Porous metal hydride electrode

• US 20070141464A1
• Filed: 12/21/2005
• Published: 06/21/2007
• Est. Priority Date: 12/21/2005
• Status: Abandoned Application

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Lemmon, John, Wei, Chang, Yang, Hai, Wang, Shengxian, Huang, Qunjian, Fu, Qijia, Hart, Richard
• Application Number:
  US11/314,252
• Publication Number:
  US 20070141464A1
• Time in Patent Office: Days
• US Class Current: 429/218.200
• CPC Class Codes: H01M 10/24 Alkaline accumulators
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 4/12 of consumable metal or alloy electrodes use of alloy compositions as active materials H01M4/38
• CPC Class Codes: H01M 4/242 Hydrogen storage electrodes
• CPC Class Codes: H01M 4/26 Processes of manufacture
• CPC Class Codes: H01M 8/184 Regeneration by electrochemical means
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

An electrode for use in a fuel cell or a battery is provided. The electrode may include a porous main body that may include a metal hydride defining a pore volume effective for preventing water starvation in the fuel cell or battery. An associated method for making and/or using is provided.

Claims

1. An electrode precursor, comprising:

a main body comprising a metal hydride and a sacrificial additive, and

the sacrificial additive being disposed in the main body to define an inner surface of the main body and further to define a pore volume, wherein

the sacrificial additive is present in an amount sufficient that, when removed, the pore volume of the main body is of sufficient volume to prevent or reduce water starvation in a fuel cell or in a battery in which an electrode formed from the electrode precursor is disposed.

2. The electrode precursor of claim 1, wherein the porous main body comprises one or more of nickel or cobalt.

3. The electrode precursor of claim 1, wherein the electrode is an anode.

4. The electrode precursor of claim 1, wherein the main body comprises one or more of an AB₅ alloy, AB₂ alloy, AB alloy, A₂B alloy, A₂B₁₇ alloy, or AB₃ alloy.

5. The electrode precursor of claim 4, wherein AB₅ alloy comprises one or more of LaNi₅, CaNi₅

6. The electrode precursor of claim 4, wherein AB₅ alloy comprises MA_xB_yC_z,

wherein M is a rare earth element component;

A is one of the elements Ni or Co;

B is one of the elements Cu, Fe or Mn;

C is one of the elements Al, Cr, Si, Ti, V or Sn; and

x, y and z satisfy one of the following relations,

2.2≦

x≦

4.8, 0.01≦

y≦

2.0, 0.01≦

z≦

0.6, or

4.8≦

x+y+z≦

5.4.

7. The electrode precursor of claim 4, wherein the main body comprises one or more of an AB₂ alloy.

8. The electrode precursor of claim 7, wherein the AB₂ alloy is one of Zr—

V—

Ni, Zr—

Mn—

Ni, Zr—

Cr—

Ni, TiMn, or TiCr.

9. The electrode precursor of claim 4, wherein the main body comprises one or more of an AB alloy, and wherein the AB alloy is one of TiFe or TiNi.

10. The electrode precursor of claim 1, wherein at least a portion of the sacrificial additive is capable of being retained on the inner surface of the main body.

11. The electrode precursor of claim 4, wherein the A₂B alloy is Mg₂Ni.

12. The electrode precursor of claim 4, wherein the A₂B₁₇ alloy is La₂Mg₁₇.

13. The electrode precursor of claim 4, wherein the AB₃ alloy is one of LaNi₃, CaNi₃, or LaMg₂Ni₉.

14. The electrode precursor of claim 3, wherein the main body anode material comprises a catalyzed complex hydrides.

15. The electrode precursor of claim 14, wherein the catalyzed complex hydrides comprise one or more of borides, carbides, nitrides, aluminides, or silicides.

16. The electrode precursor of claim 14, wherein the catalyzed complex hydrides comprise an alanate.

17. The electrode precursor of claim 16, wherein the alanates comprises one or more of NaAlH₄, Zn(AlH₄)₂, LiAlH₄ or Ga(AlH₄)₃.

18. The electrode precursor of claim 15, catalyzed complex hydrides comprise one or more borohydrides selected from the group consisting of Mg(BH₄)₂, Mn(BH₄)₂, and Zn(BH₄)₂.

19. An electrode formed by removal of the sacrificial material from the electrode precursor defined in claim 1.

20. The electrode of claim 19, wherein the main body has a pore volume of greater than 5 percent.

21. A fuel cell or battery comprising the electrode of claim 19.

22. A rechargeable fuel cell, comprising:

a hydrogen generator comprising the electrode of claim 19;

and

a fuel cell that shares the electrode of claim 19 with the hydrogen generator.

23. A method, comprising:

mixing a metal hydride and sacrificial material to form a mixture;

applying the mixture to metal substrate to form a main body; and

removing the sacrificial material to form a porous electrode.

24. The method of claim 23, further comprising mixing a binder with the metal hydride and the sacrificial material.

25. The method of claim 23, wherein the metal substrate is nickel foam.

26. The method of claim 23, wherein removing comprises sintering the main body.

27. The method of claim 26, wherein the sintering is a paste sintering.

28. The method of claim 26, wherein the sintering is a cold press sintering.

29. The method of claim 23, wherein the removing of the sacrificial material is by alkaline dissolving.

30. The method of claim 23, wherein the removing of the sacrificial material is by sonication.

31. The method of claim 23, wherein the removing of the sacrificial material is by heat decomposition.

32. The method of claim 23, wherein the removing of the sacrificial material is by acid dissolving.

33. The method of claim 23, wherein the sacrificial material is added in an amount that is effective for making a porous electrode having a pore volume of greater than about 5 percent.

34. The method of claim 23, further comprising pressing the main body to form an anode having a determined thickness.

35. A system, comprising:

means for forming an electrode; and

means for forming pores in the electrode.

36. The system of claim 35, further comprising a catalyst disposed in the means for forming the pores, wherein the catalyst is capable of deposing on an inner surface of the electrode after the pores are formed in the electrode.