Process for the production of synthesis gas from carbon-containing material and electrical energy

• US 20070131909A1
• Filed: 11/03/2006
• Published: 06/14/2007
• Est. Priority Date: 11/04/2005
• Status: Abandoned Application

• Current Assignee: Institut Francais Du Petrole (IFP Energies Nouvelles)
• Original Assignee: Institut Francais Du Petrole (IFP Energies Nouvelles)
• Inventors: Boudet, Nicolas, Rojey, Alexandre, Freund, Edouard
• Application Number:
  US11/592,324
• Publication Number:
  US 20070131909A1
• Time in Patent Office: Days
• US Class Current: 252/373
• CPC Class Codes: C10J 2300/0909 Drying
• CPC Class Codes: C10J 2300/0916 Biomass
• CPC Class Codes: C10J 2300/092 Wood, cellulose
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0946 Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
• CPC Class Codes: C10J 2300/1284 by renewable energy, e.g. solar energy, photovoltaic cells, wind
• CPC Class Codes: C10J 2300/16 Integration of gasification processes with another plant or parts within the plant
• CPC Class Codes: C10J 2300/1618 Modification of synthesis gas composition, e.g. to meet some criteria
• CPC Class Codes: C10J 2300/1665 to alcohols, e.g. methanol or ethanol
• CPC Class Codes: C10J 2300/1684 with electrolysis of water
• CPC Class Codes: C10J 2300/1846 Partial oxidation, i.e. injection of air or oxygen only
• CPC Class Codes: C10J 3/00 Production of combustible gases containing carbon monoxide from solid carbonaceous fuels destructive distillation processes C10B
• CPC Class Codes: C10J 3/66 by introducing them into the gasification zone
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02P 20/145 the feedstock being materials of biological origin

Abstract

The invention relates to a process for the production of a synthesis gas SG 1. Process for the production of a synthesis gas SG that has an H2/CO ratio of between 1.9 and 2.3 starting from a carbon-containing material that is relatively low in hydrogen, water and electrical energy, in which: Electrolysis of the water is carried out to produce, on the one hand, oxygen, and, on the other hand, hydrogen, A CF current that comprises at least the majority of the carbon contained in the carbon-containing material CF is subjected to a partial oxidation POX with essentially pure oxygen produced by electrolysis, At least a portion of the hydrogen that is produced by electrolysis is added to the CF current upstream and/or downstream from the partial oxidation POX, in such an amount that the H2/CO ratio of the final synthesis gas SG is between 1.9 and 2.3, the carbon-containing material being dried upstream from the POX so that the O2/H2 molar ratio of the POX-supplied oxygen to the added hydrogen is between 0.45 and 0.55.

Claims

1. A process for the production of a synthesis gas (SG) that has an H2/CO ratio of between 1.9 and 2.3 starting from a carbon-containing material is relatively low in hydrogen;

water; and

electrical energy, wherein;

Electrolysis of the water is carried out to produce oxygen and, hydrogen,

A flow (CF) that comprises at least the majority of carbon contained in the carbon-containing material is subjected to a partial oxidation (POX) with essentially pure oxygen produced by said electrolysis,

At least a portion of the hydrogen that is produced by electrolysis is added to the flow (CF) upstream and/or downstream from the partial oxidation POX, in such an amount that the H2/CO ratio of the final synthesis gas (SG) is between 1.9 and 2.3,

the process comprising, upstream from the POX, a drying stage (DRY) for drying said carbon-containing material, whereby the degree of drying during the drying stage is adjusted so that the electrolysis oxygen used in the POX stage and the added electrolysis hydrogen are in an O2/H2 molar ratio of between 0.45 and 0.55.

2. A process according to claim 1, wherein said O2/H2 molar ratio is essentially equal to 0.5.

3. A process according to claim 1, in wherein said carbon-containing material comprises primarily or totally vegetable biomass.

4. A process according to claim 1, in wherein said carbon-containing material comprises primarily or totally carbon or lignite.

5. A process according to claim 1, wherein said carbon-containing material comprises primarily a petroleum residue of a majority of hydrocarbons boiling above 550°

C.

6. A process according to claim 1, wherein the degree of moisture of the carbon-containing material is between 12% and 28% by weight at the output of the drying of said carbon-containing material.

7. A process according to claim 6, in which the degree of moisture of the carbon-containing material is between 15% and 25% by weight at the output of the drying stage.

8. Process according to claim 1, wherein heat energy is transferred directly or indirectly from the effluent of the POX to the drying stage.

9. A process according to claim 1, in which the flow that is supplied to the POX comprises steam that is generated during the cooling of the effluents of said POX.

10. A process according to claim 1, in which the electrolysis is carried out under a pressure Pe of between 0.5 and 3.5 MPa, and the POX is supplied at a pressure P_pox of the formula:

0<

Pe−

P_pox<

0.25 MPa.

11. A process according to claim 1, in which the electrolysis is carried out under a pressure Pe of between 0.10 and 0.12 MPa.

12. A process according to claim 8, in which the flow that is supplied to the POX comprises steam that is generated during the cooling of the effluents of said POX.

13. A process according to claim 12, in which the electrolysis is carried out under a pressure Pe of between 0.5 and 3.5 MPa, and the POX is supplied at a pressure P_pox of the formula:

0<

Pe−

P_pox<

0.15 MPa.

14. A process according to claim 13, in which the electrolysis is carried out under a pressure Pe of between 0.10 and 0.12 MPa.