Method of microwave processing ceramics and microwave hybrid heating system for same

• US 20070023971A1
• Filed: 09/01/2004
• Published: 02/01/2007
• Est. Priority Date: 09/01/2004
• Status: Abandoned Application

• Current Assignee: Alfred University
• Original Assignee: Alfred University
• Inventors: Saha, Subrata, Mohan V.C., Ram, Delregno, Gary
• Application Number:
  US10/570,940
• Publication Number:
  US 20070023971A1
• Time in Patent Office: Days
• US Class Current: 264/432
• CPC Class Codes: A61C 13/203 using microwave energy
• CPC Class Codes: C03C 23/007 by thermal treatment
• CPC Class Codes: C04B 2235/3246 Stabilised zirconias, e.g. YSZ or cerium stabilised zirconia
• CPC Class Codes: C04B 2235/604 Pressing at temperatures other than sintering temperatures
• CPC Class Codes: C04B 2235/656 characterised by specific heating conditions during heat treatment
• CPC Class Codes: C04B 2235/6562 Heating rate
• CPC Class Codes: C04B 2235/6565 Cooling rate
• CPC Class Codes: C04B 2235/6567 Treatment time
• CPC Class Codes: C04B 2235/667 Sintering using wave energy, e.g. microwave sintering
• CPC Class Codes: C04B 2235/77 Density
• CPC Class Codes: C04B 2235/782 Grain size distributions
• CPC Class Codes: C04B 2235/785 Submicron sized grains, i.e. from 0,1 to 1 micron
• CPC Class Codes: C04B 2235/94 Products characterised by their shape
• CPC Class Codes: C04B 2235/95 Products characterised by their size, e.g. microceramics
• CPC Class Codes: C04B 2235/96 Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
• CPC Class Codes: C04B 35/486 Fine ceramics
• CPC Class Codes: C04B 35/64 Burning or sintering processes C04B33/32 takes precedence ; powder metallurgy B22F
• CPC Class Codes: F27B 17/025 for dental workpieces
• CPC Class Codes: H05B 2206/046 Microwave drying of wood, ink, food, ceramic, sintering of ceramic, clothes, hair
• CPC Class Codes: H05B 6/80 Apparatus for specific applications stoves or ranges F24C7/02

Abstract

A method for sintering ceramic materials using a microwave hybrid heating system includes the steps of providing a ceramic member to be sintered, providing a microwave furnace, providing a thermal containment box comprising a material that is virtually transparent to microwave energy, providing at least one susceptor comprising a material that directly couples to microwave energy at room temperature substantially immediately within the thermal containment box, positioning the ceramic member within the thermal containment chamber proximate the susceptor, and irradiating the thermal containment box with microwave energy. The susceptor couples to the microwave energy and generates heat within the thermal containment box and the temperature of the ceramic member increases to the microwave coupling-trigger temperature, at which time the ceramic member couples directly to the microwave energy and is directly sintered by the microwave energy in cooperation with radiant energy from the one susceptor.

Claims

1. A method for sintering ceramic materials at a sintering temperature greater than room temperature using a microwave hybrid heating system, said method comprising the steps of:

(a) providing a ceramic member to be sintered, said ceramic member comprising a material that does not substantially reflect microwave energy and that does not substantially couple to microwave energy until said ceramic material is heated to a microwave coupling-trigger temperature;

(b) providing a microwave furnace having a magnetron microwave source and a microwave chamber lined with a reflective material;

(c) providing a thermal containment box having an inner surface and an outer surface defining a thermal containment chamber, said thermal containment box comprising an insulative material that does not substantially absorb or reflect microwave energy at any temperature less than or equal to a maximum sintering temperature of said ceramic member to be sintered and which has a melting temperature that is greater than said maximum sintering temperature of said ceramic member to be sintered;

(d) providing at least one susceptor within said thermal containment chamber, said at least one susceptor comprising a material that directly couples to microwave energy at room temperature substantially immediately;

(e) positioning said ceramic member within said thermal containment chamber proximate said at least one susceptor;

(f) irradiating said microwave chamber with microwave energy from said magnetron source, whereby said at least one susceptor substantially immediately couples to the microwave energy and the heat from said at least one susceptor radiates therefrom to heat said thermal containment chamber and said ceramic member positioned therewithin such that the temperature of said ceramic member increases to said microwave coupling-trigger temperature, at which time said ceramic member couples directly to the microwave energy; and

(g) sintering said ceramic member with the microwave energy in cooperation with the radiant energy from said at least one susceptor.

2. The method of claim 1, wherein said at least one susceptor has a microwave reflecting temperature that is greater than or substantially equal to said microwave coupling-trigger temperature of said ceramic member.

3. The method of claim 1, wherein said at least one susceptor comprises at least one primary susceptor and at least one secondary susceptor.

4. The method of claim 3, wherein said at least one primary susceptor has a microwave reflecting temperature that is less than or substantially equal to said coupling temperature of said ceramic member.

5. The method of claim 4, wherein said at least one secondary susceptor has a microwave coupling-trigger temperature that is higher than room temperature and lower than said microwave reflecting temperature of said at least one primary susceptor.

6. The method of claim 3, wherein said at least one primary susceptor and said at least one secondary susceptor each have a melting temperature that is greater than a maximum sintering temperature of said ceramic member.

7. The method of claim 1, wherein said at least one susceptor comprises SiC and said ceramic member comprises zirconia stabilized with about 3 mol % yttria.

8. The method of claim 3, wherein said at least one primary susceptor comprises SiC and said at least one secondary susceptor comprises a zirconia ceramic.

9. The method of claim 1, wherein said at least one ceramic member comprises a green dental ceramic material.

10. The method of claim 1, wherein said at least one ceramic member comprises a sintered dental ceramic material that is coated with one or more layers of a dental enamel material or a glass-ceramic material.

11. The method of claim 9, wherein said green dental ceramic material is Y-TZP.

12. The method of claim 10, wherein said sintered dental ceramic material is Y-TZP.

13. A microwave hybrid heating system for sintering at least one ceramic member having a microwave coupling-trigger temperature greater than room temperature, said microwave hybrid heating system comprising:

a microwave furnace having a magnetron microwave source and a microwave chamber lined with a reflective material;

a thermal containment box having an inner surface and an outer surface defining a thermal containment chamber, said thermal containment box comprising an insulative material that does not substantially absorb or reflect microwave energy at any temperature less than a maximum sintering temperature of said at least one ceramic member to be sintered and which has a melting temperature greater than said maximum sintering temperature of said at least one ceramic member to be sintered; and

at least one susceptor provided within said thermal containment chamber, said at least one susceptor comprising a material that directly couples to microwave energy at room temperature substantially immediately;

wherein said at least one ceramic member to be sintered is positioned within said thermal containment chamber such that when microwave energy from said magnetron source irradiates said thermal containment box, said at least one susceptor substantially immediately couples to the microwave energy, heat generated from said at least one susceptor radiates therefrom to heat said thermal containment chamber and said at least one ceramic member positioned therein such that the temperature of said at least one ceramic member increases to said microwave coupling-trigger temperature, at which time said at least one ceramic member couples directly to the microwave energy and is sintered by the microwave energy in cooperation with the radiant heat emitted from said at least one susceptor.

14. The microwave hybrid heating system of claim 13, wherein said at least one susceptor has a microwave reflecting temperature greater than or substantially equal to said microwave coupling-trigger temperature of said at least one ceramic member.

15. The microwave hybrid heating system of claim 13, wherein said at least one susceptor comprises at least one primary susceptor and at least one secondary susceptor.

16. The microwave hybrid heating system of claim 15, wherein said at least one primary susceptor has a microwave reflecting temperature less than or substantially equal to said microwave coupling-trigger temperature of said at least one ceramic member.

17. The microwave hybrid heating system of claim 16, wherein said at least one secondary susceptor has a couple triggering temperature that is higher than room temperature and lower than said microwave reflecting temperature of said at least one primary susceptor.

18. The microwave hybrid heating system of claim 15, wherein said at least one primary susceptor and said at least one secondary susceptor each have a melting temperature that is greater than a maximum sintering temperature of said at least one ceramic member.

19. The microwave hybrid heating system of claim 13, wherein said at least one susceptor comprises SiC and said ceramic member comprises zirconia stabilized with about 3 mol % yttria.

20. The microwave hybrid heating system of claim 15, wherein said at least one primary susceptor comprises SiC and said at least one secondary susceptor comprises a zirconia ceramic.