A solution of metal-polymer chelate(s) and applications thereof

• US 20070170393A1
• Filed: 01/31/2005
• Published: 07/26/2007
• Est. Priority Date: 02/23/2004
• Status: Active Grant

• Current Assignee: Caiteng Zhang
• Original Assignee: Caiteng Zhang
• Inventors: Zhang, Caiteng
• Granted Patent: US 8,193,291 B2
• Time in Patent Office: Days
• US Class Current: 252/183.130
• CPC Class Codes: A23K 20/163 Sugars; Polysaccharides
• CPC Class Codes: A23K 20/20 Inorganic substances, e.g. oligoelements
• CPC Class Codes: A61K 8/60 Sugars; Derivatives thereof
• CPC Class Codes: A61K 8/73 Polysaccharides
• CPC Class Codes: A61Q 11/00 Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
• CPC Class Codes: B01D 2251/90 Chelants
• CPC Class Codes: B01D 71/00 Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
• CPC Class Codes: B01J 20/24 Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
• CPC Class Codes: B01J 20/262 obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds per se C08G
• CPC Class Codes: B01J 20/265 modified or post-treated polymers polymer carriers or substrates subjected to further impregnating or coating B01J20/3208
• CPC Class Codes: B01J 45/00 Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties ion-exchange chromatography processes B01D15/36
• CPC Class Codes: C05F 11/00 Other organic fertilisers
• CPC Class Codes: C07H 23/00 Compounds containing boron, silicon, or a metal, e.g. chelates, vitamin B12 esters with inorganic acids C07H11/00; metal salts, see parent compounds
• CPC Class Codes: C07H 3/00 Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms preparation by hydrolysis of di-or polysaccharides C13; separation or purification of sucrose, glucose, fructose, lactose or maltose C13
• CPC Class Codes: C07H 5/06 Aminosugars
• CPC Class Codes: C08B 1/00 Preparatory treatment of cellulose for making derivatives thereof , e.g. pre-treatment, pre-soaking, activation
• CPC Class Codes: C08B 15/00 Preparation of other cellulose derivatives or modified cellulose , e.g. complexes
• CPC Class Codes: C08B 37/003 Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
• CPC Class Codes: C08L 1/02 Cellulose; Modified cellulose
• CPC Class Codes: C08L 5/08 Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
• CPC Class Codes: D06M 15/03 : Polysaccharides or derivatives thereof
• CPC Class Codes: Y02E 50/30 : Fuel from waste, e.g. synthetic alcohol or diesel
• CPC Class Codes: Y02W 30/40 : Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Abstract

In a solution of metal-polymer chelate(s) and applications thereof, a metal-polymer chelate is prepared by mixing water and R—COOH soluble carbohydride molecules and/or hydroxyl or hydroxyl amino and/or carboxyl and/or carbohydrate polymers, metal salts and/or ammonia or amines. The solution of metal-polymer chelate(s) is used extensively in different technical areas including oxidation, condensation, degradation, oxidizing condensation, gas detection, artificial imitated chitosan solution, artificial imitated glucosamine, disinfectant, biochemical reaction for fermentation, biological protein and its metabolite purification, metal enzyme biocatalyst, dry activation of protein enzyme, bacteria preservation systems, oil product, plant, semiconductor, nano filtration, nano material production, nano organic matter, nano ceramic, nano plastic, nano textile, battery, liquid crystal, and biochip. These reactions give effects for chemical engineering, gas removal, and waste solvent treatment.

Claims

1. A solution of metal-polymer chelates(s), comprising:

0.1 to 99.87 percent water;

0.01 to 40 percent R—

COOH;

0.01 to 30 percent R—

COOH soluble molecule or polymer selected from the group consisting of carbohydrate molecules, hydroxyl or hydroxyl amino, and carbohydrate polymers; and

0.01 to 30 percent metal salts;

wherein the R—

COOH is an organic acid or an organic acid matter including one or more metal-polymer chelates.

2. The solution of metal-polymer chelates(s) of claim 1, wherein the solution of metal-polymer chelates(s) is comprised of water and R—

COOH;

soluble carbohydrates molecules and hydroxyl and carbohydrates polymer,

metal salts; and

ammonia or amine matters.

3. The solution of metal-polymer chelates(s) of claim 1, wherein said solution of metal-polymer chelates(s) is comprised of water and R—

COOH;

soluble carbohydrate molecules and monosaccharide bimolecules, metal salts; and

ammonia or amine matters.

4. The solution of metal-polymer chelates(s) of claim 1, wherein the solution of metal-polymer chelates(s) is comprised of water and R—

COOH;

alkaline saponification soluble R—

COOH having high or middle quantity of alkyl R such as fatty acid or carbohydrate molecules;

metal salts;

and ammonia or amine matters.

5. The solution of metal-polymer chelates(s) of claim 1, wherein the metal salt is one or more monovalent, bivalent, or trivalent metal salts and the metal salt is selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, radium, nickel, chromium, lead, copper, iron, zinc, titanium, manganese, cobalt, silver, gold, platinum, palladium, cadmium, lithium, rubidium, cesium, mercury, tin, zirconium, aluminum, thallium, antimony, bismuth, germanium, gallium, molybdenum, tungsten, yttrium, scandium, rhodium, iridium, technetium, osmium, ruthenium, rhenium, vanadium, indium, lanthanum and actinium series metal salt.

6. The solution of metal-polymer chelates(s) of claim 1, wherein the number of R—

COOH is equal to or greater then one, and the R is an alkyl radical or an alkyl matter, and the R—

COOH is selected from the group consisting of monocarboxylic acid, dicarboxylic acid, tricarboxylic acid, acetic acid, citric acid, vitamin C, salicylic acid, ethylene glycol, formic acid, propionic acid, malonic acid, lactic acid, malic acid, succinic acid, adipic acid, maleic acid, fumaric acid, ortho acid, oxalic acid, lauric acid, tartaric acid, lycium acid, humic acid, nitrified humic acid, fatty acid, opines in a plant, carboxyl acid fiber, and carboxyl resin such as Amberlite IRC-50.

7. The solution of metal-polymer chelates(s) of claim 1, wherein the R—

COOH soluble molecule or polymer is one or more molecule or polymer selected from the group consisting of sucrose, maltose, lactose, rechalose;

disaccharide group, monosaccharide group (including glucosamine), chitosan, degraded oils, seaweed cell wall (containing calcium without adding a metal salt), cereal such as an unhusked rice (containing calcium without adding a metal salt), cytokinin-O-glucosides including monosaccharide bimolecules or polyvinyl alcohol together with ammonia (or amine) matter or separate polyvinyl alcohol, or humic acid together with ammonia (or amine) matter without requiring a dissolution of acid, nitrified humic acid, peat, separate humic acid, nitrified humic acid, peat, or amino polyvinyl alcohol, or 0.1˜

6% of hydroxypropylmethyl cellulose (HPMC) and 1˜

4% of chitosan, or 0.1˜

6% of hydroxypropylmethyl cellulose (HPMC) and 1˜

4% artificial synthesized chitosan, or hydroxypropylmethyl cellulose (HPMC) together with ammonia (or amine) matter, or hydroxypropylmethyl cellulose (HPMC), or hydroxyl or hydroxyl and amino and/or carboxyl and/or carbohydrate polymer or/and oil or/and sugar mixed with each other.

8. The solution of metal-polymer chelates(s) of claim 1, wherein the metal-polymer chelate is a monosaccharide molecule (including glucosamine) or monosaccharide bimolecule or disaccharide or hydroxyl or hydroxyl and amino or carboxyl or carbohydrate polymer solution of metal-polymer chelates(s), wherein the polymer bridging agent (preferably a solution of metal-polymer chelates(s) containing monosaccharide or monosaccharide bimolecule) and inorganic polymer carrier (including inorganic and organic bridge inorganic polymer or nano inorganic polymer) and plant fiber (including carboxyl acid fiber or modification having carboxyl acid fiber) and carboxyl resin such as amberlite IRC-50 and/amino resin or inorganic matter such as polylysine or aminosilane, wherein the metal-polymer chelate and inorganic polymer carrier and plant fiber and carboxyl resin and /amino resin or inorganic matter can perform solid-liquid separation and purification for amino metal compound or amino metal polymer or amino nano metal polymer or amino nano metal compound or nano metal polymer or nano metal compound or amino biological protein or pure biological protein.

9. The solution of metal-polymer chelates(s) of claim 1, wherein the solution of metal-polymer chelates(s) includes a moisture absorbent combined with the metal-polymer hybrid.

10. The solution of metal-polymer chelates(s) of claim 8, wherein the polymer bridging agent is polyvinylpyrrolidone (PVP).

11. The solution of metal-polymer chelates(s) of claim 1, further including a protein enzyme or a bacteria or a cell.

12. The solution of metal-polymer chelates(s) of claim 1, wherein the solution of metal-polymer chelates(s) and/or the hydroxyl polymer including a silicic acid group and/or a nano powder.

13. The solution of metal-polymer chelates(s of claim 1, wherein the solution of metal-polymer chelates(s) is used for the nano material production or nano ceramic or nano plastic or nano textile industry from gas, liquid to solid comprising ozone, strong oxygen O⁻

2 or O₂⁻

, hydrogen peroxide, nitrogen gas, ammonia and ammonia gas, sulfur and sulfur gas, phosphoric acid, nitric acid, nitric acid, hydrofluoric acid, boric acid, sulfuric acid, carbonic acid, sulfonic acid, hydrochlorous acid, trichloroacetic acid, isophthalic acid, phthalic acid, graphite, carbon black, bone, pearl, enamel.

14. The solution of metal-polymer chelates(s) of claim 1, wherein the solution of metal-polymer chelates(s) used for a nano plastic industry or a nano textile industry includes a plastic or rubber polymer.

31. The solution of metal-polymer chelates(s) of claim 2, wherein the metal salt is one or more monovalent, bivalent, or trivalent metal salts and the metal salt is selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, radium, nickel, chromium, lead, copper, iron, zinc, titanium, manganese, cobalt, silver, gold, platinum, palladium, cadmium, lithium, rubidium, cesium, mercury, tin, zirconium, aluminum, thallium, antimony, bismuth, germanium, gallium, molybdenum, tungsten, yttrium, scandium, rhodium, iridium, technetium, osmium, ruthenium, rhenium, vanadium, indium, lanthanum and actinium series metal salt.

32. The solution of metal-polymer chelates(s) of claim 3, wherein the metal salt is one or more monovalent, bivalent, or trivalent metal salts and the metal salt is selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, radium, nickel, chromium, lead, copper, iron, zinc, titanium, manganese, cobalt, silver, gold, platinum, palladium, cadmium, lithium, rubidium, cesium, mercury, tin, zirconium, aluminum, thallium, antimony, bismuth, germanium, gallium, molybdenum, tungsten, yttrium, scandium, rhodium, iridium, technetium, osmium, ruthenium, rhenium, vanadium, indium, lanthanum and actinium series metal salt.

33. The solution of metal-polymer chelates(s) of claim 4, wherein the metal salt is one or more monovalent, bivalent, or trivalent metal salts and the metal salt is selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, radium, nickel, chromium, lead, copper, iron, zinc, titanium, manganese, cobalt, silver, gold, platinum, palladium, cadmium, lithium, rubidium, cesium, mercury, tin, zirconium, aluminum, thallium, antimony, bismuth, germanium, gallium, molybdenum, tungsten, yttrium, scandium, rhodium, iridium, technetium, osmium, ruthenium, rhenium, vanadium, indium, lanthanum and actinium series metal salt.

34. The solution of metal-polymer chelates(s) of claim 2, wherein the number of R—

COOH is equal to or greater then one, and the R is an alkyl radical or an alkyl matter, and the R—

COOH is selected from the group consisting of monocarboxylic acid, dicarboxylic acid, tricarboxylic acid, acetic acid, citric acid, vitamin C, salicylic acid, ethylene glycol, formic acid, propionic acid, malonic acid, lactic acid, malic acid, succinic acid, adipic acid, maleic acid, fumaric acid, ortho acid, oxalic acid, lauric acid, tartaric acid, lycium acid, humic acid, nitrified humic acid, fatty acid, opines in a plant, carboxyl acid fiber, and carboxyl resin such as Amberlite IRC-50.

35. The solution of metal-polymer chelates(s) of claim 3, wherein the number of R—

COOH is equal to or greater then one, and the R is an alkyl radical or an alkyl matter, and the R—

COOH is selected from the group consisting of monocarboxylic acid, dicarboxylic acid, tricarboxylic acid, acetic acid, citric acid, vitamin C, salicylic acid, ethylene glycol, formic acid, propionic acid, malonic acid, lactic acid, malic acid, succinic acid, adipic acid, maleic acid, fumaric acid, ortho acid, oxalic acid, lauric acid, tartaric acid, lycium acid, humic acid, nitrified humic acid, fatty acid, opines in a plant, carboxyl acid fiber, and carboxyl resin such as Amberlite IRC-50.

36. The solution of metal-polymer chelates(s) of claim 4, wherein the number of R—

COOH is equal to or greater then one, and the R is an alkyl radical or an alkyl matter, the R—

COOH is selected from the group consisting of monocarboxylic acid, dicarboxylic acid, tricarboxylic acid, acetic acid, citric acid, vitamin C, salicylic acid, ethylene glycol, formic acid, propionic acid, malonic acid, lactic acid, malic acid, succinic acid, adipic acid, maleic acid, fumaric acid, ortho acid, oxalic acid, lauric acid, tartaric acid, lycium acid, humic acid, nitrified humic acid, fatty acid, opines in a plant, carboxyl acid fiber, and carboxyl resin such as Amberlite IRC-50.

37. The solution of metal-polymer chelates(s) of claim 2, wherein the R—

COOH soluble molecule or polymer is one or molecule or polymer selected from the group consisting of sucrose, maltose, lactose, rechalose;

disaccharide group, monosaccharide group (including glucosamine), chitosan, degraded oils, seaweed cell wall (containing calcium without adding a metal salt), cereal such as an unhusked rice (containing calcium without adding a metal salt), cytokinin-O-glucosides including monosaccharide bimolecules or polyvinyl alcohol together with ammonia (or amine) matter or separate polyvinyl alcohol, or humic acid together with ammonia (or amine) matter without requiring a dissolution of acid, nitrified humic acid, peat, separate humic acid, nitrified humic acid, peat, or amino polyvinyl alcohol, or 0.1˜

6% of hydroxypropylmethyl cellulose (HPMC) and 1˜

4% of chitosan, or 0.1˜

6% of hydroxypropylmethyl cellulose (HPMC) and 1˜

4% artificial synthesized chitosan, or hydroxypropylmethyl cellulose (HPMC) together with ammonia (or amine) matter, or hydroxypropylmethyl cellulose (HPMC), or hydroxyl or hydroxyl and amino and/or carboxyl and/or carbohydrate polymer or/and oil or/and sugar mixed with each other.

38. The solution of metal-polymer chelates(s) of claim 3, wherein the R—

COOH soluble molecule or polymer is one or more molecule or polymer selected from the group consisting of sucrose, maltose, lactose, rechalose;

disaccharide group, monosaccharide group (including glucosamine), chitosan, degraded oils, seaweed cell wall (containing calcium without adding a metal salt), cereal such as an unhusked rice (containing calcium without adding a metal salt), cytokinin-O-glucosides including monosaccharide bimolecules or polyvinyl alcohol together with ammonia (or amine) matter or separate polyvinyl alcohol, or humic acid together with ammonia (or amine) matter without requiring a dissolution of acid, nitrified humic acid, peat, separate humic acid, nitrified humic acid, peat, or amino polyvinyl alcohol, or 0.1˜

6% of hydroxypropylmethyl cellulose (HPMC) and 1˜

4% of chitosan, or 0.1˜

6% of hydroxypropylmethyl cellulose (HPMC) and 1˜

4% artificial synthesized chitosan, or hydroxypropylmethyl cellulose (HPMC) together with ammonia (or amine) matter, or hydroxypropylmethyl cellulose (HPMC), or hydroxyl or hydroxyl and amino and/or carboxyl and/or carbohydrate polymer or/and oil or/and sugar mixed with each other.

39. The solution of metal-polymer chelates(s) of claim 4, wherein the R—

COOH soluble molecule or polymer is one or more molecule or polymer selected from the group consisting of collection of sucrose, maltose, lactose, rechalose;

disaccharide group, monosaccharide group (including glucosamine), chitosan, degraded oils, seaweed cell wall (containing calcium without adding a metal salt), cereal such as an unhusked rice (containing calcium without adding a metal salt), cytokinin-O-glucosides including monosaccharide bimolecules or polyvinyl alcohol together with ammonia (or amine) matter or separate polyvinyl alcohol, or humic acid together with ammonia (or amine) matter without requiring a dissolution of acid, nitrified humic acid, peat, separate humic acid, nitrified humic acid, peat, or amino polyvinyl alcohol, or 0.1˜

6% of hydroxypropylmethyl cellulose (HPMC) and 1˜

4% of chitosan, or 0.1˜

6% of hydroxypropylmethyl cellulose (HPMC) and 1˜

4% artificial synthesized chitosan, or hydroxypropylmethyl cellulose (HPMC) together with ammonia (or amine) matter, or hydroxypropylmethyl cellulose (HPMC), or hydroxyl or hydroxyl and amino and/or carboxyl and/or carbohydrate polymer or/and oil or/and sugar mixed with each other.

40. The solution of metal-polymer chelates(s) of claim 9, wherein the hybrid moisture absorbent is polyvinylpyrrolidone (PVP).

15. A solution of metal-polymer chelates(s), being used for an oxidation of producing oxygen cations and degradations.

16. A solution of metal-polymer chelates(s), being used for a condensation and an oxidizing condensation.

17. A solution of metal-polymer chelates(s), being used in artificial imitated chitosan.

18. A solution of metal-polymer chelates(s), being used in a biochemical reaction for fermentation.

19. A solution of metal-polymer chelates(s) being used in a metal enzyme biocatalyst.

20. A solution of metal-polymer chelates(s), being used in a disinfectant.

21. A solution of metal-polymer chelates(s), being used in a cell or bacteria or protein enzyme culture medium preservation system.

22. A solution of metal-polymer chelates(s), being used for dietic treatments and health cares

23. A solution of metal-polymer chelates(s), being used for the production of chemical matters of a plant.

24. A solution of metal-polymer chelates(s), being used for genes and carriers.

25. A solution of metal-polymer chelates(s), being used in a nano filtration system.

26. A solution of metal-polymer chelates(s), being used for the production of a fermentation nano material.

27. A solution of metal-polymer chelates(s), being used for the nano inorganic matter and nano ceramic and nano plastic and nano textile industries.

28. A solution of metal-polymer chelates(s), being used in the manufacture of liquid crystals and semiconductors and biochips.

29. A solution of metal-polymer chelates(s) is used for batteries.

30. A solution of metal-polymer chelates(s is used for processing a solvent liquid and removing a solvent liquid, and detecting the concentration of an organic gas.