Active and adaptive photochromic fibers, textiles and membranes

• US 20070113358A1
• Filed: 03/14/2005
• Published: 05/24/2007
• Est. Priority Date: 03/16/2004
• Status: Abandoned Application

• Current Assignee: University of Delaware
• Original Assignee: University of Delaware
• Inventors: Rabolt, John, Bianco, Andrea
• Application Number:
  US10/572,867
• Publication Number:
  US 20070113358A1
• Time in Patent Office: Days
• US Class Current: 8/500
• CPC Class Codes: D01D 5/003 the material being a polymer solution or dispersion D01D5/0053 takes precedence
• CPC Class Codes: D01D 5/0038 the fibre formed by solvent evaporation, i.e. dry electro-spinning
• CPC Class Codes: D01F 1/06 Dyes
• CPC Class Codes: D01F 6/16 from polymers of unsaturated carboxylic acids or unsaturated organic esters, e.g. polyacrylic esters, polyvinyl acetate
• CPC Class Codes: F41H 3/02 Flexible, e.g. fabric covers, e.g. screens, nets characterised by their material or structuremaking thereof, see the relevant classes, e.g. D04
• CPC Class Codes: G11B 7/245 containing a polymeric component
• CPC Class Codes: G11B 7/246 containing dyes

Abstract

A process to make a dyed fiber which has the steps of mixing a dye capable of changing color and a polymer into a solution at a temperature below the temperature at which the dye or polymer degrades to form a polymer dye solution and electrospinning said polymer dye solution to form a fiber wherein the dye penetrates more than the surface of the fiber. The invention also relates to the fiber and use of the fiber.

Claims

1. A process to make a dyed fiber which comprises mixing at least one dye capable of changing color and said dye comprises photochromic compound, magnetochromic compound, electrochromic compound, thermochromic compound, piezochromic compound, or leuco body and at least one polymer into at least one solvent at a temperature below the temperature at which the dye or polymer degrades to form a polymer dye solution and electrospinning said polymer dye solution to form a fiber wherein the dye penetrates more than the surface of the fiber.

2. The process as claimed in claim 1, wherein said dye is uniformly dispersed through said fiber.

3. The process as claimed in claim 1, wherein said dye is photochromic compound.

4. The process as claimed in claim 2, wherein said dye is photochromic compound.

5. The process as claimed in claim 3, wherein said leuco body is a triarylmethane dye, quinone dye, indigoide dye, or azine dye.

6. The process as claimed in claim 1, wherein said polymer is Poly(L-lactide)(PLA), 75/25 Poly(DL-lactide-co-ε

-caprolactone), 25/75 Poly(DL-lactide-co-E-caprolacto-ne), Poly(E-caprolactone), polyglycolic acid, polydioxanone, collagen, polytetrafluoroethylene, polyurethane, polyester, polypropylene, polyethylene, polybutylene or silicone.

7. The process as claimed in claim 1, wherein said polymer dye solution contains at least one solvent selected from the group consisting of hexafluoroisopropanol, dichloromethane, dimethylacetamide, chloroform, dimethylformamide, methylene chloride, and xylene.

8. The process as claimed in claim 1, wherein said polymer is a polyester, polydimethyl isophthalate (DMI), polymethyl methacrylate (PMMA), polyethylene terephthalate (PET), polycarbonate, polystyrene, polyvinylidene chloride, polyvinylidene fluoride, polyethyleneoxide, nylon 6, nylon 6/6, nylon 11, nylon 12 or mixtures thereof.

9. The process as claimed in claim 8, wherein said at least one solvent is a high-volatile solvent group or a low-volatile solvent group or a mixture thereof.

10. The process as claimed in claim 9, wherein said solvent is acetone, chloroform, ethanol, isopropanol, methanol, toluene, tetrahydrofuran, water, benzene, benzyl alcohol, 1,4-dioxane, propanol, carbon tetrachloride, cyclohexane, cyclohexanone, methylene chloride, phenol, pyridine, trichloroethane or acetic acid;

N,N-dimethyl formamide (DMF), dimethyl sulfoxide (DMSO), N,N-dimethylacetamide (DMAc), 1-methyl-2-pyrrolidone (NMP), ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), acetonitrile (AN), N-methylmorpholine-N-oxide, butylene carbonate (BC), 1,4-butyrolactone (BL), diethyl carbonate (DEC), diethylether (DEE), 1,2-dimethoxyethane (DME), 1,3-dimethyl-2-imidazolidinone (DMI), 1,3-dioxolane (DOL), ethyl methyl carbonate (EMC), methyl formate (MF), 3-methyloxazolidin-2-on (MO), methyl propionate (MP), 2-methyletetrahydrofurane (MeTHF) or sulpholane (SL).

12. The process as claimed in claim 1, wherein the electrospinning is conducted at room temperature.

13. The process as claimed in claim 1, wherein there are at least two dyes capable of changing color being used.

14. The process as claimed in claim 1, wherein there are at least two polymers being used.

15. A fiber made from the process as claimed in claim 1.

16. A camouflage material which comprises the fiber as claimed in claim 15.

17. A sensor which comprises the fiber as claimed in claim 15.

18. A sensing membrane which comprises the fiber as claimed in claim 15.

19. A counterfeit protector which comprises the fiber as claimed in claim 15.

20. An information storage mechanism which comprises the fiber as claimed in claim 15.

21. An optical switch which comprises the fiber as claimed in claim 15.

11. A process to make a dyed fiber which comprises mixing at least a photochromic dye and/or a thermochromic dye and a polymethyl methacrylate polymer into a CHCl₃ solution to form a polymer dye solution and electrospinning said polymer dye solution to form a fiber wherein the dye penetrates more than the surface of the fiber.