Technique and apparatus to detect carbon monoxide poisoning of a fuel cell stack

• US 20070141406A1
• Filed: 12/19/2005
• Published: 06/21/2007
• Est. Priority Date: 12/19/2005
• Status: Abandoned Application

• Current Assignee: Plug Power Inc.
• Original Assignee: Plug Power Inc.
• Inventors: Ou, Jing
• Application Number:
  US11/311,613
• Publication Number:
  US 20070141406A1
• Time in Patent Office: Days
• US Class Current: 429/432
• CPC Class Codes: H01M 8/04552 of the individual fuel cell
• CPC Class Codes: H01M 8/04753 of fuel cell reactants
• CPC Class Codes: H01M 8/04776 at auxiliary devices, e.g. reformer, compressor, burner
• CPC Class Codes: H01M 8/04955 Shut-off or shut-down of fuel cells
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A technique that is usable with a fuel cell stack includes determining a cell voltage profile of the fuel cell stack and determining an average cell voltage of the fuel cell stack. The technique includes detecting carbon monoxide poisoning of the fuel cell stack based on the cell voltage profile and the average cell voltage.

Claims

1. A method usable with a fuel cell stack, comprising:

determining a cell voltage profile based on cell voltages of a fuel cell stack;

determining an average cell voltage based on cell voltages of the fuel cell stack; and

detecting carbon monoxide poisoning of the fuel cell stack based on the cell voltage profile and the average cell voltage.

2. The method of claim 1, wherein the act of detecting comprises:

detecting carbon monoxide poisoning based on a standard deviation of the cell voltage profile and the average cell voltage.

3. The method of claim 2, further comprising:

determining the standard deviation, the act of determining the standard deviation comprising;

measuring cell voltages of the fuel cell stack, the cell voltages spanning a range; and

excluding cell voltages near the upper and lower ends of the range from the determination of the standard deviation.

4. The method of claim 3, wherein the excluded cell voltages comprise voltages excluded from the cell voltage profile.

5. The method of claim 3, wherein the excluded cell voltages comprise voltages from the top ten percent of the range.

6. The method of claim 3, wherein the excluded cell voltages comprise cell voltages from the bottom ten percent of the range.

7. The method of claim 1, wherein the act of determining the cell voltage profile comprises:

measuring cell voltages of the stack to form a first group of cell voltages that span a range excluding cell voltages near upper and lower ends of the range form the cell voltage profile.

8. The method of claim 7, wherein the act of excluding comprises excluding cell voltages within ten percent of the upper end of the range.

9. The method of claim 7, wherein the act of excluding comprises excluding cell voltages within ten percent of the lower end of the range.

10. The method of claim 1, further comprising:

forming the cell voltage profile to significantly exclude an effect on the cell voltage profile caused by at least one of the following;

flow channel flooding, membrane drying and fuel starvation.

11. A fuel cell system comprising:

a fuel cell stack; and

a circuit to determine a cell voltage profile and an average cell voltage based on cell voltages of a fuel cell stack, and detect carbon monoxide poisoning of the fuel cell stack based on the cell voltage profile and the average cell voltage.

12. The fuel cell system of claim 11, wherein the circuit comprises:

a cell voltage monitoring circuit to scan cell voltages of the fuel cell stack; and

a controller to receive an indication of the scanned cell voltages from the cell voltage monitoring circuit, form the cell voltage profile and the average cell voltage, and detect the carbon monoxide poisoning.

13. The fuel cell system of claim 11, wherein the circuit detects carbon monoxide poisoning based on a standard deviation of the cell voltage and the average cell voltage.

14. The fuel cell system of claim 13, wherein the circuit determines the standard deviation, the determination including excluding cell voltages near the upper and lower ends of a range spanned by the cell voltages.

15. The fuel cell system of claim 14, wherein the excluded cell voltages comprise voltages excluded from the cell voltage profile.

16. The fuel cell system of claim 14, wherein the excluded cell voltages comprise voltages from the top ten percent of the range.

17. The fuel cell system of claim 11, wherein the circuit obtains a first group of the cell voltages, the first group spanning a range, and excludes cell voltages near the upper and lower ends of the range to form the cell voltage profile.

18. The fuel cell system of claim 11, wherein the circuit determines the cell voltage profile by measuring cell voltages of the stack to form a first group of cell voltages that span a range excluding cell voltages near upper and lower ends of the range.

19. The fuel cell system of claim 18, wherein the circuit excludes cell voltages within ten percent of the upper end of the range.

20. The fuel cell system of claim 11, wherein the circuit forms the cell voltage profile to significantly exclude an effect on the profile caused by at least one of the following:

flow channel flooding, membrane drying and fuel starvation.