Electrode for fuel cell, membrane-electrode assembly comprising same and fuel cell system comprising same

• US 20070042262A1
• Filed: 07/28/2006
• Published: 02/22/2007
• Est. Priority Date: 07/29/2005
• Status: Active Grant

• Current Assignee: Samsung SDI Company Limited
• Original Assignee: Samsung SDI Company Limited
• Inventors: Shin, Chan-Gyun
• Granted Patent: US 8,057,958 B2
• Time in Patent Office: Days
• US Class Current: 429/483
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: H01M 4/8652 as mixture
• CPC Class Codes: H01M 4/92 Metals of platinum group H01M4/94 , H01M4/9058 take precedence
• CPC Class Codes: H01M 4/926 on carbon or graphite
• CPC Class Codes: H01M 8/1004 characterised by membrane-electrode assemblies [MEA] H01M8/12 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An electrode for a fuel cell, and a membrane-electrode assembly and a fuel cell system including the same. The electrode for a fuel cell includes a supporter including a nano-carbon fiber, a nano-carbon grown from the nano-carbon fiber, and a catalyst disposed on the nano-carbon.

Claims

1. An electrode for a fuel cell comprising:

a supporter including a nano-carbon fiber;

a nano-carbon grown from the nano-carbon fiber; and

a catalyst disposed on the nano-carbon.

2. The electrode of claim 1, wherein the nano-carbon fiber is connected with the nano-carbon by a proton conductive binder.

3. The electrode of claim 2, wherein the proton conductive binder comprises a material selected from the group consisting of polyperfluorosulfonic acid, poly[2,2′

-(m-phenylene)-5,5′

-bibenzimidazole], poly(2,5-benzimidazole), polybenzoxazole, polybenzthiazole, and combinations thereof.

4. The electrode of claim 1, wherein the catalyst comprises a material selected from the group consisting of Pt, Ru, Fe, Pd, Ni, Rh, Co, and combinations thereof.

5. The electrode of claim 1, wherein a second active catalyst is disposed on a surface of the nano-carbon.

6. The electrode of claim 5, wherein the second active catalyst comprises a material selected from the group consisting of platinum, ruthenium, osmium, a platinum-ruthenium alloy, a platinum-osmium alloy, a platinum-palladium alloy, a platinum-M alloy, and combinations thereof, and wherein M comprises a transition element material selected from the group consisting of Ga, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sn, Mo, W, Rh, and combinations thereof.

7. The electrode of claim 1, wherein the catalyst is located at a terminal end of the nano-carbon.

8. A membrane-electrode assembly comprising:

an anode;

a cathode; and

a polymer electrolyte membrane between the anode and the cathode,

wherein at least one of the anode or the cathode comprises;

a supporter including a nano-carbon fiber;

a nano-carbon grown from the nano-carbon fiber; and

a catalyst disposed on the nano-carbon.

9. The membrane-electrode assembly of claim 8, wherein the nano-carbon fiber is connected with the nano-carbon by a proton conductive binder.

10. The membrane-electrode assembly of claim 9, wherein the proton conductive binder comprises a material selected from the group consisting of polyperfluorosulfonic acid, poly[2,2′

-(m-phenylene)-5,5′

-bibenzimidazole], poly(2,5-benzimidazole), polybenzoxazole, polybenzthiazole, and combinations thereof.

11. The membrane-electrode assembly of claim 8, wherein the catalyst comprises a material selected from the group consisting of Pt, Ru, Fe, Pd, Ni, Rh, Co, and combinations thereof.

12. The membrane-electrode assembly of claim 8, wherein a second active catalyst is disposed on a surface of the nano-carbon.

13. The membrane-electrode assembly of claim 12, wherein the second active catalyst comprises a material selected from the group consisting of platinum, ruthenium, osmium, a platinum-ruthenium alloy, a platinum-osmium alloy, a platinum-palladium alloy, a platinum-M alloy, and combinations thereof, and wherein M comprises a transition element material selected from the group consisting of Ga, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sn, Mo, W, Rh, and combinations thereof.

14. The membrane-electrode assembly of claim 8, wherein each of the anode and the cathode comprises:

the supporter including the nano-carbon fiber;

the nano-carbon grown from the nano-carbon fiber; and

the catalyst disposed on the nano-carbon.

15. A fuel cell system comprising:

an electricity generating element adapted to generate electricity through oxidation of a fuel and reduction of an oxidant, and comprising;

a membrane-electrode assembly comprising;

an anode;

a cathode; and

a polymer electrolyte membrane disposed therebetween,

wherein at least one of the anode or the cathode comprises;

a supporter including a nano-carbon fiber,

a nano-carbon grown from the nano-carbon fiber; and

a catalyst disposed on the nano-carbon; and

a separator arranged at either side of the membrane-electrode assembly;

a fuel supplier adapted to supply a fuel to the electricity generating element; and

an oxidant supplier adapted to supply an oxidant to the electricity generating element.

16. The fuel cell system of claim 15, Wherein the nano-carbon fiber is connected with the nano-carbon by a proton conductive binder.

17. The fuel cell system of claim 16, wherein the proton conductive binder comprises a material selected from the group consisting of polyperfluorosulfonic acid, poly[2,2′

-(m-phenylene)-5,5′

-bibenzimidazole], poly(2,5-benzimidazole), polybenzoxazole, polybenzthiazole, and combinations thereof.

18. The fuel cell system of claim 15, wherein the catalyst comprises a material selected from the group consisting of Pt, Ru, Fe, Pd, Ni, Rh, Co, and combinations thereof.

19. The fuel cell system of claim 15, wherein a second active catalyst is disposed on a surface of the nano-carbon.

20. The fuel cell system of claim 19, wherein the second active catalyst comprises a material selected from the group consisting of platinum, ruthenium, osmium, a platinum-ruthenium alloy, a platinum-osmium alloy, a platinum-palladium alloy, a platinum-M alloy, and combinations thereof, and wherein M comprises a transition element material selected from the group consisting of Ga, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sn, Mo, W, Rh, and combinations thereof.