Fluorescent pattern forming article, recording medium, security medium, and recording method

• US 20060286407A1
• Filed: 06/15/2006
• Published: 12/21/2006
• Est. Priority Date: 06/16/2005
• Status: Abandoned Application

• Current Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Original Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Inventors: Harada, Koichi, Amano, Akio, Iwanaga, Hiroki
• Application Number:
  US11/453,471
• Publication Number:
  US 20060286407A1
• Time in Patent Office: Days
• US Class Current: 428/690
• CPC Class Codes: B32B 2250/24 All layers being polymeric
• CPC Class Codes: B32B 2264/105 Metal
• CPC Class Codes: B32B 2307/416 Reflective
• CPC Class Codes: B32B 2307/422 Luminescent, fluorescent, phosphorescent
• CPC Class Codes: B32B 2429/02 Records or discs
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/308 comprising acrylic (co)polymers
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 27/365 comprising polycarbonates
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: C09K 2211/182 of the rare earth metals, i.e. Sc, Y or lanthanide

Abstract

A fluorescent pattern forming article including a first layer containing a metal ion, and a second layer disposed facing the first layer and containing a ligand coordinating with the metal ion contained in the first layer to thereby enable an intensity of fluorescence based on the metal ion to be changed.

Claims

1. A fluorescent pattern forming article comprising:

a first layer containing a metal ion; and

a second layer disposed facing the first layer and containing a ligand coordinating with the metal ion contained in the first layer to thereby enable an intensity of fluorescence based on the metal ion to be changed.

2. The fluorescent pattern forming article according to claim 1, which further comprises a partitioning layer interposed between the first and second layers for separating these layers from each other.

8. The fluorescent pattern forming article according to claim 1, wherein the first layer and/or the second layer is formed into a pattern.

9. The fluorescent pattern forming article according to claim 8, which further comprises a partitioning layer interposed between the first and second layers for separating these layers from each other, said partitioning layer being formed into a pattern corresponding to at least one of the patterns of the first layer and/or the second layer.

10. The fluorescent pattern forming article according to claim 8, which further comprises a protective layer for covering the first layer and/or the second layer that has been formed into the pattern.

11. The fluorescent pattern forming article according to claim 1, which further comprises a supporting substrate attached respectively to the first layer and/or the second layer.

12. The fluorescent pattern forming article according to claim 1, which further comprises a supporting substrate attached respectively to the first layer and/or the second layer, and a reflective film interposed between the supporting substrate and the first layer and/or the second layer.

13. The fluorescent pattern forming article according to claim 1, which further comprises a transparent substrate attached respectively to one main surface of the first layer and/or the second layer, and a reflective film attached respectively to the other main surface of the first layer and/or the second layer.

15. The fluorescent pattern forming article according to claim 1, wherein the first layer and/or the second layer is substantially transparent to visible light.

16. The fluorescent pattern forming article according to claim 1, which further comprises a partitioning layer interposed between the first and second layers for separating these layers from each other, the partitioning layer being substantially transparent to visible light.

17. The fluorescent pattern forming article according to claim 1, wherein the metal ion is formed of at least one kind of metal selected from the group consisting of rare earth metals, indium, gallium, palladium, platinum, ruthenium, copper, zinc and aluminum.

18. The fluorescent pattern forming article according to claim 1, wherein the metal ion is contained as a metal ion complex in the first layer.

19. The fluorescent pattern forming article according to claim 1, wherein the ligand acts to increase the intensity of fluorescence based on the metal ion as it is coordinated with the metal ion of the first layer, the ligand being at least one kind of compound selected from the group consisting of a phosphine oxide compound, a sulfoxy compound, a carboxylic compound, a carbonyl compound, phenanthroline, bipyridine, and a acetylacetonato compound.

20. The fluorescent pattern forming article according to claim 1, wherein the ligand acts to decrease the intensity of fluorescence based on the metal ion as it is coordinated with the first complex of the first layer, the ligand being at least one compound selected from the group consisting of a hydroxy compound and water.

3. A fluorescent pattern forming article comprising:

a first layer containing a metal ion;

a second layer disposed facing the first layer and containing a ligand coordinating with the metal ion contained in the first layer to thereby enable an intensity of fluorescence based on the metal ion to be increased; and

a third layer interposed between the first and second layers and containing a fluorescent compound having the metal ion and the ligand coordinated with the metal ion, said fluorescent compound being formed into a pattern.

4. The fluorescent pattern forming article according to claim 3, in which a part of the third layer has a function to separate the first layer from the second layer.

5. The fluorescent pattern forming article according to claim 3, wherein the metal ion contained in the first layer and/or the ligand contained in the second layer is capable of diffusing into a region other than the pattern of the fluorescent compound interposed between the first and second layers to thereby enable the intensity of fluorescence based on the metal ion to become homogeneous throughout the entire surface with time.

14. The fluorescent pattern forming article according to claim 3, wherein the fluorescent compound is capable of emitting fluorescence as it is irradiated with ultraviolet rays and is substantially transparent to visible light.

6. A fluorescent pattern forming article comprising:

a first layer containing a first complex having a metal ion and fluorescent properties and functioning as a fluorescent layer;

a second layer disposed facing the first layer and containing a ligand coordinating with the metal ion of the first complex contained in the first layer to thereby enable an intensity of fluorescence based on the metal ion to be decreased; and

a partitioning layer interposed between the first and second layers for separating these layers from each other, said partitioning layer containing a second complex having the ligand coordinated with the metal ion of the first complex, said second complex being formed into a pattern.

7. The fluorescent pattern forming article according to claim 6, wherein the first complex contained in the first layer and/or the ligand contained in the second layer is capable of diffusing into a region other than the pattern of the second complex interposed between the first and second layers to thereby enable the intensity of fluorescence based on the metal ion to become homogeneous throughout the entire surface with time.

21. A recording medium which is capable of recording information as a distribution of fluorescent intensity, the recording medium comprising:

a first layer containing a metal ion; and

a second layer disposed facing the first layer and containing a ligand coordinating with the metal ion contained in the first layer, to thereby enable an intensity of fluorescence based on the metal ion to be changed.

22. A security medium which is capable of recording security information as a distribution of fluorescent intensity, the security medium comprising:

a first layer containing a metal ion; and

a second layer disposed facing the first layer and containing a ligand coordinating with the metal ion contained in the first layer, to thereby enable an intensity of fluorescence based on the metal ion to be changed.

23. A recording method for performing recording of information onto a fluorescent pattern forming article comprising a first layer containing a metal ion;

and a second layer disposed facing the first layer and containing a ligand coordinating with the metal ion contained in the first layer and enabling an intensity of fluorescence based on the metal ion to be changed;

the method comprising;

externally applying at least one kind of energy selected from the group consisting of heat, stress and light to the fluorescent pattern forming article to enable the ligand of the second layer to be coordinated with the metal ion contained in the first layer, thereby changing the intensity of fluorescence to perform the recording of information.