Apparatus and process for optimising the circulation of a suspension in a facility comprising a three-phase reactor

• US 20070014703A1
• Filed: 07/11/2006
• Published: 01/18/2007
• Est. Priority Date: 06/25/2001
• Status: Active Grant

• Current Assignee: Eric Lenglet, Franck Gaviot-Blanc, Jean-Mare Schweitzer
• Original Assignee: Eric Lenglet, Franck Gaviot-Blanc, Jean-Mare Schweitzer
• Inventors: Lenglet, Eric, Schweitzer, Jean-Mare, Gaviot-Blanc, Franck
• Granted Patent: US 7,560,495 B2
• Time in Patent Office: Days
• US Class Current: 422/139
• CPC Class Codes: B01J 2208/00256 in a heat exchanger for the heat exchange medium separate from the reactor
• CPC Class Codes: B01J 2208/003 involving reactant slurries
• CPC Class Codes: B01J 2208/00539 Pressure
• CPC Class Codes: B01J 2208/00548 Flow
• CPC Class Codes: B01J 2219/00247 Fouling of the reactor or the process equipment
• CPC Class Codes: B01J 8/228 externally, i.e. the particles leaving the vessel and subsequently re-entering it
• CPC Class Codes: C10G 2/342 with moving solid catalysts

Abstract

To facilitate operation of a facility for chemical conversion of a feed that comprises a reactor (2) containing a slurry constituted by at least one suspension of at least one solid in a liquid, a gas supply, and a circuit that is external of the reactor, for continuous movement of a slurry stream, wherein the external circuit withdraws slurry from the reactor from at least one point (A) and re-introduces at least a portion of the slurry at at least one other point (B), the facility is further provided with means for stopping circulation of the slurry in the circuit; means for pressurized introduction of at least one fluid for draining the slurry contained in the circuit; and means for circulating the slurry in the external circuit under conditions such that the Reynolds number is more than 2500.

Claims

1. (canceled)

9. A process according to claim 1, wherein said facility further comprises means for condensing at least a portion of the gaseous effluent from said reactor (2), and means (37) for storing at least a portion of the condensed effluent, wherein said storage means (37) is connected to means for introduction of at least one pressurized fluid at point (D) of said circuit.

14. A process for using said facility according to claim 1, wherein said reactor is used to convert or desulphurize residual heavy hydrocarbons, to perform aliphatic alkylation, or to perform oxidation.

11. A process for using a facility comprising at least one reactor (2) containing a slurry comprising at least one suspension of at least one solid in a liquid,

a gas supply located in the lower portion of said reactor,

a circuit (11, 12, 13), external to said reactor, for continuous circulation of a slurry stream, said circuit comprising means for withdrawing said slurry stream from at least one point (A) of said reactor, and means for reintroducing at least a portion of said slurry stream at at least one other point (B) of said reactor, and a separation section (17) for separating at least one fluid contained in said slurry stream traversing the external circuit (11, 12, 13), said facility further comprising:

at least one block valve (14) for stopping circulation of said slurry stream in said circuit (11, 12, 13);

means for introduction of at least one pressurized fluid at at least one point (D) of said circuit for draining slurry contained in said circuit;

means (16) for circulating said slurry in said external circuit under conditions such that the Reynolds number is more than 2500 at every point in said external circuit (11, 12, 13), said process comprising;

introducing said at least one pressurized fluid introduced at at least one point (D) of said circuit for draining slurry, wherein said at least one pressurized fluid at least partially comprises at least one of the reaction fluids.

2. A process according to claim 11, in which said at least one point (D) is between said at least one block valve (14) for stopping circulation of the slurry and said separation section (17).

3. A process according to claim 11, wherein said means for introduction of at least one pressurized fluid is connected to a source of pressurized gas.

4. A process according to claim 11, wherein said means for introduction of at least one pressurized fluid is connected to a source of pressurized liquid.

5. A process according to claim 11, wherein said means for introduction of at least one pressurized fluid at at least one introduction point (D) is connected to a source of at least one pressurized fluid which is substantially free of solid in suspension and is at a pressure higher than that of point (D);

and

a free volume (5) is provided in the upper portion of the reactor (2) above the liquid/solid suspension, said free volume being greater than the total volume of the liquid/solid suspension contained in the circuit and in the separation section (17).

6. A process according to claim 5, wherein said facility further comprises means for detecting at least one operational defect in said facility connected to means (50) for controlling closure of the block valve (14) and for controlling opening of at least one valve (41, 42, 43) said circuit into communication with said source of pressurized fluid which is substantially free of solid in suspension.

7. A process according to claim 11, wherein said reactor (2) further comprises:

means (6) for injecting said reactive gas at a plurality of points; and

means for suspending and agitating the slurry in the reactor to avoid deposition of solid in the reactor (2) above the gas injection points.

8. A process according to claim 11, wherein said means (16) for circulating slurry in said external circuit is of a size so that said Reynolds number of the slurry is in the range 2500 to 500000 at every point in said external circuit.

10. A process according to claim 11, wherein said solid in suspension is a reaction catalyst, and said pressurized fluid is a fluid that is chemically compatible with the catalyst.

13. A process according to claim 11, wherein the freezing point of said at least one pressurized fluid is lower than that of the liquid phase contained in the slurry.

16. A process according to claim 5, wherein said means for introduction of at least one pressurized fluid introduces pressurized fluid at point (D) and point (C) of said circuit, wherein point (D) is downstream of said block valve (14) and point (C) is upstream of said block valve.

18. A process according to claim 11, wherein said facility further comprising a line for removing gaseous effluent from said reactor, a heat exchanger for condensing at least a portion of the gaseous effluent removed from said reactor, a first separation drum connected to said heat exchanger for separating a gas phase, a first liquid phase, and a second liquid phase from said gaseous effluent, and a line connecting said first separation drum to a second separation drum for delivering said second liquid phase to said second separation drum.

19. A process according to claim 18, wherein said means for introduction of at least one pressurized fluid at at least one point (D) of said circuit comprises a line for removing a gaseous phase from said second separation drum which is connected to said circuit at point (D), and point (D) is positioned between said at least one block valve (14) and said separation section.

20. A process according to claim 19, wherein said means for introduction of at least one pressurized fluid at at least one point (D) of said circuit further comprises a line for removing a liquid phase from said second separation drum which is connected to said circuit at point (C), and point (C) is positioned between said means for withdrawing said slurry stream from at least one point (A) of said reactor and said separation section.

21. A process according to claim 19, wherein said means for introduction of at least one pressurized fluid at at least one point (D) of said circuit further comprises a line for removing a liquid phase from said second separation drum which is connected to said line for removing a gaseous phase from said second separation drum which is connected to said circuit at point (D).

22. A process according to claim 20, wherein said means for introduction of at least one pressurized fluid at least one point (D) of said circuit further comprises a line connected to said line for removing a liquid phase from said second separation drum which is connected to said line for removing a gaseous phase from said second separation drum which is connected to said circuit at point (D).

23. A process according to claim 11, wherein said means (16) for circulating said slurry in said external circuit is positioned between said separation section and said means for reintroducing at least a portion of said slurry stream at point (B) of said reactor.

24. A process according to claim 11,

wherein said means for introduction of at least one pressurized fluid at at least one introduction point (D) is connected to a source of at least one pressurized fluid which is substantially free of solid in suspension and is at a pressure higher than that of point (D);

and

a free volume (5) is provided in the upper portion of the reactor (2) above the liquid/solid suspension, said free volume being greater than the total volume of the liquid/solid suspension contained in the circuit and in the separation section (17); and

said facility further comprising means for detecting at least one operational defect in said facility connected to means (50) for obtaining automatic immediate closure of said block valve (14), when said at least one operational defect is detected, and for subsequently automatically introducing pressurized fluid substantially free of solid in suspension by opening of at least one valve (41, 42, 43) thereby placing said circuit into communication with said source of pressurized fluid which is substantially free of solid in suspension via said means for introduction of at least one pressurized fluid at at least one point (D).

12. A process for using a facility comprising at least one reactor (2) containing a slurry comprising at least one suspension of at least one solid in a liquid,

a gas supply located in the lower portion of said reactor,

a circuit (11, 12, 13), to said reactor, for continuous circulation of a slurry stream, said circuit comprising means for withdrawing said slurry stream from at least one point (A) of said reactor, and means for reintroducing at least a portion of said slurry stream at at least one other point (B) of said reactor, and a separation section (17) for separating at least one fluid contained in said slurry stream traversing the external circuit (11, 12, 13), said facility further comprising:

at least one block valve (14) for stopping circulation of said slurry stream in said circuit (11, 12, 13);

means for introduction of at least one pressurized fluid at at least one point (D) of said circuit for draining slurry contained in said circuit;

means (16) for circulating said slurry in said external circuit under conditions such that the Reynolds number is more than 2500 at every point in said external circuit (11, 12, 13), said process comprising;

introducing said at least one pressurized fluid introduced at at least one point (D) of said circuit for draining slurry, wherein said at least one pressurized fluid is at least one fluid selected from the group formed by nitrogen, hydrogen, carbon monoxide, liquid or vaporized hydrocarbons principally comprising compounds containing less than 20 carbon atoms, and mixtures formed completely or partially from said different fluids.

15. A process according to claim 12, wherein the freezing point of said at least one pressurized fluid is lower than that of the liquid phase contained in the slurry.

17. A process according to claim 15, wherein said means for introduction points (D) and (C) are positioned at a distance from said block valve such that pressurized fluid introduced into the circuit at these points will permit at least 80% of the horizontal or slightly inclined potions of the circuit to be flushed.

25. A process for draining the external circuit of a facility comprising

at least one reactor (2) containing a slurry comprising at least one suspension of at least one solid in a liquid,

a gas supply located in the lower portion of said reactor,

a circuit (11, 12, 13), to said reactor, for continuous circulation of a slurry stream, said circuit comprising means for withdrawing said slurry stream from at least one point (A) of said reactor, and means for reintroducing at least a portion of said slurry stream at at least one other point (B) of said reactor, and a separation section (17) for separating at least one fluid contained in said slurry stream traversing the external circuit (11, 12, 13),

said facility further comprising:

at least one block valve (14) for stopping circulation of said slurry stream in said circuit (11, 12, 13);

means for introduction of at least one pressurized fluid at at least one point (D) of said circuit for draining slurry contained in said circuit;

means (16) for circulating said slurry in said external circuit under conditions such that the Reynolds number is more than 2500 at every point in said external circuit (11, 12, 13);

said process comprising;

closing said block valve and introducing at least one pressurized fluid at point (D) of said circuit to drain slurry contained in said circuit into said reactor at point (B),

wherein said at least one pressurized fluid is at least a fraction of at least one of the reaction fluids or obtained from an external source of at least one fluid selected from the group formed by nitrogen, hydrogen, carbon monoxide, liquid or vaporized hydrocarbons principally comprising compounds containing less than 20 carbon atoms, and mixtures formed completely or partially from said different fluids.

26. A process for draining the external circuit of a facility comprising:

at least one reactor (2) containing a slurry comprising at least one suspension of at least one solid in a liquid;

a gas supply located in the lower portion of said reactor; and

a circuit (11, 12, 13), external to said reactor, for continuous circulation of a slurry stream, said circuit comprising;

a line for withdrawing said slurry stream from at least one point (A) of said reactor,

at least one block valve (14) on said circuit downstream of point (A) for stopping circulation of said slurry stream in said circuit,

means for introduction of at least one pressurized fluid at at least one point (D) of said circuit, said point (D) being downstream of said block valve,

a separation section (17), downstream of said point (D), for separating at least one fluid contained in said slurry stream traversing the external circuit,

a line for reintroducing at least a portion of said slurry stream at at least one other point (B) of said reactor, wherein point (B) is below point (A), and means (16),

downstream of said separation section (17) and upstream of point (B), for circulating said slurry in said external circuit from point (A) to point (B) under conditions such that the Reynolds number is more than 2500 at every point in said external circuit (11, 12, 13),

wherein said means for introduction of at least one pressurized fluid at at least one introduction point (D) is connected to a source of at least one pressurized fluid which is substantially free of solid in suspension and is at a pressure higher than that of point (D); and

a free volume (5) is provided in the upper portion of the reactor (2) above the liquid/solid suspension, said free volume being greater than the total volume of the liquid/solid suspension contained in the circuit and in the separation section (17),

said facility further comprising means for detecting at least one operational defect in said facility connected to means (50) for obtaining automatic immediate closure of said block valve (14), when said at least one operational defect is detected, and for subsequently automatically introducing pressurized fluid substantially free of solid in suspension by opening of at least one valve (41, 42, 43) thereby placing said circuit into communication with said source of pressurized fluid which is substantially free of solid in suspension via said means for introduction of at least one pressurized fluid at at least one point (D);

said process comprising;

closing said block valve and introducing at least one pressurized fluid at point (D) of said circuit to drain slurry contained in said circuit into said reactor at point (B),

wherein said at least one pressurized fluid is at least a fraction of at least one of the reaction fluids or obtained from an external source of at least one fluid selected from the group formed by nitrogen, hydrogen, carbon monoxide, liquid or vaporized hydrocarbons principally comprising compounds containing less than 20 carbon atoms, and mixtures formed completely or partially from said different fluids.