Method of removing heavy metals from silicate sources during silicate manufacturing
First Claim
1. A method of producing a metal silicate material comprising the steps of:
- a) providing a silicon dioxide source;
b) reacting said silicon dioxide source with a caustic to form a metal silicate solution;
b) introducing a calcium phosphate material selected from the group consisting of hydroxyapatite, dicalcium phosphate, tricalcium phosphate, and any mixtures thereof, to said formed metal silicate solution; and
d) removing any resultant insoluble heavy metal complexes and/or salts from said metal silicate solution.
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Accused Products
Abstract
Methods for the removal of lead from a metal silicate during the process of manufacturing of such a material are provided. With the reliance upon lower cost starting silicon dioxide starting materials that are known to exhibit elevated amounts of heavy metal therein for the purpose of producing metal silicates (such as sodium silicate, as one example), it has been realized that removal of significant amounts of such heavy metals is necessary to comply with certain regulatory requirements in order to provide a finished material that exhibits the same low level of heavy metal contamination as compared with finished materials that are made from more expensive, purer starting silicon dioxides. Two general methods may be followed for such decontamination purposes. One entails the introduction of a calcium phosphate material, such as dicalcium phosphate, tricalcium phosphate, and/or hydroxyapatite, to a formed metal silicate solution but prior to filtering. The other requires the introduction of calcium phosphate material (again, hydroxyapatite, tricalcium phosphate, and/or dicalcium phosphate) in a silicon dioxide, caustic, and water slurry with said dicalcium phosphate thus present throughout the overall reaction steps of metal silicate formation and is removed by filtering. In each situation, the hydroxyapatite, tricalcium phosphate, or dicalcium phosphate actually aids in rendering immobile the heavy metals therein, such as lead, cadmium, and the like, thereby preventing release of high amounts of bioavailable amounts of such heavy metals from products for which the target metal silicates are considered reactants. Thus, the heavy metal-containing metal silicates may then be utilized to produce precipitated silicas, as one example, that exhibit much lower levels of bioavailable heavy metals as compared with the original silicon dioxide source.
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Citations
20 Claims
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1. A method of producing a metal silicate material comprising the steps of:
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a) providing a silicon dioxide source;
b) reacting said silicon dioxide source with a caustic to form a metal silicate solution;
b) introducing a calcium phosphate material selected from the group consisting of hydroxyapatite, dicalcium phosphate, tricalcium phosphate, and any mixtures thereof, to said formed metal silicate solution; and
d) removing any resultant insoluble heavy metal complexes and/or salts from said metal silicate solution. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10)
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11. A method of producing a metal silicate material comprising the steps of:
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a) providing a silicon dioxide source;
b) reacting said silicon dioxide source with a soda ash to form solid a metal silicate;
c) dissolving solid metal silicate with water to form metal silicate solution;
d) introducing a calcium phosphate material selected from the group consisting of hydroxyapatite, dicalcium phosphate, tricalcium phosphate, and any mixtures thereof, to said formed metal silicate solution; and
e) removing any resultant insoluble heavy metal complexes and/or salts from said metal silicate solution. - View Dependent Claims (12, 13, 14, 15, 16, 17, 18, 19, 20)
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Specification