FABRIC TREATED WITH DURABLE STAIN REPEL AND STAIN RELEASE FINISH AND METHOD OF INDUSTRIAL LAUNDERING TO MAINTAIN DURABILITY OF FINISH

• US 20060228964A1
• Filed: 04/11/2006
• Published: 10/12/2006
• Est. Priority Date: 04/12/2005
• Status: Abandoned Application

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.), Huntsman International LLC (Huntsman Corporation)
• Original Assignee: Ciba Specialty Chemicals Corp (BASF SE), Invista North America Sarl (Invista)
• Inventors: Seals, Leonard Ray, WATKINS, MICHELLE H., Covelli, Carmen A.
• Application Number:
  US11/279,272
• Publication Number:
  US 20060228964A1
• Time in Patent Office: Days
• US Class Current: 442/94
• CPC Class Codes: D06F 35/00 Washing machines, apparatus, or methods not otherwise provided for
• CPC Class Codes: D06L 4/20 using agents which contain halogen
• CPC Class Codes: D06M 15/277 containing fluorine
• CPC Class Codes: D06M 15/576 containing fluorine
• CPC Class Codes: D06M 2101/32 Polyesters
• CPC Class Codes: D06M 2200/11 Oleophobic properties
• CPC Class Codes: D06M 2200/12 Hydrophobic properties
• CPC Class Codes: D06M 23/00 Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
• CPC Class Codes: D06M 23/02 Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
• CPC Class Codes: Y10T 442/2262 Coating or impregnation is oil repellent but not oil or stain release
• CPC Class Codes: Y10T 442/2279 Coating or impregnation improves soil repellency, soil release, or anti- soil redeposition qualities of fabric
• CPC Class Codes: Y10T 442/2287 Fluorocarbon containing
• CPC Class Codes: Y10T 442/2861 Coated or impregnated synthetic organic fiber fabric
• CPC Class Codes: Y10T 442/3146 Strand material is composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material

Abstract

The invention provides a fabric comprising one or more polyesters optionally with other fibers which is treated with a finish comprising at least one fluorochemical stain repellent agent and at least one fluorochemical stain release agent, wherein the fabric maintains oil repellency and stain release capability after at least five industrial launderings at about 55° C. to about 65° C. The invention also provides a method of treating a fabric with a finish to impart oil repellency, water repellency, and stain release which is durable to repeated industrial laundering. The invention further provides textile articles comprising the treated fabric, and a method for industrial laundering of such treated fabric and textile articles.

Claims

1. A fabric comprising one or more polyesters or one or more polyesters blended with other fibers or combinations of fibers, wherein the fabric is treated with a finish comprising at least one fluorochemical stain repellent agent and at least one fluorochemical stain release agent, wherein the fabric has an oil repellency rating of at least 3 as measured by AATCC Test Method 118-2002 and a stain release rating of at least 3 as measured by AATCC Test Method 130-2000 after at least 5 industrial launderings at about 55°

C. to about 65°

C.

2. The fabric of claim 1 wherein the fabric further has a water repellency rating of at least 3 as measured by the Water Drop Test Method.

3. The fabric of claim 1 wherein the fabric further has said oil repellency and said stain release ratings after at least 30 industrial launderings.

4. The fabric of claim 1 wherein the fabric has said oil repellency and said stain release ratings after at least 50 industrial launderings.

5. The fabric of claim 1 comprising a blend with cotton, wherein the fabric comprises from about 5 weight percent to about 95 weight percent polyester, based on total weight of fabric.

6. The fabric of claim 5, wherein the polyester is a bicomponent fiber comprising poly(trimethylene terephthalate) and at least one polymer selected from the group consisting of poly(ethylene terephthalate), poly(trimethylene terephthalate), and poly(tetramethylene terephthalate), or a combination of such members.

7. The treated fabric of claim 6, wherein the bicomponent fiber comprises a combination of poly(ethylene terephthalate) and poly(trimethylene terephthalate).

8. The fabric of claim 1, wherein the at least one fluorochemical stain repellent agent comprises at least one fluorinated polyurethane, and the at least one fluorochemical stain release agent comprises at least one fluorinated substituted urethane.

9. The fabric of claim 8 wherein the ratio of the percent on weight of fabric of the at least one fluorinated polyurethane to the percent on weight of fabric of the at least one fluorinated substituted urethane is from about 0.2 to about 3.0.

10. The fabric of claim 9, wherein the ratio of the percent on weight of fabric of the at least one fluorinated polyurethane to the percent on weight of fabric of the at least one fluorinated substituted urethane is from about 0.6 to about 1.4.

11. A textile article comprising the fabric of claim 1.

12. The textile article of claim 11 wherein the textile article is selected from the group consisting of a uniform, a jumpsuit, a smock, a work shirt, a work pant, a chef coat, a chef apron, and a chef hat, or a combination of such articles.

13. A method for treating a fabric with a finish to impart oil repellency, water repellency, and stain release which is durable to repeated industrial laundering, the method comprising the steps of:

a) providing a fabric comprising one or more polyesters or one or more polyesters blended with another fiber or combination of fibers;

b) applying a finish comprising at least one fluorinated polyurethane stain repellent agent and at least one fluorinated substituted urethane stain release agent, wherein the ratio of the percent on weight of fabric of the at least one fluorinated polyurethane to the percent on weight of fabric of the at least one fluorinated substituted urethane is from about 0.2 to about 3.0; and

c) drying the fabric with applied finish from about 160°

C. to about 200°

C.

14. The method of claim 13, wherein the fabric comprises polyester and cotton, and the fabric comprises from about 5 weight percent to about 95 weight percent polyester, based on total weight of fabric.

15. The method of claim 14, wherein the polyester is a bicomponent fiber comprising poly(trimethylene terephthalate) and at least one polymer selected from the group consisting of poly(ethylene terephthalate), poly(trimethylene terephthalate), poly(tetramethylene terephthalate), and a combination of such members.

16. The method of claim 15, wherein the bicomponent fiber comprises poly(ethylene terephthalate) and poly(trimethylene terephthalate).

17. The method of claim 13, wherein the method of applying the finish is selected from the group consisting of padding, coating, impregnating, immersing, spraying, brushing, film-coating, and a combination of such application methods.

18. The method of claim 13, wherein the fabric with applied finish is dried for about 1 minute to about 2 minutes.

19. The method of claim 13, wherein the ratio of the percent on weight of fabric of the at least one fluorinated polyurethane stain repellent agent to the percent on weight of fabric of the at least one fluorinated substituted urethane stain release agent is from about 0.6 to about 1.4.

20. A method for industrial laundering of a fabric or a textile article comprising the fabric, the fabric being treated with a finish comprising at least one fluorochemical stain repellent agent and at least one fluorochemical stain release agent to impart oil repellency and stain release, the method comprising the steps of:

a) providing a treated fabric or a textile article comprising the treated fabric,

b) washing the fabric or the textile article in water containing a detergent at about 55°

C. to about 65°

C.;

c) separating the wash water from the fabric or textile article;

d) rinsing the fabric or the textile article;

e) separating the rinse water from the fabric or textile article; and

f) drying the fabric or textile article to provide dry fabric or dry textile article having an oil repellency rating of at least 3 as measured by AATCC Test Method 118-2002 and a stain release rating of at least 3 as measured by AATCC Test Method 130-2000.

23. The method of claim 20 wherein the fabric or the textile article has said oil repellency and said stain release ratings of at least 3 after repeating steps a) through f) at least 5 times.

24. The method of claim 20, wherein the fabric or the textile article has said oil repellency and said stain release ratings after repeating steps a) through f) above at least 30 times.

25. The method of claim 20, wherein the fabric or textile article has said oil repellency and said stain release ratings after repeating steps a) through f) at least 40 times.

26. The method of claim 20, wherein the fabric or textile article has said oil repellency and said stain release ratings after repeating steps a) through f) at least 50 times.

21. The method of claim 21, wherein the finish comprises at least one fluorinated urethane polymer as the stain repellent agent and at least one perfluorinated polymer as the stain release agent.

22. The method of claim 21, wherein the water for washing contains chlorine bleach.