Method of thermally tempering coated article with transparent conductive oxide (TCO) coating using flame(s) in tempering furnace adjacent TCO to burn off oxygen and product made using same

• US 20070031593A1
• Filed: 08/02/2005
• Published: 02/08/2007
• Est. Priority Date: 08/02/2005
• Status: Active Grant

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Krasnov, Alexey, Blacker, Richard, Richardson, Cory
• Granted Patent: US 7,744,955 B2
• Time in Patent Office: Days
• US Class Current: 427/162
• CPC Class Codes: C03C 17/245 by deposition from the vapour phase
• CPC Class Codes: C03C 17/2453 Coating containing SnO2
• CPC Class Codes: C03C 2217/211 SnO2
• CPC Class Codes: C03C 2217/214 Al2O3
• CPC Class Codes: C03C 2217/216 ZnO
• CPC Class Codes: C03C 2217/24 Doped oxides
• CPC Class Codes: C03C 2217/256 Ag
• CPC Class Codes: C03C 2218/154 by sputtering
• CPC Class Codes: C03C 2218/32 After-treatment

Abstract

A method of making a coated article including a transparent conductive oxide (TCO) film supported by a glass substrate is provided. In certain example embodiments, the coated article including the TCO film on the glass substrate is thermally tempered in a tempering furnace. In certain example embodiments, during tempering flame(s) are provided proximate the exposed surface of the TCO in order to burn off excess oxygen near the TCO surface thereby preventing or reducing oxidation of the TCO during the tempering process. A coated article, that is thermally tempered, made by such a product is also provided.

Claims

1. A method of making a coated article including a transparent conductive film, the method comprising:

providing a glass substrate;

forming a film comprising a transparent conductive oxide on the glass substrate; and

tempering the coated article including the glass substrate and the film comprising the transparent conductive oxide, and wherein at least one flame is provided in a tempering furnace in order to burn off oxygen to prevent or reduce oxidizing of the film comprising transparent conductive oxide during tempering.

2. The method of claim 1, wherein the flame is provided proximate a surface of the film comprising transparent conductive oxide, and wherein the film comprising the transparent conductive oxide has a sheet resistance of from about 5-100 ohms/square.

3. The method of claim 1, wherein a plurality of flames are provided in the tempering furnace.

4. The method of claim 1, wherein following tempering the film is still electrically conductive.

5. The method of claim 1, wherein at least part of the flame is located within about 20 cm of a surface of the film comprising transparent conductive oxide.

6. The method of claim 1, wherein at least part of the flame is located within about 10 cm of a surface of the film comprising transparent conductive oxide.

7. The method of claim 1, wherein at least part of the flame is located within about 5 cm of a surface of the film comprising transparent conductive oxide.

8. The method of claim 1, wherein at least part of the flame is located within about 2 cm of a surface of the film comprising transparent conductive oxide.

9. The method of claim 1, wherein at least part of the flame touches the film comprising transparent conductive oxide in the tempering furnace.

10. The method of claim 1, wherein no flame or flames is/are provided in a beginning portion of the tempering furnace.

11. The method of claim 10, wherein the beginning portion of the tempering furnace where no flame is provided is at least about 10% of the length of the tempering furnace.

12. The method of claim 10, wherein the beginning portion of the tempering furnace where no flame is provided is at least about 20% of the length of the tempering furnace.

13. The method of claim 1, wherein said forming the film comprising transparent conductive oxide on the glass substrate comprising sputtering at least one sputtering target at approximately room temperature.

14. The method of claim 1, wherein another layer is provided on the glass substrate so as to be located between the glass substrate and the film comprising transparent conductive oxide.

15. The method of claim 1, wherein the coated article has a visible transmission of at least about 50% before and/or after the tempering.

20. The method of claim 1, wherein the flame touches the film in the tempering furnace.

21. The method of claim 1, wherein the film comprising the transparent conductive oxide has a sheet resistance of no greater than about 200 ohms/square.

22. The method of claim 21, wherein the film comprising the transparent conductive oxide has a sheet resistance of no greater than about 100 ohms/square.

16. A method of making a coated article including a transparent conductive film, the method comprising:

providing a glass substrate;

forming a transparent conductive film comprising a transparent conductive oxide on the glass substrate; and

tempering the coated article including the glass substrate and the transparent conductive film, and wherein at least one flame is provided in a tempering furnace proximate the transparent conductive film.

17. The method of claim 16, wherein at least part of the flame is located within about 20 cm of an exposed surface of the transparent conductive film.

18. The method of claim 16, wherein the coated article has a visible transmission of at least about 50% before and/or after the tempering.

19. The method of claim 16, wherein the flame touches the transparent conductive film in the tempering furnace.