Staged modular hydrocarbon reformer with internal temperature management

• US 20070157516A1
• Filed: 01/09/2006
• Published: 07/12/2007
• Est. Priority Date: 01/09/2006
• Status: Abandoned Application

• Current Assignee: Delphi Technologies, Inc. (BorgWarner Incorporated)
• Original Assignee: Delphi Technologies, Inc. (BorgWarner Incorporated)
• Inventors: Fischer, Bernhard
• Application Number:
  US11/327,870
• Publication Number:
  US 20070157516A1
• Time in Patent Office: Days
• US Class Current: 48/61
• CPC Class Codes: C01B 2203/0261 containing a catalytic partial oxidation step [CPO]
• CPC Class Codes: C01B 2203/1011 Packed bed of catalytic structures, e.g. particles, packing elements
• CPC Class Codes: C01B 2203/1017 characterised by the form of the structure
• CPC Class Codes: C01B 2203/1235 Hydrocarbons
• CPC Class Codes: C01B 2203/142 At least two reforming, decomposition or partial oxidation steps in series
• CPC Class Codes: C01B 3/382 Multi-step processes
• CPC Class Codes: C01B 3/386 Catalytic partial combustion
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A hydrocarbon reformer comprising a plurality of sequential reforming stages separated by non-reforming spaces. The first stage catalyst bed is an egg-crate structure divided into fully active, partially active, and inactive flow cells arranged such that fully active cells are adjacent only to partially active and inactive cells. Fuel and air flowing through the partially active and inactive cells cool the catalyst bed, thereby preventing thermal excess in the first stage and consequent bed erosion. Fuel and oxygen thus heated in the first stage are mixed at the end of the first stage with the reformate formed, and the mixture is provided to the next stage, which is fully catalytic, to yield a final reformate. Because the fuel and oxygen in the second stage are diluted with reformate from the first stage, insufficient heat is generated in the fully-catalytic second stage to cause thermal degradation thereof.

Claims

1. A hydrocarbon reformer for reforming hydrocarbon fuel and oxygen into a reformate, comprising:

a) a housing having an inlet for conveying a flow stream of hydrocarbon fuel and oxygen into said reformer and an outlet for conveying a flow stream of said reformate out of said housing;

b) a first catalyst bed disposed in said housing; and

c) a second catalyst bed disposed in said housing downstream of said first catalyst bed in a flow direction of said streams through said housing.

2. A reformer in accordance with claim 1 wherein said second catalyst bed is spaced apart from said first catalyst bed.

3. A reformer in accordance with claim 2 wherein a portion of the surface of said first catalyst bed is free of catalytic material.

4. A reformer in accordance with claim 3 wherein the surface of said second catalyst bed is fully coated with catalytic material.

5. A reformer in accordance with claim 1 wherein at least one of said first and second catalyst bed includes an egg-crate structure.

6. A reformer in accordance with claim 5 wherein said egg-crate structure comprises:

a) a first plurality of first spaced-apart parallel plates extending in a first direction; and

b) a second plurality of second spaced-apart parallel plates extending in a second direction substantially orthogonal to said first direction,

wherein catalytic material is deposited on less than all of the surfaces of said first and second plates.

7. A reformer in accordance with claim 6 wherein at least one of said first plates have a first plurality of spaced-apart first slots extending partially across said plate in a widthwise direction;

and

b) at least one of said second plates have a second plurality of spaced-apart second slots extending partially across said plate in a widthwise direction,

wherein said first spaced-apart slots and second spaced-apart slots are interlocked to form said structure.

8. A reformer in accordance with claim 6 wherein said catalytic material is deposited on an entire first side of each of said first and second plates, and wherein said second side of each of said first and second plates is free of said catalytic material.

9. A reformer in accordance with claim 7 wherein said first plates are arranged in said structure such that like sides of said first plates are facing each other, and wherein said second plates are arranged in said structure such that like sides of said second plates are facing each other.

10. A reformer in accordance with claim 6 wherein said catalytic material is deposited on portions of said first and second plates and wherein said first and second plates are arranged in said structure such that a plurality of flow cells is formed in said structure, each of said flow cells having four walls.

11. A reformer in accordance with claim 10, wherein the number of catalytic walls of said four walls is selected from the group consisting of zero, one, two, three, and four.

12. A reformer in accordance with claim 1 wherein said second catalyst bed is an egg-crate structure.

13. A reformer substrate having an egg-crate structure, said structure comprising a first plurality of first spaced-apart parallel plates extending in a first direction and a second plurality of second spaced-apart parallel plates extending in a second direction substantially orthogonal to said first direction, wherein catalytic material is deposited on less than all of the surfaces of said first and second plates.