STABLE ANTIMICROBIAL COMPOSITIONS INCLUDING SPORE, BACTERIA, FUNGI, AND/OR ENZYME

• US 20060247150A1
• Filed: 05/05/2006
• Published: 11/02/2006
• Est. Priority Date: 06/29/2000
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Besse, Michael E., Pedersen, Daniel E., Molinaro, Katherine J., Magnuson, Joshua P., Steep, Jaclyn
• Granted Patent: US 7,795,199 B2
• Time in Patent Office: Days
• US Class Current: 510/499
• CPC Class Codes: C11D 17/041 Compositions releasably affixed on a substrate or incorporated into a dispensing means
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/30 Amines; Substituted amines ; Quaternized amines
• CPC Class Codes: C11D 3/381 Microorganisms
• CPC Class Codes: C11D 3/386 Preparations containing enzymes , e.g. protease or amylase
• CPC Class Codes: C11D 3/38663 Stabilised liquid enzyme compositions
• CPC Class Codes: C11D 3/48 Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

Abstract

The present invention relates to a stable antimicrobial and cleaning compositions including an amine antimicrobial agent; a borate salt; and spores (bacterial or fungal), vegetative bacteria, fungi, or enzyme, and to methods of using the composition. The composition can also include a polyol.

Claims

1. A cleaning composition comprising:

spore, bacteria, fungi, or enzyme;

alkanol amine borate; and

amine antimicrobial agent.

2. The composition of claim 1, wherein the amine antimicrobial agent comprises aliphatic amine, ether amine, or diamine.

3. The composition of claim 2, wherein the amine antimicrobial agent comprises an ether amine of Formula 1:

R₁—

O—

R₂—

NH₂, of Formula 2;

R₁—

O—

R₂—

NH—

R₃—

NH₂, or mixtures thereof;

in which;

R₁ is a linear saturated or unsaturated C₆-C₁₈ alkyl;

R₂ is a linear or branched C₁-C₈ alkyl; and

R₃ is a linear or branched C₁-C₈ alkyl.

4. The composition of claim 2, wherein the amine antimicrobial agent comprises

[(R¹)NH(R²)NH₃]⁺(CH₃ COO)⁻

or
[(R¹)NH₂(R²)NH₃⁺⁺](CH₃COO)₂;

in which;

R¹ is C10-C18 aliphatic group or an ether group having the formula R¹⁰OR¹¹;

in which R¹⁰ is a C10-C18 aliphatic group and R¹¹ is a C1-C5 alkyl group; and

R² is a C1-C5 alkylene group

5. The composition of claim 1, wherein the composition has pH greater than or equal to 8.

6. The composition of claim 1, further comprising polyol.

7. The composition of claim 1, comprising about 5 to about 35 wt-% alkanol amine borate and the alkanol amine borate comprises monoethanolammonium borate, diethanolammonium borate, triethanolammonium borate, or a combination thereof.

8. The composition of claim 1, further comprising about 0.003 to about 35 wt-% nonionic surfactant and the nonionic surfactant comprises:

nonionic block copolymer comprising of at least (EO)_y(PO)_z, wherein y and z are independently between 2 and 100;

C_6-24 alkyl phenol alkoxylate having 2 to 15 moles of ethylene oxide;

C_6-24 alcohol alkoxylate having 2 to 15 moles of ethylene oxide;

alkoxylated amine having 2-20 moles of ethylene oxide;

or mixtures thereof.

9. The composition of claim 1, further comprising about 0.0005 to about 35 wt-% silicone surfactant.

11. The composition of claim 1, comprising detersive enzyme.

12. The composition of claim 24, wherein the detersive enzyme comprises protease, amylase, lipase, cellulase, peroxidase, gluconase, or mixtures thereof.

13. A cleaning composition comprising:

spore, bacteria, fungi, or enzyme;

borate salt; and

amine antimicrobial agent;

the composition being substantially free of sodium ion.

10. The composition of claim 16, comprising about 0.1 to about 20 wt-% hydrotrope.

14. The composition of claim 13, wherein the amine antimicrobial agent comprises aliphatic amine, ether amine, or diamine.

15. The composition of claim 14, wherein the amine antimicrobial agent comprises an ether amine of Formula 1:

R₁—

O—

R₂—

NH₂, of Formula 2;

R₁—

O—

R₂—

NH—

R₃—

NH₂, or mixtures thereof;

in which;

R₁ is a linear saturated or unsaturated C₆-C₁₈ alkyl;

R₂ is a linear or branched C₁-C₈ alkyl; and

R₃ is a linear or branched C₁-C₈ alkyl.

16. The composition of claim 14, wherein the amine antimicrobial agent comprises

[(R¹)NH(R²)NH₃]⁺(CH₃ COO)⁻

or
[(R¹)NH₂(R²)NH₃⁺⁺](CH₃COO)₂;

in which;

R¹ is C10-C18 aliphatic group or an ether group having the formula R¹⁰OR¹¹;

in which R¹⁰ is a C10-C18 aliphatic group and R¹¹ is a C1-C5 alkyl group; and

R² is a C1-C5 alkylene group

17. A method of cleaning a hard surface, comprising applying to the surface a cleaning composition comprising:

spore, bacteria, fungi, or enzyme;

borate salt;

amine antimicrobial agent;

nonionic surfactant; and

, optionally,

about 0.1 to about 35 wt-% silicone surfactant.

18. A method of increasing the coefficient of friction of a hard surface, comprising applying to the surface a cleaning composition comprising:

spore, bacteria, fungi, or enzyme;

borate salt;

amine antimicrobial agent;

nonionic surfactant; and

, optionally,

about 0.1 to about 35 wt-% silicone surfactant.

19. A method of cleaning grout, comprising applying to the grout a cleaning composition comprising:

spore, bacteria, fungi, or enzyme;

borate salt;

amine antimicrobial agent;

nonionic surfactant; and

, optionally,

about 0.1 to about 35 wt-% silicone surfactant.