Peelable vacuum skin packages

• US 20060269707A1
• Filed: 05/31/2005
• Published: 11/30/2006
• Est. Priority Date: 05/31/2005
• Status: Active Grant

• Current Assignee: Bemis Company Incorporated (Amcor Plc)
• Original Assignee: Curwood Incorporated (Amcor Plc)
• Inventors: Berbert, Otacilio T.
• Granted Patent: US 8,597,746 B2
• Time in Patent Office: Days
• US Class Current: 428/35.700
• CPC Class Codes: B65D 75/305 Skin packages
• CPC Class Codes: B65D 75/5855 Peelable seals
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/1379 Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
• CPC Class Codes: Y10T 428/1383 Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer]

Abstract

The present invention describes vacuum skin packages comprising a thermoplastic film and a polyester substrate wherein the thermoplastic film includes at least a first polymer layer having a first surface and an opposing second surface and comprises an ethylene/unsaturated ester copolymer, wherein the first surface has been surface treated in a manner to exhibit a surface tension of between 36-60 dynes/cm. The thermoplastic film is adapted to form a peelable seal between the first surface of the first polymer layer of the thermoplastic film and the polyester substrate by a pressure of less than 1×10⁵ Pa applied therebetween, wherein the peelable seal has a seal strength of between 0.5-6 lb./in. (0.09-1.08 kg/cm).

Claims

1. A vacuum skin package comprising:

(a) a thermoplastic film;

(b) a polyester substrate;

wherein said thermoplastic film comprises at least a first polymer layer having a first surface and an opposing second surface, wherein said first surface has a surface tension of between 36-60 dynes/cm as measured in accordance with ASTM D-2578-84 Test Method, wherein said first layer is an exterior film layer comprising an ethylene/unsaturated ester copolymer and is free of both polybutylene and ionomer resin; and

wherein said thermoplastic film is adapted to form a peelable seal between said first surface of said first layer of said thermoplastic film and said polyester substrate by pressure of less than 1×

10⁵ Pa applied therebetween, wherein said peelable seal has a seal strength of between 0.5-6 lb./in. (0.09-1.08 kg/cm) as measured in accordance with ASTM F-904 Test Method.

2. A vacuum skin package according to claim 1, wherein said thermoplastic film is a coextruded thermoplastic film formed by either cast or blown film coextrusion.

3. A vacuum skin package according to claim 1, wherein said thermoplastic film has an unrestrained linear thermal shrinkage in both the machine and transverse directions of less than 15% as measured in accordance with ASTM D-2732 Test Method.

4. A vacuum skin package according to claim 1, wherein said thermoplastic film further comprises a second polymer layer of an ionomer resin or a blend thereof, wherein said second layer adheres to said first layer and is an interior film layer.

5. A vacuum skin package according to claim 4, wherein said thermoplastic film is a cross-linked thermoplastic film such that at least one polymer layer of said cross-linked thermoplastic film has a gel content of not less than 5% as measured in accordance with ASTM D 2765-01 Test Method.

6. A vacuum skin package according to claim 4, wherein said thermoplastic film further comprises a third polymer layer of an adhesive material, wherein said third layer adheres to said second layer and is an interior film layer.

7. A vacuum skin package according to claim 6, wherein said thermoplastic film further comprises a fourth polymer layer of a material selected from the group consisting of polyolefin resin, ionomer resin and oxygen barrier material, wherein said fourth layer adheres to said third layer.

8. A vacuum skin package according to claim 7, wherein said thermoplastic film further comprises a fifth polymer layer of an adhesive material, wherein said fifth layer adheres to said fourth layer and is an interior film layer.

9. A vacuum skin package according to claim 8, wherein said thermoplastic film further comprises a sixth polymer layer of a material selected from the group consisting of polyolefin resin, ionomer resin and blends thereof.

10. A vacuum skin package according to claim 9, wherein said thermoplastic film further comprises a seventh polymer layer of a polyolefin resin or blend thereof, wherein said seventh layer is an exterior film layer.

11. A vacuum skin package according to claim 1, wherein said first surface of said first layer of said thermoplastic film has a surface tension of between 40-56 dynes/cm as measured in accordance with ASTM D-2578-84 Test Method.

12. A vacuum skin package according to claim 7, wherein said oxygen barrier material is a polymeric material such that said thermoplastic film has an oxygen transmission rate of between 0-2.0 cc/100 in.²/24 hours at 23°

C. and 0% R.H. as measured in accordance with ASTM D-3985-02 Test Method.

13. A vacuum skin package according to claim 7, wherein said oxygen barrier material is selected from the group consisting of homopolymers or copolymers of ethylene/vinyl alcohol, vinylidene chloride copolymers, and blends thereof.

14. A vacuum skin package according to claim 1, wherein said polyester substrate comprises a material selected from the group consisting of polyethylene terephthalate (PET), crystalline polyethylene terephthalate (CPET), amorphous polyethylene terephthalate (APET), and blends thereof.

15. A vacuum skin package according to claim 1, wherein said ethylene/unsaturated ester copolymer comprises a material selected from the group consisting of ethylene/methyl acrylate copolymer, ethylene/methyl methacrylate copolymer, ethylene/ethyl acrylate copolymer, ethylene/ethyl methacrylate copolymer, ethylene/butyl acrylate copolymer, ethylene/2-ethylhexyl methacrylate copolymer, ethylene/vinyl acetate copolymer, and blends thereof.

16. A vacuum skin package comprising:

(a) a thermoplastic film;

(b) a polyester substrate;

wherein said thermoplastic film comprises at least a first polymer layer, a second polymer layer, a third polymer layer, a fourth polymer layer and a fifth polymer layer;

wherein said first layer has a first surface and an opposing second surface, wherein said first surface has a surface tension of between 40-56 dynes/cm as measured in accordance with ASTM D-2578-84 Test Method and comprises a material selected from the group consisting of ethylene/methyl acrylate copolymer, ethylene/methyl methacrylate copolymer, ethylene/ethyl acrylate copolymer, ethylene/ethyl methacrylate copolymer, ethylene/butyl acrylate copolymer, ethylene/2-ethylhexyl methacrylate copolymer, ethylene/vinyl acetate copolymer, and blends thereof, wherein said first layer is an exterior film layer and is free of both polybutylene and ionomer resin;

wherein said second layer comprises an ionomer resin or a blend thereof, wherein said second layer adheres to said first layer and is an interior film layer;

wherein said third layer comprises a material selected from the group consisting of polyolefin resin, ionomer resin, oxygen barrier material and a blend thereof, wherein said third layer is an interior film layer;

wherein said fourth layer comprises a material selected from the group consisting of polyolefin resin, an ionomer resin or blends thereof, wherein said fourth layer is an interior film layer;

wherein said fifth layer comprising a polyolefin resin or a blend thereof, wherein said fifth layer is an exterior film layer; and

wherein said thermoplastic film is adapted to form a peelable seal between said first surface of said first polymer layer of said thermoplastic film and said polyester substrate by pressure of less than 1×

10⁵ Pa applied therebetween, wherein said peelable seal has a seal strength of between 0.5-6 lb./in. (0.09-1.08 kg/cm) as measured in accordance with ASTM F-904 Test Method.

17. A vacuum skin package according to claim 16, wherein said thermoplastic film is a thermoplastic coextruded film formed by either cast or blown film coextrusion.

18. A vacuum skin package according to claim 16, wherein said thermoplastic film further comprises a sixth polymer layer and a seventh polymer layer, wherein said sixth and seventh layers each comprise an adhesive material.

19. A vacuum skin package according to claim 16, wherein said thermoplastic film has an unrestrained linear thermal shrinkage in both the machine and transverse directions of less than 15% as measured in accordance with ASTM D-2732 Test Method.

20. A vacuum skin package according to claim 16, wherein said thermoplastic film is a cross-linked thermoplastic film such that at least one layer of said cross-linked thermoplastic film has a gel content of not less than 5% as measured in accordance with ASTM D 2765-01 Test Method.

21. A vacuum skin package according to claim 16, wherein said first surface of said first layer of said thermoplastic film has a surface tension of between 40-56 dynes/cm as measured in accordance with ASTM D-2578-84 Test Method.

22. A vacuum skin package according to claim 16, wherein said oxygen barrier material is a polymeric material such that said thermoplastic film has an oxygen transmission rate of between 0-2.0 cc/100 in.²/24 hours at 23°

C. and 0% R.H. as measured in accordance with ASTM D-3985-02 Test Method.

23. A vacuum skin package according to claim 16, wherein said oxygen barrier material comprises a material selected from the group consisting of homopolymers or copolymers of ethylene/vinyl alcohol, vinylidene chloride copolymers, and blends thereof.

24. A vacuum skin package according to claim 16, wherein said polyester substrate comprises a material selected from the group consisting of polyethylene terephthalate (PET), crystalline polyethylene terephthalate (CPET), amorphous polyethylene terephthalate (APET), and blends thereof.

25. A vacuum skin package according to claim 16, wherein said sixth layer adheres to both said second and third layers, wherein said seventh layer adheres to both said third and fourth layers.

26. A vacuum skin package comprising:

(a) a thermoplastic film;

(b) a polyester substrate;

wherein said thermoplastic film comprises at least a first polymer layer, a second polymer layer, a third polymer layer, a fourth polymer layer, a fifth polymer layer, a sixth polymer layer and a seventh polymer layer;

wherein said first layer has a first surface and an opposing second surface, wherein said first surface has a surface tension of between 40-56 dynes/cm as measured in accordance with ASTM D-2578-84 Test Method and comprises ethylene/vinyl acetate copolymer or a blend thereof, wherein said first layer is an exterior film layer and is free of both polybutylene and ionomer resin;

wherein said second layer comprises an ionomer resin or a blend thereof, wherein said second layer adheres to both said first and third layers;

wherein said third layer comprises an adhesive material and adheres to both said second and fourth layers;

wherein said fourth layer comprises either a material selected from the group consisting of polyolefin resin, ionomer resin, and a blend thereof, or an oxygen barrier material, wherein said oxygen barrier material is a polymeric material such that said thermoplastic film has an oxygen transmission rate of between 0-2.0 cc/100 in.²/24 hours at 23°

C. and 0% R.H. as measured in accordance with ASTM D-3985-02 Test Method, wherein said fourth layer is an interior film layer;

wherein said fifth layer comprises an adhesive material and adheres to both said fourth and sixth layers;

wherein said sixth layer comprises a material selected from the group consisting of polyolefin resin, ionomer resin, and blends thereof;

wherein said seventh layer comprises a polyolefin resin or blend thereof, wherein said seventh layer adheres to said sixth layer and is an exterior film layer; and

wherein said thermoplastic film is adapted to form a peelable seal between said first surface of said first polymer layer of said thermoplastic film and said polyester substrate by pressure of less than 1×

10⁵ Pa applied therebetween, wherein said peelable seal has a seal strength of between 0.5-6 lb./in. (0.09-1.08 Kg/cm) as measured in accordance with ASTM F-904 Test Method.

27. A vacuum skin package according to claim 26, wherein said thermoplastic film is a coextruded thermoplastic film formed by either cast or blown film coextrusion.

28. A vacuum skin package according to claim 26, wherein said thermoplastic film has an unrestrained linear thermal shrinkage in both the machine and transverse directions of less than 15% as measured in accordance with ASTM D-2732 Test Method.

29. A vacuum skin package according to claim 26, wherein said thermoplastic film is a cross-linked thermoplastic film such that at least one polymer layer of said cross-linked thermoplastic film has a gel content of not less than 5% as measured in accordance with ASTM D 2765-01 Test Method.

30. A vacuum skin package according to claim 26, wherein said polyester substrate comprises a material selected from the group consisting of polyethylene terephthalate (PET), crystalline polyethylene terephthalate (CPET), amorphous polyethylene terephthalate (APET), and blends thereof.

31. A vacuum skin package according to claim 26, wherein said oxygen barrier material comprises a material selected from the group consisting of homopolymers or copolymers of ethylene/vinyl alcohol, vinylidene chloride copolymers, and blends thereof.

32. A vacuum skin packaging kit comprising:

(a) a thermoplastic film;

(b) a polyester substrate;

wherein said thermoplastic film comprises at least a first polymer layer, a second polymer layer, a third polymer layer, a fourth polymer layer, a fifth polymer layer, a sixth polymer layer and a seventh polymer layer;

wherein said first layer has a first surface and an opposing second surface, wherein said first surface has a surface tension of between 40-56 dynes/cm as measured in accordance with ASTM D-2578-84 Test Method and comprises ethylene/vinyl acetate copolymer or a blend thereof, wherein said first layer is an exterior film layer and is free of both polybutylene and ionomer resin;

wherein said second layer comprises an ionomer resin or a blend thereof, wherein said second layer adheres to both said first and third layers;

wherein said third layer comprises an adhesive material and adheres to both said second and fourth layers;

wherein said fourth layer comprises either a material selected from the group consisting of polyolefin resin, ionomer resin, and a blend thereof, or an oxygen barrier material, wherein said oxygen barrier material is a polymeric material such that said thermoplastic film has an oxygen transmission rate of between 0-2.0 cc/100 in.²/24 hours at 23°

C. and 0% R.H. as measured in accordance with ASTM D-3985-02 Test Method, wherein said fourth layer is an interior film layer;

wherein said fifth layer comprises an adhesive material and adheres to both said fourth and sixth layers;

wherein said sixth layer comprises a material selected from the group consisting of polyolefin resin, ionomer resin, and blends thereof;

wherein said seventh layer comprises a polyolefin resin or blend thereof, wherein said seventh layer adheres to said sixth layer and is an exterior film layer; and

wherein said thermoplastic film is adapted to form a peelable seal between said first surface of said first polymer layer of said thermoplastic film and said polyester substrate by pressure of less than 1×

10⁵ Pa applied therebetween, wherein said peelable seal has a seal strength of between 0.5-6 lb./in. (0.09-1.08 Kg/cm) as measured in accordance with ASTM F-904 Test Method.

33. A vacuum skin packaging kit according to claim 32, wherein said thermoplastic film is a coextruded thermoplastic film formed by either cast or blown film coextrusion.

34. A vacuum skin packaging kit according to claim 32, wherein said thermoplastic film has an unrestrained linear thermal shrinkage in both the machine and transverse directions of less than 15% as measured in accordance with ASTM D-2732 Test Method.

35. A vacuum skin packaging kit according to claim 32, wherein said thermoplastic film is a cross-linked thermoplastic film such that at least one polymer layer of said cross-linked thermoplastic film has a gel content of not less than 5% as measured in accordance with ASTM D 2765-01 Test Method.

36. A vacuum skin packaging kit according to claim 32, wherein said polyester substrate comprises a material selected from the group consisting of polyethylene terephthalate (PET), crystalline polyethylene terephthalate (CPET), amorphous polyethylene terephthalate (APET), and blends thereof.

37. A vacuum skin packaging kit according to claim 32, wherein said oxygen barrier material comprises a material selected from the group consisting of homopolymers or copolymers of ethylene/vinyl alcohol, vinylidene chloride copolymers, and blends thereof.