Process and apparatus for manufacturing ethylene polymers and copolymers

• US 20070032614A1
• Filed: 07/05/2006
• Published: 02/08/2007
• Est. Priority Date: 08/05/2005
• Status: Active Grant

• Current Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Van Nuland, Tom, De Koster, Willy, Clymans, Paul, Cornelissen, Philip, Lammens, Henri, Decoster, Martin, Goossens, Ivo, Ciancio, Fausto
• Granted Patent: US 7,582,709 B2
• Time in Patent Office: Days
• US Class Current: 526/65
• CPC Class Codes: B01J 19/2415 Tubular reactors
• CPC Class Codes: B01J 2219/00006 Large-scale industrial plants
• CPC Class Codes: B01J 2219/0002 Plants assembled from modules joined together
• CPC Class Codes: B01J 2219/0004 Processes in series
• CPC Class Codes: B01J 2219/00069 Flow rate measurement
• CPC Class Codes: B01J 2219/00094 Jackets
• CPC Class Codes: B01J 2219/00159 controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
• CPC Class Codes: B01J 2219/00162 controlling the pressure
• CPC Class Codes: B01J 2219/00164 controlling the flow
• CPC Class Codes: B01J 2219/00252 Formation of deposits other than coke
• CPC Class Codes: C08F 10/02 Ethene
• CPC Class Codes: C08F 2/00 Processes of polymerisation
• CPC Class Codes: C08F 2/01 characterised by special features of the polymerisation apparatus used
• CPC Class Codes: C08F 2/38 Polymerisation using regulators, e.g. chain terminating agents , e.g. telomerisation
• CPC Class Codes: C08F 210/02 Ethene
• CPC Class Codes: C08F 218/08 Vinyl acetate
• CPC Class Codes: Y02P 30/40 Ethylene production
• CPC Class Codes: Y10S 526/918 Polymerization reactors for addition polymer preparation
• CPC Class Codes: Y10S 526/92 Apparatus for use in addition polymerization processes

Abstract

The invention relates to a process for the manufacture of ethylene polymers and copolymers in which ethylene is compressed in a primary compressor at a throughput of at least 55 tonnes/hour, mixed with recycled ethylene and further compressed in a two-stage reciprocating secondary compressor having at least 14 cylinders to a pressure of at least 2300 bar at a throughput of at least 120 tonnes/hour, heating at least a portion of that ethylene to a temperature of at least 95° C. and introducing it into a tubular reactor of diameter at least 65 mm and a length of at least 1500 m, introducing initiator in at least three reaction zones to give a conversion of at least 28% and maintaining a pressure drop over the reactor to maintain a flow velocity of at least 6 m/s.

Claims

1. A process for the manufacture of ethylene polymers and copolymers comprising the steps of:

compressing ethylene in a primary compressor at a throughput of at least 55 tonnes/hour and then mixing that ethylene with recycled ethylene and further compressing the ethylene to a pressure of at least 2300 bar at a throughput of at least 120 tonnes/hour in a secondary compressor,

heating at least a portion of the compressed ethylene to a temperature of at least 95°

C. and introducing that heated ethylene into the front end of a tubular reactor having a maximum internal diameter of at least 65 mm and a length of at least 1500 m,

introducing initiator into the tubular reactor in at least three separate locations, thereby defining at least three reaction zones, allowing the ethylene to polymerize, and cooling the reaction mixture in at least the first two reaction zones, such that at least 28% of the monomer is converted to polymer,

maintaining a pressure drop over the length of the tubular reactor such as to maintain a flow velocity in the tubular reactor of at least 6 m/s,

releasing the reaction mixture through a high-pressure, let-down valve, cooling the reaction mixture and separating the reaction mixture in a product separator into polymer and unreacted ethylene, and

recycling unreacted ethylene.

2. A process as claimed in claim 1 in which the primary compressor is a reciprocating compressor having at least 8 cylinders and compresses the ethylene to a pressure of at least 200 bar.

3. A process as claimed in claim 1 in which the secondary compressor is a two-stage compressor and has 14 or 16 cylinders arranged in a single frame.

4. A process as claimed in claim 1 in which the secondary compressor has 14, 16, 18, 20, or 22 cylinders arranged in two separate frames.

5. A process as claimed in claim 1 in which the secondary compressor has a maximum of 32 cylinders arranged in two separate frames.

6. A process as claimed in claim 1 in which the throughput through the secondary compressor is in the range of from 140 to 210 tonnes/hr.

7. A process as claimed in claim 1 in which the portion of compressed ethylene is heated to at least 135°

C. prior to introduction into the front end of the tubular reactor.

8. A process as claimed in claim 1 in which in each reaction zone upstream of an initiator injection point the reaction mixture is cooled to at least 20°

C. below the peak temperature of that reaction zone.

9. A process as claimed in claim 1 in which the maximum internal diameter of the tubular reactor is at least 76 mm.

10. A process as claimed in claim 1 in which the initiator is injected at 4, 5, or 6 different points.

11. A process as claimed in claim 1 in which the flow velocity in the tubular reactor is in the range of from 8 m to 30 m/sec.

12. A process as claimed in claim 1 in which the conversion is in the range of from 28 to 40%.

13. A process as claimed in claim 11 in which the conversion is in the range of from 30 to 37%.

14. A process as claimed in claim 1 in which the reaction mixture is cooled in a product cooler arranged downstream of the high-pressure, let-down valve, the product cooler having a maximum internal diameter of at least 65 mm and a length of at least 200 m.

15. A process as claimed in claim 1 in which the product separator has two stages with the pressure in the first stage being in the range of from 250 to 350 bar and the pressure in the second stage being in the range of from 1 to 10 bara.

16. An apparatus for the manufacture of polyethylene and polyethylene copolymers comprising a primary compressor capable of a throughput of at least 55 tonnes/hr arranged to supply compressed ethylene to a two-stage secondary compressor and capable of compressing ethylene at a throughput of at least 120 tonnes/hr at a pressure of at least 2300 bar, the secondary compressor communicating, via a conduit provided with heating means to enable at least a portion of the compressed ethylene to be heated to at least 95°

C., with the front end of a tubular reactor,

the secondary compressor optionally communicating via one or more further conduits with one or more points downstream of the front end of the tubular reactor for the supply of one or more ethylene sidestreams to the tubular reactor,

the tubular reactor having at least three inlets for the injection of initiator thereby defining at least three reaction zones and being provided with a heating/cooling jacket in each reaction zone, the tubular reactor having a maximum internal diameter of at least 65 mm and being provided with a high-pressure, let-down valve, the production plant further comprising,

a cooling means arranged downstream of the high-pressure, let-down valve,

a product separator, and

at least one conduit for the transfer of recycled ethylene from the product separator to the secondary compressor.

17. The apparatus of claim 16 in which the two-stage secondary compressor has at least 14 cylinders.

18. The apparatus of claim 16 in which the product separator has at least two stages.