Preparation of highly pure methyl tert-butyl ether

• US 20060264681A1
• Filed: 06/14/2003
• Published: 11/23/2006
• Est. Priority Date: 07/10/2002
• Status: Active Grant

• Current Assignee: Evonik Degussa GmbH
• Original Assignee: OXENO Olefinchemie GmbH (Evonik Degussa GmbH)
• Inventors: Nierlich, Franz, Scholz, Bernhard, Peters, Udo, Praefke, Jochen, Filipiak, Richard, Obenaus, Fritz, Droste, Wilhelm, Neumeister, Joachim, Malzkorn, Rainer
• Granted Patent: US 7,304,188 B2
• Time in Patent Office: Days
• US Class Current: 568/671
• CPC Class Codes: C07C 41/42 by distillation
• CPC Class Codes: C07C 43/046 Alkyl tert-alkyl ether, e.g. CH3OC(CH3)3

Abstract

The invention relates to a process for preparing methyl tert-butyl ether (MTBE) in qualities which are suitable for organic syntheses and for use as a specialty solvent from MTBE in fuel quality.

Claims

1. A process for preparing methyl tert-butyl ether having a purity of greater than 99.7% from technical grade methyl tert-butyl ether by fractional distillation, which comprises separating said technical grade methyl tert-butyl ether into a low boiler fraction comprising methyl tert-butyl ether, methanol and water, a middle fraction comprising methyl tert-butyl ether in a purity of greater than 99.7% and a high boiler fraction comprising tert-butyl alcohol and butene oligomers.

2. The process as claimed in claim 1, wherein the fractional distillation is carried out in at least two columns.

3. The process as claimed in claim 1, wherein the fractional distillation is carried out in at least one dividing wall column.

4. The process as claimed in claim 1 wherein the fractional distillation is carried out in a two-column system which consists of a main column and a side column, and the low boiler fraction is obtained as the top product and the high boiler fraction as the bottom product of the main column and the middle fraction is purified in the side column to give the methyl tert-butyl ether having a purity of greater than 99.7%.

5. The process as claimed in claim 4, wherein the methyl tert-butyl ether having a purity of greater than 99.7% is obtained as the top product of the side column.

6. he process as claimed in claim 4, wherein the methyl tert-butyl ether having a purity of greater than 99.7% is obtained as the bottom product of the side column.

7. The process as claimed in claim 4, wherein the fraction of the side column which does not comprise the methyl tert-butyl ether having a purity of greater than 99.7% is recycled into the main column.

8. The process as claimed in claim 1, wherein the methyl tert-butyl ether having a purity of greater than 99.7% has a 2-methoxybutane content of less than 500 ppm by mass.

9. The process as claimed in claim 1, wherein the low boiler fraction is recycled into the fractional distillation.

10. The process as claimed in claim 1, wherein the high boiler fraction is recycled into the fractional distillation.

11. A process for preparing highly pure isobutene by catalytically cleaving the methyl tert-butyl ether having a purity of greater than 99.7% prepared by the process as claimed in claim 1.