Gas separation method and apparatus using partial pressure swing adsorption

• US 20070017368A1
• Filed: 07/25/2005
• Published: 01/25/2007
• Est. Priority Date: 07/25/2005
• Status: Abandoned Application

• Current Assignee: Bloom Energy Corporation
• Original Assignee: Bloom Energy Corporation
• Inventors: Finn, John, McElroy, James, Levan, M.
• Application Number:
  US11/188,118
• Publication Number:
  US 20070017368A1
• Time in Patent Office: Days
• US Class Current: 95/96
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2256/16 Hydrogen
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/80 Water
• CPC Class Codes: B01D 2258/0208 from fuel cells
• CPC Class Codes: B01D 2259/40003 Methods relating to valve switching
• CPC Class Codes: B01D 2259/40056 Gases other than recycled product or process gas
• CPC Class Codes: B01D 2259/4006 Less than four
• CPC Class Codes: B01D 2259/40062 Four
• CPC Class Codes: B01D 2259/40081 Counter-current
• CPC Class Codes: B01D 2259/40086 by using a purge gas B01D2259/4009 takes precedence
• CPC Class Codes: B01D 2259/402 using two beds
• CPC Class Codes: B01D 53/0462 Temperature swing adsorption
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: B01D 53/261 by adsorption
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 2008/147 Fuel cells with molten carbonates
• CPC Class Codes: H01M 8/04014 Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
• CPC Class Codes: H01M 8/04089 of gaseous reactants
• CPC Class Codes: H01M 8/04097 with recycling of the reactants H01M8/04119, H01M8/04104 take precedence
• CPC Class Codes: H01M 8/04141 : by water containing exhaust gases
• CPC Class Codes: H01M 8/04164 : by condensers, gas-liquid separators or filters
• CPC Class Codes: H01M 8/0625 : in a modular combined reactor/fuel cell structure
• CPC Class Codes: H01M 8/0662 : Treatment of gaseous reactants or gaseous residues, e.g. cleaning
• CPC Class Codes: H01M 8/0668 : Removal of carbon monoxide or carbon dioxide
• CPC Class Codes: Y02C 20/40 : of CO2
• CPC Class Codes: Y02E 60/50 : Fuel cells

Abstract

A four-step partial pressure swing adsorption method and apparatus is provided for gas separation, such as for recovering fuel from the fuel exhaust of a fuel cell stack.

Claims

1. A gas separation method, comprising:

(a) a first feed/purge step comprising;

providing a feed gas inlet stream into a first adsorbent bed;

collecting a feed gas outlet stream comprising at least one separated component of the feed gas at a first output;

providing a purge gas inlet stream into a second adsorbent bed; and

collecting a purge gas outlet stream at a second output;

(b) a first flush step, conducted after the first feed/purge step, the first flush step comprising;

providing the purge gas inlet stream into the first adsorbent bed;

collecting the purge gas outlet stream, which comprises at least one component of the feed gas that was trapped in a void volume of the first adsorbent bed, at the first output;

providing the feed gas inlet stream into the second adsorbent bed; and

collecting the feed gas outlet stream, which comprises a portion of the purge gas that was trapped in a void volume of the second bed, at an output different from the first output;

(c) a second feed/purge step, conducted after the first flush step, the second feed/purge step comprising;

providing the feed gas inlet stream into the second adsorbent bed;

collecting the feed gas outlet stream comprising at least one separated component of the feed gas at the first output;

providing the purge gas inlet stream into the first adsorbent bed; and

collecting the purge gas outlet stream at an output different from the first output;

(d) a second flush step, conducted after the second feed/purge step, the second flush step comprising;

providing the purge gas inlet stream into the second adsorbent bed;

collecting the purge gas outlet stream, which comprises at least one component of the feed gas that was trapped in a void volume of the second adsorbent bed, at the first output;

providing the feed gas inlet stream into the first adsorbent bed; and

collecting a feed gas outlet stream, which comprises a portion of the purge gas that was trapped in a void volume of the first bed, at an output different from the first output.

2. The method of claim 1, wherein:

in the first and the second flush steps, the feed gas outlet stream is collected at the second output; and

in the second feed/purge step, the purge gas outlet stream is collected at the second output.

3. The method of claim 2, wherein:

the first output comprises a first conduit into which a desired separated component of the feed gas is provided, and the second output comprises a second conduit different from the first conduit; and

a duration of the first and the second feed/purge steps is at least five times as long as a duration of the first and the second flush steps.

4. The method of claim 3, wherein:

the feed gas inlet stream is provided in each of the first and the second adsorbent beds in a first direction in steps (a), (b), (c) and (d);

in the first and the second feed/purge steps, the purge gas inlet stream is provided into each of the first and the second adsorbent beds in a different direction from the first direction; and

in the first and the second flush steps, the purge gas inlet stream is provided into each of the first and the second adsorbent beds in the first direction.

5. The method of claim 3, further comprising repeating steps (a), (b), (c) and (d), in this order, a plurality of times.

6. The method of claim 2, wherein:

the feed gas inlet stream comprises hydrogen and carbon dioxide;

the purge gas inlet stream comprises air having a 50% or less relative humidity;

the at least one separated component which is collected at the first output comprises hydrogen;

at least a majority of the carbon dioxide in the feed gas inlet stream is adsorbed by the first and the second adsorbent beds during the first and the second feed/purge steps, respectively;

the adsorbed carbon dioxide is removed from the first and the second adsorbent beds by the purge gas inlet stream, during the second and the first feed/purge steps, respectively; and

the removed carbon dioxide is collected with the purge gas outlet stream at the second output during the second and the first feed/purge steps.

7. The method of claim 6, wherein:

the feed gas inlet stream further comprises carbon monoxide and water vapor;

the carbon monoxide is collected together with the hydrogen at the first output;

a portion of the water vapor in the feed gas inlet stream is adsorbed by the first and the second adsorbent beds during the first and the second feed/purge steps, respectively;

the adsorbed water vapor is removed from the first and the second adsorbent beds by the purge gas inlet stream during the second and the first feed/purge steps, respectively; and

the removed water vapor is collected with the purge gas outlet stream at the second output during the second and the first feed/purge steps.

8. The method of claim 7, wherein:

the feed gas inlet stream is not pressurized prior to being provided into the first and the second adsorbent beds;

a duration of the first and the second feed/purge steps is at least five times as long as a duration of the first and the second flush steps; and

the adsorbent material of the first and the second adsorbent beds is selected from zeolite, activated carbon, silica gel or activated alumina.

9. The method of claim 8, wherein the feed gas inlet stream comprises at least a portion of a fuel exhaust stream from a solid oxide fuel cell stack.

10. The method of claim 9, further comprising providing the hydrogen and carbon monoxide from the first output into a fuel inlet stream being provided into the solid oxide fuel cell stack.

11. The method of claim 10, further comprising:

separating the fuel exhaust stream from the solid oxide fuel cell stack into at least two streams prior to modifying a composition of the fuel exhaust stream;

recycling a first fuel exhaust stream into the fuel inlet stream being provided into the solid oxide fuel cell stack; and

providing the second fuel exhaust stream into the first and the second adsorbent beds as the feed gas stream.

12. The method of claim 10, wherein:

the steps (a), (b), (c) and (d) are conducted without external heating of the adsorbent beds;

the adsorbent material of the first and the second adsorbent beds comprises activated carbon; and

the purge gas inlet stream comprises dried air of 50% or less relative humidity which has been dried using third and fourth adsorbent beds.

13. A gas separation apparatus, comprising:

a first means for providing a feed gas inlet stream;

a second means for providing a purge gas inlet stream;

a third means for collecting at least one separated component of the feed gas;

a fourth means for;

(a) receiving the feed gas inlet stream from the first means and for providing at least one separated component of the feed gas to the third means in a first feed/purge step;

(b) receiving the purge gas inlet stream from the second means and for providing a purge gas outlet stream, which comprises at least one component of the feed gas that was trapped in a void volume of the fourth means, to the third means in a first flush step, conducted after the first feed/purge step;

(c) receiving a purge gas inlet stream from the second means and for providing a purge gas outlet stream to an output different from the third means in a second feed/purge step, conducted after the first flush step; and

(d) receiving the feed gas inlet stream from the first means and for providing a feed gas outlet stream, which comprises a portion of the purge gas that was trapped in a void volume of the fourth means, to at an output different from the third means, in a second flush step, conducted after the second feed/purge step; and

a fifth means for;

(a) receiving a purge gas inlet stream from the second means and for providing a purge gas outlet stream to at an output different from the third means in a first feed/purge step;

(b) receiving the feed gas inlet stream from the first means and for providing the feed gas outlet stream, which comprises a portion of the purge gas that was trapped in a void volume of the fifth means, to an output different from the third means in a first flush step, conducted after the first feed/purge step;

(c) receiving the feed gas inlet stream from the first means and for providing the feed gas outlet stream comprising at least one separated component of the feed gas to the third means in a second feed/purge step, conducted after the first flush step; and

(d) receiving the purge gas inlet stream from the second means and for providing the purge gas outlet stream, which comprises at least one component of the feed gas that was trapped in a void volume of the fifth means to the third means in a second flush step, conducted after the second feed/purge step.

14. The apparatus of claim 13, wherein:

the first means is a means for providing the feed gas inlet stream into the fourth and the fifth means in a first direction;

the second means is a means for providing the purge gas inlet stream into each of the fourth and fifth means in a different direction from the first direction during the first and the second feed/purge steps, and for providing the purge gas inlet stream into the fourth and the fifth means in the first direction during the first and the second flush steps.

15. The apparatus of claim 13, wherein the first means is a means for providing the feed gas inlet stream into the fourth means and the fifth means, respectively, during the first and the second feed/purge steps, respectively, for at least five times as long as during the second and the first flush steps, respectively.

16. The apparatus of claim 13, further comprising a sixth means for collecting the feed gas outlet stream in the first and the second flush steps and for collecting the purge gas outlet stream in the first and the second feed/purge steps.

17. The apparatus of claim 16, wherein:

the first means is a means for providing the feed gas inlet stream comprising hydrogen and carbon dioxide;

the second means is a means for providing a purge gas inlet stream comprising air having a 50% or less relative humidity;

the third means is a means for collecting hydrogen;

the fourth means is a means for adsorbing at least a majority of the carbon dioxide in the feed gas inlet stream during the first feed/purge step, and for desorbing the adsorbed carbon dioxide by the purge gas inlet stream during the second feed/purge step;

the fifth means is a means for adsorbing at least a majority of the carbon dioxide in the feed gas inlet stream during the second feed/purge step, and for desorbing the adsorbed carbon dioxide by the purge gas inlet stream, during the first feed/purge step; and

the sixth means is a means for collecting the carbon dioxide removed during the first and the second feed/purge steps.

18. The apparatus of claim 17, wherein:

the first means is a means for providing the feed gas inlet stream comprising hydrogen, carbon dioxide, carbon monoxide and water vapor;

the third means is a means for collecting hydrogen and carbon monoxide;

the fourth means is a means for adsorbing at least a majority of the carbon dioxide and a portion of the water vapor in an unpressurized feed gas inlet stream during the first feed/purge step, and for desorbing the adsorbed carbon dioxide and water vapor by the purge gas inlet stream during the second feed/purge step;

the fifth means is a means for adsorbing at least a majority of the carbon dioxide and a portion of the water vapor in the unpressurized feed gas inlet stream during the second feed/purge step, and for desorbing the adsorbed carbon dioxide and water vapor by the purge gas inlet stream, during the first feed/purge step;

the sixth means is a means for collecting the carbon dioxide and water vapor removed during the first and the second feed/purge steps.

19. The apparatus of claim 18, wherein the first means is a means for providing the feed gas inlet stream from at least a portion of a fuel exhaust stream from a solid oxide fuel cell stack.

20. The apparatus of claim 19, wherein the third means is a means for providing the hydrogen and carbon monoxide into fuel inlet stream being provided into the solid oxide fuel cell stack.

21. The apparatus of claim 20, further comprising:

a seventh means for separating the fuel exhaust stream from the solid oxide fuel cell stack into at least two streams, wherein the first fuel exhaust stream is provided into the first means; and

an eighth means for recycling a second fuel exhaust stream into the fuel inlet stream being provided into the solid oxide fuel cell stack.

22. A gas separation apparatus, comprising:

a first conduit which in operation provides a feed gas inlet stream;

a second conduit which in operation provides a purge gas inlet stream;

a third conduit which in operation collects at least one separated component of the feed gas;

a first adsorbent bed which in operation performs the following functions;

(a) receives the feed gas inlet stream from the first conduit and provides at least one separated component of the feed gas to the third conduit in a first feed/purge step;

(b) receives the purge gas inlet stream from the second conduit and provides a purge gas outlet stream, which comprises at least one component of the feed gas that was trapped in a void volume of the first bed to the third conduit in a first flush step, conducted after the first feed/purge step;

(c) receives a purge gas inlet stream from the second conduit and provides a purge gas outlet stream to an output different from the third conduit in a second feed/purge step, conducted after the first flush step; and

(d) receives the feed gas inlet stream from the first conduit and provides a feed gas outlet stream, which comprises a portion of the purge gas that was trapped in a void volume of the first bed, to at an output different from the third conduit in a second flush step, conducted after the second feed/purge step; and

a second adsorbent bed which in operation performs the following functions;

(a) receives a purge gas inlet stream from the second conduit and provides a purge gas outlet stream to at an output different from the third conduit in a first feed/purge step;

(b) receives the feed gas inlet stream from the first conduit and provides the feed gas outlet stream, which comprises a portion of the purge gas that was trapped in a void volume of the second bed, to an output different from the third conduit in a first flush step, conducted after the first feed/purge step;

(c) receives the feed gas inlet stream from the first conduit and provides the feed gas outlet stream comprising at least one separated component of the feed gas to the third conduit in a second feed/purge step, conducted after the first flush step; and

(d) receives the purge gas inlet stream from the second conduit and provides the purge gas outlet stream, which comprises at least one component of the feed gas that was trapped in a void volume of the second bed to the third conduit in a second flush step, conducted after the second feed/purge step.

23. The apparatus of claim 22, wherein:

the first conduit is operatively connected to the first and the second beds to provide the feed gas inlet stream into the first and the second beds in a first direction;

the second conduit is operatively connected to the first and the second bed through a plurality of valves such that the purge gas inlet stream is provided into each of the first and the second beds in a different direction from the first direction during the first and the second feed/purge steps, and the purge gas inlet stream is provided into the first and the second beds in the first direction during the first and the second flush steps.

24. The apparatus of claim 23, further comprising a fourth conduit which in operation collects the feed gas outlet stream in the first and the second flush steps and which collects the purge gas outlet stream in the first and the second feed/purge steps, depending on a positioning of the plurality of the valves.

25. The apparatus of claim 22, wherein:

the first conduit comprises a hydrogen, carbon dioxide, carbon monoxide and water vapor conduit;

the second conduit comprises a dry air conduit;

the third conduit is hydrogen and carbon monoxide removal conduit; and

the fourth conduit is a carbon dioxide and water vapor removal conduit.

26. The apparatus of claim 25, wherein the first conduit is operatively connected a fuel exhaust from a solid oxide fuel cell stack.

27. The apparatus of claim 26, wherein the third conduit is operatively connected to a fuel inlet of the solid oxide fuel cell stack.

28. The apparatus of claim 27, further comprising:

a first valve comprising an inlet operatively connected to a fuel exhaust conduit from the solid oxide fuel cell stack, a first outlet operatively connected to the first conduit and a second outlet operatively connected to a fuel inlet of the solid oxide fuel cell stack;

a blower or compressor operatively connected to the first valve and to the fuel inlet of the solid oxide fuel cell stack, which in operation controllably provides a desired amount of a fuel exhaust stream to the fuel inlet of the solid oxide fuel cell stack; and

at least one heat exchanger which is located between the fuel exhaust of the solid oxide fuel cell stack and the blower or compressor, which in operation lowers a temperature of the fuel exhaust stream to a temperature suitable for being provided into the blower or compressor.

29. The apparatus of claim 22, further comprising third and fourth adsorbent beds operatively connected to the second conduit, which in operation provide a dried air purge gas into the second conduit.