Highly conductive nano-scaled graphene plate nanocomposites and products

• US 20070158618A1
• Filed: 01/11/2006
• Published: 07/12/2007
• Est. Priority Date: 01/11/2006
• Status: Active Grant

• Current Assignee: Global Graphene Group, Inc.
• Original Assignee: Nanotek Instruments, Inc.
• Inventors: Song, Lulu, Zhamu, Aruna, Guo, Jiusheng, Jang, Bor
• Granted Patent: US 7,566,410 B2
• Time in Patent Office: Days
• US Class Current: 252/500
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01M 4/02 Electrodes composed of, or comprising, active material
• CPC Class Codes: H01M 8/0213 Gas-impermeable carbon-containing materials
• CPC Class Codes: H01M 8/0215 Glass; Ceramic materials
• CPC Class Codes: H01M 8/0221 Organic resins; Organic polymers
• CPC Class Codes: H01M 8/0223 Composites
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y10S 977/70 Nanostructure
• CPC Class Codes: Y10S 977/755 Nanosheet or quantum barrier/well, i.e. layer structure having one dimension or thickness of 100 nm or less
• CPC Class Codes: Y10S 977/773 Nanoparticle, i.e. structure having three dimensions of 100 nm or less
• CPC Class Codes: Y10S 977/778 within specified host or matrix material, e.g. nanocomposite films
• CPC Class Codes: Y10S 977/783 Organic host/matrix, e.g. lipid

Abstract

Disclosed is a nano-composite material comprising fully separated nano-scaled graphene platelets (NGPs) dispersed in a matrix material, wherein each of the platelets comprises a sheet of graphite plane or multiple sheets of graphite plane and has a thickness no greater than 100 nm and the platelets have an average length, width, or diameter no greater than 500 nm. The graphene plates are present in an amount no less than 15% by weight based on the total weight of the platelets and the matrix material combined. Typically, the nanocomposite is electrically conductive with a bulk conductivity no less than 10 S/cm and more typically no less than 100 S/cm. Highly conductive NGP nanocomposites are particularly useful for fuel cell flow field plate (bipolar plate) and battery electrode applications. Nanocomposites with high NGP proportions can be used in automotive friction plates and aircraft brake components.

Claims

1. A nanocomposite material comprising fully separated nano-scaled graphene platelets dispersed in a matrix material, wherein each of the platelets comprises a sheet of graphite plane or multiple sheets of graphite plane and the platelets have a thickness no greater than 100 nm and an average length, width, or diameter no greater than 500 nm, and wherein the platelets are present in an amount no less than 15% by weight based on the total weight of the platelets and the matrix material combined.

2. The nanocomposite as defined in claim 1 wherein said platelet amount is sufficient to make said nanocomposite electrically conductive with a bulk conductivity no less than 10 S/cm or an areal conductivity no less than 200 S/cm², measured on the basis of a nanocomposite thickness of 1 mm.

3. The nanocomposite as defined in claim 1 wherein said nanocomposite has a bulk conductivity no less than 100 S/cm.

4. The nanocomposite as defined in claim 1 wherein said amount is between 35% and 75% by weight.

5. The nanocomposite as defined in claim 1 wherein said amount is no less than 60% by weight or no less than 45% by volume.

6. The nanocomposite as defined in claim 1 wherein said matrix material comprises a material selected from the group consisting of a polymer, a carbon, a ceramic, a glass, and combinations thereof.

7. The nanocomposite as defined in claim 1 wherein said matrix material comprises a polymer selected from the group consisting of a thermoplastic, a thermoset, a rubber, and combinations thereof.

8. The nanocomposite as defined in claim 1 wherein said platelets have an average length, width, or diameter no greater than 100 nm.

9. The nanocomposite as defined in claim 1 wherein the ratio of the flexural strength of said nanocomposite to the flexural strength of said matrix material is greater than 1.3 and/or the ratio of the flexural modulus of said nanocomposite to the flexural modulus of said matrix material is greater than 2.

17. The nanocomposite as defined in claim 1, which is shaped into a fuel cell bipolar plate, a battery electrode, an automotive friction plate, or an aircraft brake pad.

19. The nanocomposite as defined in claim 1, further comprising a nano-scaled filler selected from the group consisting of a carbon nanotube, carbon nano fiber, carbon black, metal nano-powder, and combinations thereof.

10. A nanocomposite plate comprising fully separated nano-scaled graphene platelets dispersed in a matrix material, wherein each of the graphene platelets comprises a sheet of graphite plane or multiple sheets of graphite plane and the graphene platelets have a thickness no greater than 100 nm and wherein said graphene platelets are present in an amount sufficient to make said nanocomposite plate electrically conductive with a thickness-direction conductivity no less than 20 S/cm or an areal conductivity no less than 200 S/cm², measured on the basis of a plate thickness of 1 mm.

11. The nanocomposite plate as defined in claim 10 wherein said plate has a thickness-direction conductivity no less than 100 S/cm.

12. The nanocomposite plate as defined in claim 10 wherein said amount is between 20% and 75% by weight based on the total weight of said graphene platelets and said matrix material combined.

13. The nanocomposite plate as defined in claim 10 wherein said amount is no less than 45% by weight or no less than 30% by volume.

14. The nanocomposite plate as defined in claim 10 wherein said matrix material comprises a material selected from the group consisting of a polymer, a carbon, a ceramic, a glass, and combinations thereof.

15. The nanocomposite plate as defined in claim 10 wherein said matrix material comprises a polymer selected from the group consisting of a thermoplastic, a thermoset, a rubber, and combinations thereof.

16. The nanocomposite plate as defined in claim 10 wherein said platelets have an average length, width, or diameter no greater than 100 nm.

18. The nanocomposite plate as defined in claim 10, which is used as a fuel cell bipolar plate, a battery electrode, an automotive friction plate, or an aircraft brake pad.

20. The nanocomposite plate as defined in claim 10, further comprising a nano-scaled filler selected from the group consisting of a carbon nanotube, carbon nano fiber, carbon black, metal nano-powder, and combinations thereof.