Halogen-free fire retardant system for low heat release polymers
First Claim
1. An intumescent fire retardant system for use in polymeric moldings, comprising, on the basis of 100 parts by weight blended mixture of a polymer component comprising:
- 20-45 parts of a polymeric binder comprising high density polyethylene having a density in the range of 0.940-0.970 g/cm3 and an α
-olefin-containing copolymer in the range of 0.870-0.910 g/cm3, wherein the system comprises 20-45 parts of the high density polyethylene and 0-15 parts of the α
-olefin-containing copolymer for a total of 20-45 parts polymeric binder;
5-25 parts of a nitrogenous gas-generating agent selected from the group consisting of amines, ureas, guanidines, guanamines, s-triazines, amino acids, salts thereof, and mixtures thereof, wherein the salts are selected from the group consisting of phosphates, phosphonates, phosphinates, borates, cyanurates, sulfates and mixtures thereof;
10-35 parts of a water vapor-generating agent;
1-5 parts of an antioxidant; and
0-15 parts of a reinforcing agent, wherein the system is essentially halogen-free.
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Abstract
An intumescent fire retardant system for making polymeric moldings that is halogen-free and provides fire shielding, thermal shielding and a low heat release rate. The intumescent fire retardant system of the present invention comprises, on the basis of 100 parts by weight blended mixture, 20-45 parts of a polymeric binder based on high density polyethylene and an α-olefin-containing copolymer, such as linear low density polyethylene, and 5-25 parts of a nitrogenous gas-generating agent, 10-30 parts of a water vapor-generating agent, 1-5 parts of an antioxidant, and 0-15 parts of a reinforcing agent. The fire retardant system of the present invention is essentially halogen-free.
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Citations
19 Claims
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1. An intumescent fire retardant system for use in polymeric moldings, comprising, on the basis of 100 parts by weight blended mixture of a polymer component comprising:
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20-45 parts of a polymeric binder comprising high density polyethylene having a density in the range of 0.940-0.970 g/cm3 and an α
-olefin-containing copolymer in the range of 0.870-0.910 g/cm3, wherein the system comprises 20-45 parts of the high density polyethylene and 0-15 parts of the α
-olefin-containing copolymer for a total of 20-45 parts polymeric binder;
5-25 parts of a nitrogenous gas-generating agent selected from the group consisting of amines, ureas, guanidines, guanamines, s-triazines, amino acids, salts thereof, and mixtures thereof, wherein the salts are selected from the group consisting of phosphates, phosphonates, phosphinates, borates, cyanurates, sulfates and mixtures thereof;
10-35 parts of a water vapor-generating agent;
1-5 parts of an antioxidant; and
0-15 parts of a reinforcing agent, wherein the system is essentially halogen-free. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12)
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13. An intumescent fire retardant system for use in polymeric moldings, comprising, on the basis of 100 parts by weight blended mixture:
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20-45 parts of a polymeric binder comprising high density polyethylene having a density in the range of 0.940-0.970 g/cm3 and an α
-olefin-containing copolymer having a density in the range of 0.870-0.910 g/cm3, wherein 20-45 parts of the blended mixture is the high density polyethylene and 0-15 parts of the blended mixture is the α
-olefin-containing copolymer;
15-25 parts of a nitrogenous gas-generating agent selected from the group consisting of an ammonium salt, a melamine salt, or mixtures thereof, wherein the salts are selected from the group consisting of phosphates, phosphonates, phosphinates, borates, cyanurates, sulfates and mixtures thereof;
20-30 parts of a water vapor-generating agent selected from the group consisting of hydrated magnesia, hydrated alumina, intercalated graphite, and mixtures thereof;
1-5 parts of an antioxidant selected from the group consisting of distearylthiodipropionate, a hindered phenol, and mixtures thereof; and
3-10 parts of a reinforcing agent selected from the group consisting of glass fibers, mica, titanium oxide and mixtures thereof, wherein the system is essentially halogen-free. - View Dependent Claims (14, 15, 16, 17, 18)
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19. An intumescent fire retardant thermoplastic moldable composition comprising, on the basis of 100 parts by weight blended mixture:
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55-80 parts of a thermoplastic matrix; and
20-45 parts of an intumescent fire retardant additive comprising on the basis of 100 parts by weight blended mixture;
20-45 parts of a polymeric binder comprising high density polyethylene having a density in the range of 0.940-0.970 g/cm3 and an α
-olefin-containing copolymer having a density less than the density of the high density polyethylene;
5-25 parts of a nitrogenous gas-generating agent selected from the group consisting of amines, ureas, guanidines, guanamines, s-triazines, amino acids, salts thereof, and mixtures thereof, wherein the salts are selected from the group consisting of phosphates, phosphonates, phosphinates, borates, cyanurates, sulfates, and mixtures thereof;
10-35 parts of a water vapor-generating agent;
1-5 parts of an antioxidant; and
0-15 parts of a reinforcing agent, wherein the thermoplastic polymer matrix and the intumescent fire retardant additive are each essentially halogen-free, and wherein the composition exhibits a peak heat release rate of less than 500 kW/m2 as measured by the ASTM E1354 cone calorimeter method.
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Specification