Recuperative reforming reactor

• US 20070028860A1
• Filed: 08/08/2005
• Published: 02/08/2007
• Est. Priority Date: 08/08/2005
• Status: Active Grant

• Current Assignee: Utilization Technology Development NFP
• Original Assignee: Utilization Technology Development NFP
• Inventors: Hemsath, Klaus
• Granted Patent: US 7,293,533 B2
• Time in Patent Office: Days
• US Class Current: 123/3
• CPC Class Codes: B01J 2208/00221 comprising baffles for guiding the flow of the heat exchange medium
• CPC Class Codes: B01J 2208/00309 with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
• CPC Class Codes: B01J 2219/0004 Processes in series
• CPC Class Codes: B01J 8/008 Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction B01J8/0285, B01J8/067, B01J8/087, B01J8/1836 take precedence
• CPC Class Codes: B01J 8/0457 the beds being placed in separate reactors
• CPC Class Codes: B01J 8/0496 Heating or cooling the reactor
• CPC Class Codes: B01J 8/067 Heating or cooling the reactor B01J8/062 takes precedence
• CPC Class Codes: C01B 2203/0233 the reforming step being a steam reforming step
• CPC Class Codes: C01B 2203/0811 by combustion of fuel
• CPC Class Codes: C01B 2203/1294 Evaporation by heat exchange with hot process stream
• CPC Class Codes: C01B 2203/143 Three or more reforming, decomposition or partial oxidation steps in series
• CPC Class Codes: C01B 3/382 Multi-step processes
• CPC Class Codes: C01B 3/384 the catalyst being continuously externally heated
• CPC Class Codes: F02M 27/02 by catalysts

Abstract

A method and apparatus for fuel reforming using the exhaust gases from internal combustion engines and high temperature combustion processes in which a fuel for reforming and steam mixture is introduced into a tube bundle having a plurality of heat exchange tubes and heat from the exhaust gases is transferred into the heat exchange tubes, thereby increasing the temperature of the mixture. The heated mixture is reformed by contact with a reforming catalyst external to, but proximate to the exit of, the tube bundle, forming a reformed fuel. To remove substantially all of the heat from the exhaust gases, a plurality of tube bundles and associated reforming catalyst arranged in series are provided.

Claims

1. An apparatus for fuel reforming comprising:

reforming means for reforming a reformable fuel, said reforming means having a reformable fuel inlet and a reformed fuel outlet;

heat exchange means for heating said reformable fuel in said reforming means, said heat exchange means in convective heat exchange communication with said reforming means and having a heated heat exchange fluid inlet and a cooled heat exchange fluid outlet;

a heat exchange fluid source selected from the group consisting of an internal combustion engine, a combustor and combinations thereof, said heat exchange fluid source having a heated heat exchange fluid outlet in fluid communication with said heated heat exchange fluid inlet of said heat exchange means; and

said reforming means comprising at least one tube bundle comprising a plurality of heat exchange tubes having a reformable fuel tube inlet in fluid communication with said reformable fuel inlet and a fuel outlet in fluid communication with said reformed fuel outlet, and at least one reforming catalyst, said at least one reforming catalyst disposed external to said tube bundle proximate said fuel outlet.

2. An apparatus in accordance with claim 1, wherein said heated heat exchange fluid outlet of said internal combustion engine is in fluid communication with said reformable fuel inlet of said reforming means.

6. An apparatus in accordance with claim 1 comprising a plurality of serially configured said tube bundles, wherein said fuel outlet of an upstream said tube bundle is in fluid communication with said reformable fuel inlet of a downstream said tube bundle.

7. An apparatus in accordance with claim 1, wherein said plurality of tubes comprise at least one convection heat transfer enhancement.

8. An apparatus in accordance with claim 7, wherein said at least one convective heat transfer enhancement is selected from the group consisting of dimples, bumps, and combinations thereof disposed on at least one surface of said plurality of heat exchange tubes.

9. An apparatus in accordance with claim 7, wherein said at least one heat transfer enhancement comprises at least one helical coil disposed at least one of internal and external to said plurality of heat exchange tubes.

10. An apparatus in accordance with claim 7, wherein said at least one convective heat transfer enhancement comprises at least one heat exchange fin disposed in said at least one tube bundle external to said plurality of heat exchange tubes.

11. An apparatus in accordance with claim 1 further comprising an elongated solid tube insert disposed within at least a portion of said plurality of heat exchange tubes.

12. An apparatus in accordance with claim 11, wherein said elongated solid tube insert comprises said at least one reforming catalyst.

3-5. -5. (canceled)

13-18. -18. (canceled)