Vehicle interior article of skin-integrated laminate, method for manufacturing non-foaming polyurethane resin and method for manufacturing skin-integrated laminate using the same

• US 20060264522A1
• Filed: 04/20/2006
• Published: 11/23/2006
• Est. Priority Date: 04/28/2005
• Status: Active Grant

• Current Assignee: Covestro Deutschland AG
• Original Assignee: Bayer Materialscience AG (Covestro AG)
• Inventors: Nishikawa, Shinji, Suzuki, Masaru, Ido, Hiroaki, Ikuta, Hiroshi
• Granted Patent: US 7,572,404 B2
• Time in Patent Office: Days
• US Class Current: 521/51
• CPC Class Codes: C08G 18/6685 with compounds of group C08G18/3225 or polyamines of C08G18/38
• CPC Class Codes: C08G 2120/00 Compositions for reaction injection moulding processes

Abstract

The present invention is directed to skin-integrated laminates and their use as vehicle interior articles, in which the laminates feel comfortable to the touch and have a high quality of external appearances. The invention also relates to a method for manufacturing these non-foaming polyurethane resins for use as design skins in vehicle interior articles and to a method for manufacturing a skin-integrated laminate from these non-foaming polyurethane resins, with both methods having increased productivity and lower cost, and without any adverse influence on the work environment. The non-foaming polyurethane resin forms a design skin surface by a reaction injection molding process, in which (I) a polyol mixture of (1) a polyol, (2) a chain extender which is 1-methyl-3,5-diethyl-2,4-diaminobenzene and/or 1-methyl-3,5-diethyl-2,6-diaminobenzene, (3) a catalyst, and (4) optionally, an auxiliary agent, and (II) a polyisocyanate compound, are reacted. The surface hardness of the non-foaming polyurethane resin, as measured by an Asker A hardness meter, is from 30 to 70.

Claims

1. A vehicle interior article comprising a skin-integrated laminate comprising a core material and a design surface skin of a non-foaming polyurethane resin which is prepared by a reaction injection molding process, wherein the non-foaming polyurethane resin comprises:

(I) a polyol mixture which comprises;

(1) a polyol,

(2) from 2.0 to 7.0 parts by weight, based on 100 parts by weight of (I) the polyol mixture, of a chain extender, the chain extender being selected from the group consisting of 1-methyl-3,5-diethyl-2,4-diaminobenzene, 1-methyl-3,5-diethyl-2,6-diaminobenzene and mixtures thereof,

(3) a catalyst, and

(4) optionally, an auxiliary agent, and

(II) a polyisocyanate compound,

and in which the surface hardness of the non-foaming polyurethane resin, as measured by an Asker A hardness meter, is from 30 to 70.

2. A vehicle interior article which comprises the skin-integrated laminate of claim 1, wherein the laminate additionally comprises a semi-rigid polyurethane foam between the design surface skin and the core material.

3. A method of producing a non-foaming polyurethane resin comprising

(A) reaction injection molding of

(I) a polyol mixture comprising

(1) a polyol,

(2) from 2.0 to 7.0 parts by weight, based on 100 parts by weight of (I) the polyol mixture, of a chain extender, the chain extender being selected from the group consisting of 1-methyl-3,5-diethyl-2,4-diaminobenzene, 1-methyl-3,5-diethyl-2,6-diaminobenzene and mixtures thereof,

(3) a catalyst, and

(4) optionally, a auxiliary agent, and

(II) a polyisocyanate compound, and

(B) molding the part at the cure time of 30 to 100 seconds under the condition that the gel time for reaction mixture liquid based on components (I) and (II) is from 5.0 to 15.0 seconds,

with the resultant molded product having thickness of 0.5 to 3.0 mm.

4. The method of claim 3, wherein the surface hardness of the non-foaming polyurethane resin is from 30 to 7, as measured by an Asker A hardness meter.

5. A method of producing a skin-integrated laminate comprising a design surface skin of a non-foaming polyurethane resin and a core material, comprising the steps of:

(1) installing a core material to a core part of an article mold,

(2) applying a mold release agent on a cavity part surface of an article mold,

(3) optionally, applying a paint film on the cavity part surface of an article mold,

(4) closing the core part and the cavity part of an article mold,

(5) reaction injection molding (I) a polyol mixture and (II) a polyisocyanate compound (I), wherein (I) said polyol mixture comprises;

(1) a polyol, (2) from 2.0 to 7.0 parts by weight, based on 100 parts by weight of (I) the polyol mixture, of a chain extender, the chain extender being selected from the group consisting of 1-methyl-3,5-diethyl-2,4-diaminobenzene, 1-methyl-3,5-diethyl-2,6-diaminobenzene and mixtures thereof, (3) a catalysts, and (4) optionally, an auxiliary agent; and

(6) removing the integral molded article.

6. A method of producing a skin-integrated laminate comprising a design surface of a non-foaming polyurethane resin, a semi-rigid polyurethane foam and a core material, which comprises the steps of:

(1) applying a mold release agent on a core part and a cavity part of an article mold for the surface skin which forms the design surface;

(2) optionally, applying a paint film on the cavity surface of an article mold;

(3) closing the core part and the cavity part of the article mold;

(4) reaction injection molding a mixture comprising (I) a polyol mixture, and (II) a polyisocyanate compound, wherein (I) said polyol mixture comprises;

(1) a polyol, (2) from 2.0 to 7.0 parts by weight, based on 100 parts by weight of (I) the polyol mixture, of a chain extender, the chain extender being selected from the group consisting of 1-methyl-3,5-diethyl-2,4-diaminobenzene, 1-methyl-3,5-diethyl-2,6-diaminobenzene and mixtures thereof, (3) a catalysts, and (4) optionally, an auxiliary agent;

(5) removing the molded article of a non-foaming polyurethane resin which forms the design surface skin;

(6) placing the molded article of a non-foaming polyurethane resin from step (5) into a cavity part of a foaming mold, (7) installing the core material to a core part of the foaming mold,

(8) pouring a semi-rigid polyurethane foam mixture onto the non-foaming polyurethane resin which was placed onto the cavity part of the foaming mold in the step (6), with an opened or closed system, and

(9) removing the resultant integral molded article having a design surface skin.