THIN-FILM BATTERIES WITH POLYMER AND LiPON ELECTROLYTE LAYERS AND METHOD
First Claim
1. An apparatus comprising:
- a first battery cell having a negative electrode, a positive electrode, and an electrolyte structure, wherein the negative electrode includes a LiPON layer covering at least a portion of the negative electrode;
the positive electrode includes a cathode material and a LiPON layer covering at least a portion of the positive electrode; and
the electrolyte structure includes a polymer electrolyte material sandwiched between the LiPON layer of the negative electrode and the LiPON layer of the positive electrode.
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Accused Products
Abstract
A method and apparatus for making thin-film batteries having composite multi-layered electrolytes with soft electrolyte between hard electrolyte covering the negative and/or positive electrode, and the resulting batteries. In some embodiments, foil-core cathode sheets each having a cathode material (e.g., LiCoO2) covered by a hard electrolyte on both sides, and foil-core anode sheets having an anode material (e.g., lithium metal) covered by a hard electrolyte on both sides, are laminated using a soft (e.g., polymer gel) electrolyte sandwiched between alternating cathode and anode sheets. A hard glass-like electrolyte layer obtains a smooth hard positive-electrode lithium-metal layer upon charging, but when very thin, have randomly spaced pinholes/defects. When the hard layers are formed on both the positive and negative electrodes, one electrode'"'"'s dendrite-short-causing defects on are not aligned with the other electrode'"'"'s defects. The soft electrolyte layer both conducts ions across the gap between hard electrolyte layers and fills pinholes.
208 Citations
31 Claims
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1. An apparatus comprising:
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a first battery cell having a negative electrode, a positive electrode, and an electrolyte structure, wherein the negative electrode includes a LiPON layer covering at least a portion of the negative electrode;
the positive electrode includes a cathode material and a LiPON layer covering at least a portion of the positive electrode; and
the electrolyte structure includes a polymer electrolyte material sandwiched between the LiPON layer of the negative electrode and the LiPON layer of the positive electrode. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17)
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18. A method comprising:
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providing a first sheet that includes an anode material and a LiPON layer covering the anode material;
providing a second sheet that includes a cathode material that includes lithium and a LiPON layer covering the cathode material; and
sandwiching a polymer electrolyte material between the LiPON layer covering the anode material of the first sheet and the LiPON layer covering the cathode material of the first cathode sheet. - View Dependent Claims (19, 20, 21, 22, 23, 24)
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25. An apparatus comprising:
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a first sheet that includes a LiPON layer covering a first face of the first sheet;
a second sheet that includes a cathode material that includes lithium and a LiPON layer covering the cathode material on a second face of the second sheet; and
means for passing lithium ions between the LiPON layer on the first face of the first sheet and the LiPON layer on the second face of the second sheet to form a first battery cell. - View Dependent Claims (26, 27, 28, 29, 30, 31)
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Specification