Broad band antireflection coating and method of making same

• US 20070030569A1
• Filed: 08/04/2005
• Published: 02/08/2007
• Est. Priority Date: 08/04/2005
• Status: Abandoned Application

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Lu, Yiwei, Van Skike, Tamzen
• Application Number:
  US11/196,476
• Publication Number:
  US 20070030569A1
• Time in Patent Office: Days
• US Class Current: 359/586
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 2217/734 comprising an alternation of high and low refractive indexes
• CPC Class Codes: G02B 1/115 Multilayers

Abstract

A coated article includes a broad band antireflection (AR) coating that utilizes aluminum oxynitride (AlO_xN_y) in the medium index (index of refraction “n”) layer of the coating. In certain example embodiments, the coating may include the following layers from the glass substrate outwardly: aluminum oxynitride (AlO_xN_y) medium index layer/high index layer/low index layer. In certain example embodiments, depending on the chemical and optical properties of the low and high index layers and the substrate, x and y of the aluminum oxynitride (AlO_xN_y) of the medium index layer can be selected to optimize the overall performance of the broad band antireflection coating.

Claims

1. A coated article including an anti-reflection coating supported by a substrate, the coated article comprising:

the substrate supporting the anti-reflection coating, wherein the anti-reflection coating comprises a low index layer having a low index of refraction (n), a medium index layer having a medium index of refraction, and a high index layer having a high index of refraction;

wherein the medium index layer comprises aluminum oxynitride and is on and in direct contact with the substrate, and wherein the medium index layer comprising aluminum oxynitride has an index of refraction of from about 1.65 to 2.0;

wherein the medium index layer comprising aluminum oxynitride has an index of refraction less than that of the high index layer and greater than that of the low index layer; and

wherein the high index layer has an index of refraction of at least about 2.0, the low index layer has an index of refraction of from about 1.35 to 1.75; and

wherein the high index layer is located between and contacting the medium index layer and the low index layer.

2. The coated article of claim 1, wherein the substrate is a glass substrate, and wherein the low index layer is an outermost layer of the anti-reflective coating and is exposed to surrounding atmosphere.

3. The coated article of claim 1, wherein each of the high, medium and low index layers are dielectric layers.

4. The coated article of claim 1, wherein the high index layer has an index of refraction of from about 2.1 to 2.6.

5. The coated article of claim 1, wherein the low index layer has an index of refraction of from about 1.4 to 1.65.

6. The coated article of claim 1, wherein the high index layer comprises an oxide of titanium

7. The coated article of claim 1, wherein the low index layer comprises SiO₂.

8. The coated article of claim 1, wherein the medium index layer comprising aluminum oxynitride has an index of refraction of from about 1.72 to 1.93.

9. The coated article of claim 1, wherein the antireflection coating consists essentially of the high index layer, the low index layer and the medium index layer.

10. The coated article of claim 1, wherein the aluminum oxynitride has an oxygen to nitrogen ratio characterized by O/(O+N) of from about 0.29 to 0.99.

11. The coated article of claim 1, wherein the aluminum oxynitride has an oxygen to nitrogen ratio characterized by O/(O+N) of from about 0.5 to 0.95.

12. The coated article of claim 1, wherein the aluminum oxynitride has an oxygen to nitrogen ratio characterized by O/(O+N) of from about 0.56 to 0.93.

13. The coated article of claim 1, wherein the coated article has a photopic reflection of no greater than about 3.0%.

14. The coated article of claim 1, wherein the coated article has a photopic reflection of no greater than about 0.5%.

15. The coated article of claim 1, wherein the medium index layer consists essentially of aluminum oxynitride.

16. The coated article of claim 1, wherein the coated article has a visible transmission of at least about 60%, and the substrate is a glass substrate.

17. The coated article of claim 1, wherein the coating supported by the glass substrate has no electrically conductive layer.

18. The coated article of claim 1, wherein the coating supported by the glass substrate has no layer of Ag or Au.

19. The coated article of claim 1, wherein the coating supported by the glass substrate has no pyrolytic layer.

20. A coated article including an anti-reflection coating supported by a substrate, the coated article comprising:

the substrate supporting the anti-reflection coating, wherein the anti-reflection coating comprises a low index layer having a low index of refraction (n), a medium index layer having a medium index of refraction, and a high index layer having a high index of refraction;

wherein the medium index layer comprises aluminum oxynitride and is located below each of the high index layer and the low index layer in the coating;

wherein the medium index layer comprising aluminum oxynitride has an index of refraction less than that of the high index layer and greater than that of the low index layer.

21. The coated article of claim 20, wherein each of the high, low and medium index layers are dielectric layers.

22. The coated article of claim 20, wherein the medium index layer comprising aluminum oxynitride has an index of refraction from about 1.63 to 2.05.