Multilayer Coating System

• US 20070202341A1
• Filed: 06/17/2005
• Published: 08/30/2007
• Est. Priority Date: 06/18/2004
• Status: Abandoned Application

• Current Assignee: AKZO Nobel Coatings International BV (Nouryon BV)
• Original Assignee: AKZO Nobel Coatings International BV (Nouryon BV)
• Inventors: Wijnands, Peter, Dogan, Nazire, Van Der Krogt, Robertus, Jonker, Josef
• Application Number:
  US11/629,960
• Publication Number:
  US 20070202341A1
• Time in Patent Office: Days
• US Class Current: 428/423.100
• CPC Class Codes: B05D 1/36 Successively applying liquids or other fluent materials, e.g. without intermediate treatment
• CPC Class Codes: B05D 3/067 Curing or cross-linking the coating
• CPC Class Codes: B05D 7/52 Two layers
• CPC Class Codes: B05D 7/53 Base coat plus clear coat type
• CPC Class Codes: C08G 18/3876 containing mercapto groups
• CPC Class Codes: C08G 18/4676 containing sulfur
• CPC Class Codes: C08G 2150/50 Compositions for coatings applied by spraying at least two streams of reaction components
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 33/00 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
• CPC Class Codes: C09D 175/04 Polyurethanes
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31605 Next to free metal
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]

Abstract

The invention relates to a multi-layer coating system comprising: at least one layer a) comprising a coating composition a) comprising at least one isocyanate-functional compound and at least one thiol-functional compound; and at least one layer b) comprising a non-aqueous coating composition b), wherein at least one layer a) and at least one layer b) have at least one common layer boundary, and wherein coating composition b) comprises all effective amount of a catalyst for the addition reaction of tile at least one thiol-functional compound and the at least one isocyanate-functional compound.

Claims

1. A multilayer coating system comprising

at least one layer a) comprising a coating composition a) comprising at least one isocyanate-functional compound and at least one thiol-functional compound, and

at least one layer b) comprising a non-aqueous coating composition b),

at least one layer a) and at least one layer b) having at least one common layer boundary, characterized in that coating composition b) comprises an effective amount of a catalyst for the addition reaction of the at least one thiol-functional compound and the at least one isocyanate-functional compound.

2. A multilayer coating system according to claim 1, characterized in that coating composition a) comprises pentaerythritol tetrakis(3-mercapto propionate).

3. A multilayer coating system according to claim 1, characterized in that coating composition a) comprises a thiol-functional polyester.

4. A multilayer coating system according to claim 3, characterized in that the thiol-functional polyester additionally comprises hydroxyl groups.

5. A multilayer coating system according to claim 1, characterized in that coating composition a) comprises pentaerythritol tetrakis(3-mercapto propionate) and a thiol-functional polyester.

6. A multilayer coating system according to claim 1, characterized in that coating composition a) comprises a photolatent base.

7. A multilayer coating system according to claim 6, characterized in that the photolatent base is an OL-amino acetophenone.

8. A multilayer coating system according to claim 1, characterized in that layer a) is a clear coat layer.

9. A multilayer coating system according to claim 1, characterized in that the catalyst for the addition reaction of the at least one thiol-flnctional compound and the at least one isocyanate-functional compound in coating composition b) is a tertiary amine.

10. A multilayer coating system according to claim 9, characterized in that the tertiary amine is N,N-dimethyl ethanolamine.

11. A multilayer coating system according to claim 1, characterized in that the catalyst for the addition reaction of the at least one thiol-functional compound and the at least one isocyanate-functional compound in coating composition b) is a metal compound with an organic ligand where the metal is a metal of Groups 3 to 13 of the Periodic Table.

12. A multilayer coating system according to claim 1, characterized in that the catalyst for the addition reaction of the at least one thiol-functional compound and the at least one isocyanate-functional compound in coating composition b) is a co-catalyst comprising a phosphine component and a Michael acceptor component.

14. A multilayer coating system according to claim 1, characterized in that layer b) is a colour and/or effect imparting base coat layer.

15. A multilayer coating system according to claim 14, characterized in that coating composition b) is a solvent borne base coat composition.

16. A multilayer coating system according to claim 1, characterized in that coating composition b) comprises a curing agent capable of chemical reaction with functional groups present in coating composition b).

13. A multilayer coating system comprising

at least one layer a) comprising a coating composition a) comprising at least one isocyanate-functional compound and at least one thiol-functional compound, and

at least one layer b) comprising a non-aqueous coating composition b),

at least one layer a) and at least one layer b) having at least one conunon layer boundary, characterized in that coating composition b) comprises an effective amount of at least one component of a co-catalyst comprising a phosphine component and a Michael acceptor component, and the other of phosphine component and Michael acceptor component is present in coating composition a).

17. A process of preparing a multilayer coating system comprising the steps of

i. applying a layer b) of a non-aqueous coating composition b) comprising an effective amount of a catalyst for the addition reaction of a thiol-functional compound and an isocyanate-functional compound to a substrate,

ii. prior to or subsequent to the application of layer b) applying a layer a) of a coating composition a) comprising at least one isocyanate-functional compound and at least one thiol-functional compound so that layer a) and layer b) have at least one common layer boundary, and

iii. curing layer a) at room temperature or elevated temperature.

18. A process according to claim 17, characterized in that it is implemented for finishing or refinishing of automobiles, large transportation vehicles, or parts thereof.

21. A process according to claim 17, characterized in that the curing is supported by irradiation with UV and/or visible light.

19. A method of reducing the strike-in effect in a multilayer coating system comprising applying a clear coat composition a) comprising at least one isocyanate-functional compound and at least one thiol-functional compound on top of a base coat layer b) prepared from a non-aqueous base coat composition b) comprising an effective amount of a catalyst for the addition reaction of the at least one thiol-functional compound and the at least one isocyanate-functional compound.

20. A kit of parts for the preparation of a non-aqueous base coat composition comprising a toner module comprising at least one resin and at least one colour and/or effect imparting pigment, a connector module comprising at least one resin compatible with the resin of the toner module, and a reducer module essentially free of resins and pigments, wherein at least one of the reducer module and the connector module comprises an effective amount of a catalyst for the addition reaction of a thiol-functional compound and an isocyanate-flnctional compound.