Foamable alcoholic composition

• US 20070148101A1
• Filed: 05/22/2006
• Published: 06/28/2007
• Est. Priority Date: 12/28/2005
• Status: Abandoned Application

• Current Assignee: GOJO Industries Incorporated
• Original Assignee: GOJO Industries Incorporated
• Inventors: Snyder, Marcia, Viscovitz, John
• Application Number:
  US11/438,664
• Publication Number:
  US 20070148101A1
• Time in Patent Office: Days
• US Class Current: 424/47
• CPC Class Codes: A01N 25/16 Foams
• CPC Class Codes: A01N 31/02 Acyclic compounds
• CPC Class Codes: A61P 31/00 Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
• CPC Class Codes: A61P 31/02 Local antiseptics
• CPC Class Codes: C11D 1/008 Polymeric surface-active agents
• CPC Class Codes: C11D 3/0094 High foaming compositions
• CPC Class Codes: C11D 3/2003 Alcohols; Phenols
• CPC Class Codes: C11D 3/3738 Alkoxylated silicones

Abstract

A stable foam composition includes greater than about 40 weight percent of an alcohol, based upon the total weight of the alcoholic composition, and a foaming surfactant selected from fluorosurfactants, siloxane polymer surfactants, and combinations thereof. When the foaming surfactant includes a fluorosurfactant, the alcoholic composition further includes a polymeric or oligomeric foam stabilizer.

Claims

1. A foamable composition comprising:

at least about 40 weight percent alcohol, based upon the total weight of the alcoholic composition; and

a foaming surfactant selected from the group consisting of siloxane polymer surfactants, anionic, cationic, and zwitterionic fluorosurfactants, and combinations thereof;

with the proviso that where the foaming surfactant comprises a fluorosurfactant, the foamable alcoholic composition further comprises a polymeric or oligomeric foam stabilizer.

2. The composition of claim 1, wherein said alcohol comprises methanol, ethanol, propanol, isopropanol, butanol, isobutanol, tertiary butanol, or mixtures thereof.

3. The composition of claim 1, wherein said foaming surfactant comprises an anionic, cationic, or zwitterionic fluorosurfactant.

4. The composition of claim 3, wherein said fluorosurfactant comprises a surfactant selected from the group consisting of perfluoroalkylethyl phosphates, perfluoroalkylethyl betaines, fluoroaliphatic amine oxides, fluoroaliphatic sodium sulfosuccinates, fluoroaliphatic phosphate esters, fluoroaliphatic quaternaries, and mixtures thereof.

5. The composition of claim 3, wherein said fluorosurfactant comprises DEA-C8-18 perfluoroalkylethyl phosphate, TEA-C8-18 perfluoroalkylethyl phosphate, NH₄-C8-18 perfluoroalkylethyl phosphate, or C8-18 perfluoroalkylethyl betaine.

6. The composition of claim 3, wherein said foaming surfactant comprises a fluorosurfactant compound that may be represented by the formula

[F₃CF₂C—

(CF₂CF₂)_x—

CH₂CH₂—

O—

P₂O₃]⁻

[R¹]⁺

where [R¹] +includes DEA, TEA, NH₄, or betaine, and where x is an integer from about 4 to about 18.

7. The composition of claim 3, wherein said foam stabilizer comprises a cationic oligomer or polymer.

8. The composition of claim 3, wherein said foamable composition comprises greater than about 60 wt. % alcohol, and said fluorosurfactant is present in an amount of from about 0.002 to about 1 wt %, based upon the total weight of the alcoholic composition.

9. The composition of claim 1, wherein said foaming surfactant comprises a siloxane polymer surfactant.

10. The composition of claim 9, wherein said siloxane polymer surfactant comprises a surfactant selected from the group consisting of organopolysiloxane dimethicone polyols, silicone carbinol fluids, silicone polyethers, alkylmethyl siloxanes, amodimethicones, trisiloxane ethoxylates, dimethiconols, quatemized silicone surfactants, polysilicones, silicone crosspolymers, silicone waxes, and mixtures thereof.

11. The composition of claim 9, wherein said siloxane polymer surfactant comprises dimethicone PEG-7 undecylenate, PEG-10 dimethicone, PEG-8 dimethicone, PEG-12 dimethicone, perfluorononylethyl carboxydecal PEG 10, PEG-20/PPG-23 dimethicone, PEG-11 methyl ether dimethicone, bis-PEG/PPG-20/20 dimethicone, silicone quats, PEG-9 dimethicone, PPG-12 dimethicone, fluoro PEG-8 dimethicone, PEG 23/PPG 6 dimethicone, PEG 20/PPG 23 dimethicone, PEG 17 dimethicone, PEG5/PPG3 methicone, bis-PEG20 dimethicone, a PEG/PPG20/15 dimethicone copolyol and sulfosuccinate blend, or a mixture thereof.

12. The composition of claim 9, wherein said foaming surfactant comprises a siloxane polymer surfactant that may be represented by the formula

R²—

Si(CH₃)₂—

[O—

Si(CH₃)₂]_a—

[O—

Si(CH₃)R³]_b—

O—

Si(CH₃)₂—

R²

where R² and R³ independently include a methyl group or a moiety that may be represented by the formula

—

(CH₂)₃—

O—

(CH₂CH₂O)_c—

[CH₂CH(CH₃)O]_d—

(CH₂CH₂O)_eH

with the proviso that both R² and R³ are not CH₃, where a is an integer from about 3 to about 21, b is an integer from about 1 to about 7, c is an integer from about 0 to about 40, d is an integer from about 0 to about 40, and e is an integer from about 0 to about 40, with the proviso that a≧

3×

b and that c+d+e≧

5.

13. The composition of claim 9, wherein said composition further comprises at least one foam stabilizer.

14. The composition of claim 13, wherein said foam stabilizer comprises a cationic oligomer or polymer.

15. The composition of claim 14, wherein said cationic oligomer or polymer comprises a polyquaternium, a quaternized copolymer of vinylpyrrolidone and dimethylamino methacrylate, a hydrophobically modified quaternized copolymer of vinylpyrrolidone &

dimethylaminopropyl methacrylamide, or a mixture thereof.

16. The composition of claim 13, wherein said foam stabilizer comprises a terpolymer of vinylcaprolactam (VCL), vinylpyrrolidone (VP) and dialkylaminoalkyl acrylate, or a isobutylene/dimethylaminopropyl maleimide/ethoxylated maleimide/maleic acid copolymer.

17. The composition of claim 13, wherein said foam stabilizer is present in an amount of from about 0.005 to about 4 wt. %, based upon the total weight of the alcoholic composition.

18. The composition of claim 13, wherein the weight ratio of foaming surfactant to foam stabilizer is from about 3.5:

1 to about 14.5;

1.

19. The composition of claim 1, wherein said foaming surfactant is present in an amount of from about 0.002 to about 4 weight percent, based upon the total weight of the alcoholic composition.

20. The composition of claim 1, wherein said alcohol is present in an amount of at least about 50 wt. % based upon the total weight of the alcoholic composition.

21. The composition of claim 1, wherein said alcohol is present in an amount of at least about 60 wt. % based upon the total weight of the alcoholic composition.

22. An antimicrobial composition comprising:

at least about 50 weight percent alcohol, based upon the total weight of the alcoholic composition; and

from about 0.002 to about 4 wt. % of a surfactant comprising a fluorosurfactant selected from the group consisting of compounds represented by the formula

[F₃CF₂C—

(CF₂CF₂)_x—

CH₂CH₂—

O—

P₂O₃]⁻

[R¹]⁺

where [R¹]+ includes DEA, TEA, NH_4, or betaine, and where x is an integer from about 4 to about 18, or a siloxane polymer surfactant, selected from the group consisting of compounds represented by the formula

R²—

Si(CH₃)₂—

[O—

Si(CH₃)₂]_a—

[O—

Si(CH₃)R³]<sub>b—

O—

Si(CH3</sub>)₂—

R²

where R2 and R3 independently include a methyl group or a moiety that may be represented by the formula

—

(CH₂)₃—

O—

(CH₂CH₂O)_c—

[CH₂CH(CH₃)O]_d—

(CH₂CH₂O)_eH

with the proviso that both R² and R³ are not CH₃, where a is an integer from about 3 to about 21, b is an integer from about 1 to about 7, c is an integer from about 0 to about 40, d is an integer from about 0 to about 40, and e is an integer from about 0 to about 40, with the proviso that a ≧

3×

b and that c+d+e≧

5, or a combination thereof;

from about 0.005 to about 4 wt. % of a polymeric or oligomeric cationic polymer.

23. The composition of claim 22, wherein said foaming surfactant comprises a fluorosurfactant that may be represented by the formula

[F₃CF₂C—

(CF₂CF₂)_x—

CH₂CH₂—

O—

P₂O₃]⁻

[R¹]⁺

where [R¹]+ includes DEA, TEA, NH_4, or betaine, and where x is an integer from about 4 to about 18.

24. The composition of claim 22, wherein said foaming surfactant comprises a siloxane polymer surfactant that may be represented by the formula

R²—

Si(CH₃)₂—

[O—

Si(CH₃)₂]_a—

[O—

Si(CH₃)R³]_b—

O—

Si(CH₃)₂—

R²

where R² and R³ independently include a methyl group or a moiety that may be represented by the formula

—

(CH₂)₃—

O—

(CH₂CH₂O)_c—

[CH₂CH(CH₃)O]_d—

(CH₂CH₂O)_eH

with the proviso that both R² and R³ are not CH₃, where a is an integer from about 3 to about 21, b is an integer from about 1 to about 7, c is an integer from about 0 to about 40, d is an integer from about 0 to about 40, and e is an integer from about 0 to about 40, with the proviso that a≧

3×

b and that c+d+e≧

5.

25. A method for forming stabilized alcoholic foam, the method comprising:

combining an alcohol, a foaming surfactant selected from the group consisting of siloxane polymer surfactants, anionic, cationic, and zwitterionic fluorosurfactants and combinations thereof, to form a foamable alcoholic composition;

mixing said alcoholic composition and air or an inert gas in a mixing chamber to form a mixture; and

passing said mixture through a mesh screen to form a foam, wherein said foamable alcoholic composition comprises at least about 40 percent by weight alcohol, based upon the total weight of the alcoholic composition, and with the proviso that, when the foaming surfactant comprises a fluorosurfactant, the foamable alcoholic composition further comprises a polymeric or oligomeric foam stabilizer.

26. The method of claim 25, wherein the foam stability of said foam at room temperature is at least about 30 seconds.

27. The method of claim 25, wherein the foam stability of said foam at room temperature is at least about 3 minutes.

28. A method for stabilizing a foam formed from a foamable alcoholic composition, the method comprising:

providing an alcoholic composition comprising an alcohol and a foaming surfactant; and

combining the alcoholic composition with a polymeric or oligomeric cationic foam stabilizer to form a stabilized foam.

29. The method of claim 28, wherein said foaming surfactant is selected from the group consisting of siloxane polymer surfactants, anionic, cationic, and zwitterionic fluorosurfactants, and combinations thereof

30. The method of claim 29, wherein said foaming surfactant comprises an anionic, cationic, or zwitterionic fluorosurfactant.

31. The method of claim 29, wherein said foaming surfactant comprises a siloxane polymer surfactant.

32. The method of claim 28, wherein said foam stabilizer comprises a cationic oligomer or polymer.

33. The method of claim 28, wherein said foam stabilizer comprises a polyquaternium, a terpolymer of vinylcaprolactam (VCL), vinylpyrrolidone (VP) and dialkylaminoalkyl acrylate, or a isobutylene/dimethylaminopropyl maleimide/ethoxylated maleimide/maleic acid copolymer.

34. The method of claim 28, wherein the foam stability of the stabilized foam is greater than the stability of a foam that does not contain a foam stabilizer.

35. The method of claim 28, wherein the foam stability of said stabilized foam at room temperature is at least about 30 seconds.

36. The method of claim 28, wherein the foam stability of said foam at room temperature is at least about 3 minutes.

37. A method for reducing dripping of a composition from a foaming pump dispenser adapted to dispense said composition, the method comprising:

providing a foamable composition comprising at least about 40 weight percent alcohol, based upon the total weight of the alcoholic composition; and

a foaming surfactant selected from the group consisting of siloxane polymer surfactants, anionic, cationic, and zwitterionic fluorosurfactants, and combinations thereof;

with the proviso that where the foaming surfactant comprises a fluorosurfactant, the foamable alcoholic composition further comprises a polymeric or oligomeric foam stabilizer;

providing a foaming pump dispenser having a dispenser head; and

placing said foamable composition into said foaming pump dispenser.

38. The method of claim 37, wherein said method further comprises the step of dispensing an aliquot of said foamable composition, wherein a portion of said aliquot remains in the dispenser head for at least about 3 minutes, and wherein said portion remaining in said dispenser head does not drip from the dispenser.