Synergistic lubricating oil composition containing a mixture of a benzo[b]perhydroheterocyclic arylamine and a diarylamine
First Claim
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1. A composition comprising a lubricating oil and a synergistic mixture of antioxidants, said mixture comprising a) from 0.1 to 10 weight percent of a first antioxidant according to formula I:
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wherein R1 and R2 are each independently selected from the group consisting of hydrogen, alkyl from 1 to 20 carbon atoms, —
OR, —
SR and —
NRR′
, where R and R′
are independently hydrogen or alkyl from 1 to 6 carbon atoms, or R1 and R2 when adjacent to each other together form a 5 to 6 membered alicyclic or aromatic ring which may be optionally substituted with 1 or 2 alkyl groups each having from 1 to 20 carbon atoms;
each R3 is hydrogen or alkyl from 1 to 6 carbon atoms, X and X′
are independently selected from —
CHR4—
, oxygen, sulfur or NR5, wherein R4 and R5 are independently hydrogen or alkyl from 1 to 6 carbon atoms, with the proviso that at least one of X or X′
is a heteroatom positioned ortho or para to the bridging nitrogen atom, and when X or X′
are nitrogen then R1 or R2 is not hydroxyl; and
further provided that when one of X or X′
is —
CHR4—
then the other may not be oxygen; and
n is an integer from 1 to 2; and
b) from 0.01 to 10 weight percent of a second antioxidant selected from the formula
wherein Ra and Rb are each independently aryl from 6 to 10 carbon atoms which may be unsubstituted or substituted with one or two alkyl groups each having from 1 to 20 carbon atoms.
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Abstract
Disclosed is a lubricating oil composition containing an oil of lubricating viscosity and a particularly effective mixture of a benzo[b]perhydroheterocyclic arylamine and a diarylamine which together provide superior oxidation inhibition.
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Citations
27 Claims
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1. A composition comprising a lubricating oil and a synergistic mixture of antioxidants, said mixture comprising
a) from 0.1 to 10 weight percent of a first antioxidant according to formula I: -
whereinR1 and R2 are each independently selected from the group consisting of hydrogen, alkyl from 1 to 20 carbon atoms, —
OR, —
SR and —
NRR′
, where R and R′
are independently hydrogen or alkyl from 1 to 6 carbon atoms, or R1 and R2 when adjacent to each other together form a 5 to 6 membered alicyclic or aromatic ring which may be optionally substituted with 1 or 2 alkyl groups each having from 1 to 20 carbon atoms;
each R3 is hydrogen or alkyl from 1 to 6 carbon atoms, X and X′
are independently selected from —
CHR4—
, oxygen, sulfur or NR5, wherein R4 and R5 are independently hydrogen or alkyl from 1 to 6 carbon atoms, with the proviso that at least one of X or X′
is a heteroatom positioned ortho or para to the bridging nitrogen atom, and when X or X′
are nitrogen then R1 or R2 is not hydroxyl; and
further provided that when one of X or X′
is —
CHR4—
then the other may not be oxygen; and
n is an integer from 1 to 2; and
b) from 0.01 to 10 weight percent of a second antioxidant selected from the formula
wherein Ra and Rb are each independently aryl from 6 to 10 carbon atoms which may be unsubstituted or substituted with one or two alkyl groups each having from 1 to 20 carbon atoms. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27)
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Specification