing process includes modifying the concentrations of components in the lubricant additive package.

11. A quality control system controlling properties of a fluid during manufacture, comprising:

a) an impedance spectroscopy (IS) probe operatively disposed in contact with the fluid;

b) an impedance spectrometer, operatively connected to the IS probe, wherein the impedance spectrometer performs impedance measurements on the fluid, and wherein the impedance spectrometer provides IS data for at least three distinct frequencies;

c) a data processing system, operatively coupled to the impedance spectrometer receiving the IS data, wherein the data processing system provides first IS signatures indicative of the fluid properties, and wherein the data processing system provides quality control information responsive to a comparison of the first IS signatures to a set of second IS signatures, wherein the set of second IS signatures are indicative of properties of a set of calibration fluids; and

d) a Quality Control Operator, operatively disposed to receive the quality control information from the data processing system, and wherein the Quality Control Operator modifies the fluid properties in response to the quality control information;

wherein the data processing system employs at least one statistical technique, and wherein the at least one statistical technique includes at least one of the following statistical techniques;

Principal Component Analysis, Multivariate Least Squares Regression, Principal Component Regression, Pattern Recognition analysis, Cluster analysis, Neural Net analysis, and Group Methods of Data Handling.

12. The quality control system of claim 11, wherein the first IS signatures and the second IS signatures include principal components.

13. The quality control system of claim 11, wherein the IS probe includes concentric tubular electrodes.

14. The quality control system of claim 11, wherein the fluid is a lubricant.

15. The quality control system of claim 11, wherein the fluid is a lubricant additive package.

16. The quality control system of claim 11, wherein the data processing system includes a CPU and a memory.

17. The quality control system of claim 11, wherein the set of calibration fluids include calibration fluids having selected concentrations of at least one additive in a base fluid, and wherein the selected concentrations are representative of desired concentration limits for the at least one additive.

18. The quality control system of claim 17, wherein the base fluid includes at least one component from the following categories:

mineral base oil and synthetic base oil.

19. The quality control system of claim 17, wherein the at least one additive includes at least one component selected from the following categories:

viscosity modifiers, pour point depressants, stabilizers, seal swell agents, anti-static additives, antioxidants, metal deactivators, anti-foam agents, detergents, dispersants, anti-wear additives, and corrosion inhibitors.

20. The quality control system of claim 11, wherein the Quality Control Operator includes at least one of the following:

a person, an apparatus, and an automatic system.

21. The quality control system of claim 11, wherein the fluid includes concentrations of additives, and wherein the Quality Control Operator modifies the fluid properties by adjusting the concentrations of additives in the fluid.

22. The quality control system of claim 11, wherein the fluid is a lubricant having concentrations of additives, and wherein the Quality Control Operator modifies the fluid properties by adjusting the concentrations of additives in the lubricant.

23. The quality control system of claim 11, wherein the fluid is lubricant additive package, wherein the lubricant additive package has concentrations of components, and wherein the Quality Control Operator modifies the fluid properties by adjusting the concentrations of components in the additive package.

24. A quality control system controlling properties of a manufactured fluid, comprising:

a) means for obtaining a set of calibration fluids representative of a manufacturing process;

b) means for performing impedance measurements on each of the calibration fluids to obtain first impedance spectroscopy (IS) data, wherein the first IS data include data for at least three frequencies;

c) means for analyzing the first IS data providing first IS signatures indicative of properties for each of the calibration fluids;

d) means for performing impedance measurements on a test fluid, wherein the test fluid is derived from the manufactured fluid, providing second IS data, wherein the second IS data include data for at least three frequencies;

e) means for analyzing the second IS data providing second IS signatures indicative of properties of the test fluid;

f) means for comparing the first IS signatures and the second IS signatures providing quality control information relating to the properties of the test fluid; and

g) means for modifying the properties of the manufactured fluid responsive to the quality control information;

wherein the means for analyzing the first IS data and the means for analyzing the second IS data include means for using at least one statistical technique, and wherein the at least one statistical technique includes at least one of the following statistical techniques;

Principal Component Analysis, Multivariate Least Squares Regression, Principal Component Regression, Pattern Recognition analysis, Cluster analysis, Neural Net analysis, and Group Methods of Data Handling.

25. The quality control system of claim 24, wherein the first IS signatures and the second IS signatures include principal components.

26. The quality control system of claim 24, wherein the means for performing impedance measurements includes an IS probe having concentric tubular electrodes.

27. The quality control system of claim 24, wherein the manufactured fluid is a lubricant.

28. The quality control system of claim 24, wherein the manufactured fluid is a lubricant additive package.

29. The quality control system of claim 24, wherein the means for analyzing the first IS data and the means for analyzing the second IS data comprise a data processing system.

30. The quality control system of claim 29, wherein the data processing system includes a CPU and a memory.

31. The quality control system of claim 24, wherein the set of calibration fluids include calibration fluids having selected concentrations of at least one additive in a base fluid, and wherein the selected concentrations are representative of desired concentration limits for the at least one additive.

32. The quality control system of claim 31, wherein the base fluid includes at least one component from the following categories:

mineral base oil and synthetic base oil.

33. The quality control system of claim 31, wherein the at least one additive includes at least one component selected from the following categories:

viscosity modifiers, pour point depressants, stabilizers, seal swell agents, anti-static additives, antioxidants, metal deactivators, anti-foam agents, detergents, dispersants, anti-wear additives, and corrosion inhibitors.

34. The quality control system of claim 24, wherein the means for modifying the properties of the manufactured fluid includes at least one of the following:

a person, an apparatus, and an automatic system.

35. The quality control system of claim 24, wherein the manufactured fluid is a lubricant having concentrations of additives, and the means for modifying the properties of the manufactured fluid modifies the manufactured fluid properties by adjusting the concentrations of additives in the lubricant.

36. The quality control system of claim 24, wherein the manufactured fluid is a lubricant additive package, wherein the lubricant additive package has concentrations of components, and wherein the means for modifying the properties of the manufactured fluid modifies the fluid properties by adjusting the concentrations of components in the additive package.

37. A fluid property quality control method, comprising the steps of:

a) obtaining a set of calibration fluids representative of a first product;

b) performing impedance measurements on each of the calibration fluids to obtain first impedance spectroscopy (IS) data, wherein the first IS data include data for at least three frequencies;

c) using an at least one statistical technique to analyze the first IS data providing first IS signatures indicative of properties for each of the calibration fluids;

d) performing impedance measurements on a test fluid providing second IS data, wherein the test fluid is representative of a second product, and wherein the second IS data include data for at least three frequencies;

e) using the at least one statistical technique to analyze the second IS data providing second IS signatures indicative of properties of the test fluid;

f) comparing the first IS signatures and the second IS signatures providing quality control information relating to the properties of the test fluid; and

g) selectively accepting the second product, responsive to the quality control information;

wherein the at least one statistical technique includes at least one of the following statistical techniques;

Principal Component Analysis, Multivariate Least Squares Regression, Principal Component Regression, Pattern Recognition analysis, Cluster analysis, Neural Net analysis, and Group Methods of Data Handling.

38. The fluid property quality control method of claim 37, wherein the first IS signatures and the second IS signatures include principal components.

39. The fluid property quality control method of claim 37, wherein the first product is a genuine product.

40. The fluid property quality control method of claim 39, wherein the second product belongs to one of the following categories:

a genuine product and a counterfeit product.

41. The fluid property quality control method of claim 37, wherein the first product is a product of acceptable quality.

42. The fluid property quality control method of claim 41, wherein the second product belongs to one of the following categories:

a product of acceptable quality and a product of unacceptable quality.

43. The fluid property quality control method of claim 37, wherein the set of calibration fluids include calibration fluids having selected concentrations of at least one additive in a base fluid, and wherein the selected concentrations are representative of desired concentration limits for the at least one additive.

44. The fluid property quality control method of claim 43, wherein the base fluid includes at least one component from the following categories:

mineral base oil and synthetic base oil.

45. The fluid property quality control method of claim 43, wherein the at least one additive includes at least one component selected from the following categories:

viscosity modifiers, pour point depressants, stabilizers, seal swell agents, anti-static additives, antioxidants, metal deactivators, anti-foam agents, detergents, dispersants, anti-wear additives, and corrosion inhibitors.

46. The fluid property quality control method of claim 37 wherein the frequencies of steps b) and d) each include at least one frequency less than one Hertz, and at least one frequency greater than one Hertz.

47. The fluid property quality control method of claim 37, wherein the test fluid is a lubricant.

48. The fluid property quality control method of claim 37, wherein the test fluid is a lubricant additive package.