Zero emissions closed rankine cycle power system

• US 20070204620A1
• Filed: 04/30/2007
• Published: 09/06/2007
• Est. Priority Date: 04/16/2004
• Status: Active Grant

• Current Assignee: World Energy Systems
• Original Assignee: World Energy Systems
• Inventors: Viteri, Fermin, Anderson, Roger, Pronske, Keith
• Granted Patent: US 7,882,692 B2
• Time in Patent Office: Days
• US Class Current: 60/671
• CPC Class Codes: F01K 23/10 with exhaust fluid of one cycle heating the fluid in another cycle F01K17/025 takes precedence
• CPC Class Codes: F01K 3/18 having heaters having both steam accumulator and heater F01K3/14; steam heaters per se F22
• CPC Class Codes: F01K 3/188 using heat from a specified chemical reaction
• CPC Class Codes: F25J 2230/06 Adiabatic compressor, i.e. without interstage cooling
• CPC Class Codes: F25J 2240/70 Steam turbine, e.g. used in a Rankine cycle
• CPC Class Codes: F25J 2240/82 with waste heat recovery, e.g. in a combined cycle, i.e. for generating steam used in a Rankine cycle
• CPC Class Codes: F25J 2250/40 One fluid being air
• CPC Class Codes: F25J 2250/50 One fluid being oxygen
• CPC Class Codes: F25J 2260/80 Integration in an installation using carbon dioxide, e.g. for EOR, sequestration, refrigeration etc.
• CPC Class Codes: F25J 3/04018 of main feed air
• CPC Class Codes: F25J 3/04127 Gas turbine as the prime mechanical driver
• CPC Class Codes: F25J 3/04533 for the direct combustion of fuels in a power plant, so-called "oxyfuel combustion"
• CPC Class Codes: F25J 3/04545 for the gasification of solid or heavy liquid fuels, e.g. integrated gasification combined cycle [IGCC]
• CPC Class Codes: F25J 3/04618 for cooling an air stream fed to the air fractionation unit
• CPC Class Codes: Y02E 20/34 Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Abstract

A fuel combustion power generation system is provided operating as a closed loop Rankine cycle and with zero atmospheric emissions. The fuel is combusted with oxygen in a combustor to generate high temperature products of combustion. The products of combustion are routed to a first side of a heat exchanger. A second side of the heat exchanger has a working fluid of the closed loop Rankine cycle passed therethrough to boil the working fluid into a gas. The working fluid is then expanded, condensed back to a liquid and pumped back to high pressure for return to the heat exchanger the products of combustion enter a condenser, where gases are collected and liquids recirculated or released. The products of combustion can be expanded upstream of the heat exchanger. The fuel can be a gaseous fuel or a solid or liquid fuel, such as coal or biomass, with gasification before combustion.

Claims

1. A zero emissions closed Rankine cycle power generation system, comprising in combination:

a closed Rankine cycle working fluid recirculation loop including a working fluid heater, a working fluid expander, a working fluid condenser and a working fluid pump;

a source of oxidizer, the oxidizer being a majority oxygen;

a source of fuel, the fuel being capable of combustion with oxygen to produce elevated temperature products of combustion;

a combustor having an oxidizer inlet downstream from said source of oxidizer, a fuel inlet downstream from said source of fuel, said combustor adapted to combust the fuel with the oxygen to produce elevated temperature products of combustion including water and carbon dioxide, and an outlet adapted to discharge the elevated temperature products of combustion from the combustor;

a heat exchanger downstream from said combustor outlet, said heat exchanger adapted to transfer heat from said elevated temperature products of combustion to the working fluid of said closed Rankine cycle as at least a portion of said working fluid heater; and

wherein said source of fuel includes both hydrocarbon fuel and carbon dioxide, at least a portion of the carbon dioxide in said source of fuel being carbon dioxide formed as a product of combustion of the hydrocarbon fuel with oxygen within said combustor.

2. The system of claim 1 wherein said source of fuel includes methane.

3. The system of claim 1 wherein said combustor includes a water inlet, said combustor adapted to combine water from said water inlet with the elevated temperature products of combustion before discharge from said combustor from said outlet.

4. The system of claim 3 wherein the water produced within said combustor is at least partially routed to said water inlet, such that the water entering said combustor at said water inlet is at least partially water produced within said combustor previously.

5. The system of claim 4 wherein a condenser is located downstream of said outlet of said combustor, said condenser adapted to condense water within the products of combustion from steam to liquid water, said condenser including a liquid water outlet oriented upstream from said water inlet of said combustor;

and a water preheater located between said liquid water outlet of said condenser and said water inlet of said combustor, said water preheater adapted to transfer heat from the products of combustion between said outlet of said combustor and said condenser to the water passing from said condenser to said combustor.

6. The system of claim 5 wherein said water preheater is adapted to heat the water therein sufficiently to boil the water from liquid water into steam, and wherein the water at said water inlet is steam.

7. The system of claim 1 wherein said oxygen from said source of oxidizer is in a gaseous phase.

8. The system of claim 1 wherein said oxygen from said source of oxidizer is substantially free of water until said oxygen enters said combustor.

9. The system of claim 1 wherein said source of oxidizer includes an air separator, said air separator including an inlet for air and an outlet for oxidizer which is a majority oxygen, said air separator adapted to separate at least a portion of oxygen in the air from nitrogen in the air.

10. The system of claim 1 wherein an expander is located downstream of said outlet of said combustor, said expander adapted to expand flow discharged from said combustor, said expander including a discharge.

11. The system of claim 10 wherein said expander includes at least one turbine.

12. The system of claim 10 wherein said expander is located upstream of said heat exchanger.

13. The system of claim 1 wherein the working fluid of said closed Rankine cycle recirculating loop is water.

14. The system of claim 1 wherein the system includes a separator for the products of combustion, said separator including an outlet for primarily carbon dioxide.

15. The system of claim 14 wherein said separator includes a condenser for the water, and said outlet for primarily carbon dioxide being an outlet for gases not condensing within said condenser.

16. The system of claim 15 wherein said outlet for primarily carbon dioxide includes at least one pump to pressurize the carbon dioxide to a pressure at least as great as a pressure within a terrestrial formation, and wherein said outlet for primarily carbon dioxide is coupled to a feed well adapted to deliver the carbon dioxide into the terrestrial formation.

17. The system of claim 16 wherein said terrestrial formation includes a natural gas pocket;

and

wherein said source of fuel includes natural gas from said natural gas pocket to which said outlet for primarily carbon dioxide is coupled.

18. A zero emissions power generation system featuring carbon dioxide recirculation with the fuel, comprising in combination:

a source of oxidizer, the oxidizer being a majority oxygen;

a source of hydrocarbon fuel, the fuel being capable of combustion with oxygen to produce elevated temperature products of combustion including water and carbon dioxide;

a combustor having an oxidizer inlet downstream from said source of oxidizer, a fuel inlet downstream from said source of fuel, said combustor adapted to combust the fuel with the oxygen to produce the elevated temperature products of combustion, and an outlet adapted to release the elevated temperature products of combustion from the combustor;

an expander located downstream from said combustor outlet, said expander adapted to expand the products of combustion, and having a discharge; and

wherein said source of fuel includes both hydrocarbon fuel and carbon dioxide, at least a portion of the carbon dioxide in said source of fuel being carbon dioxide formed as a product of combustion of the hydrocarbon fuel with oxygen within said combustor.

19. The system of claim 18 wherein said source of fuel includes methane.

20. The system of claim 18 wherein said combustor includes a water inlet, said combustor adapted to combine water from said water inlet with the elevated temperature products of combustion before discharge from said combustor from said outlet.

21. The system of claim 20 wherein at least one of the elevated temperature products of combustion is water, and wherein the water produced within said combustor is at least partially routed to said water inlet, such that the water entering said combustor at said water inlet is at least partially water produced within said combustor previously and said water acts as at least a portion of an at least partially open direct heating Rankine cycle.

22. The system of claim 21 wherein a condenser is located downstream of said outlet of said combustor, said condenser adapted to condense water within the products of combustion from steam to liquid water, said condenser including a liquid water outlet oriented upstream from said water inlet of said combustor;

and a water preheater located between said liquid water outlet of said condenser and said water inlet of said combustor, said water preheater adapted to transfer heat from the products of combustion between said outlet of said combustor and said condenser to the water passing from said condenser to said combustor.

23. The system of claim 18 wherein the system includes a separator for the products of combustion, said separator including an outlet for primarily carbon dioxide, said separator including a condenser for the water, and said outlet for primarily carbon dioxide being an outlet for gases not condensing within the condenser;

and wherein said outlet for primarily carbon dioxide includes at least one pump to pressurize the carbon dioxide to a pressure at least as great as a pressure within a terrestrial formation, and wherein said outlet for primarily carbon dioxide is coupled to a feed well adapted to deliver the carbon dioxide into the terrestrial formation, the terrestrial formation adapted to deliver hydrocarbon fuel to said source of fuel.

24. The system of claim 18 wherein a heat exchanger is located downstream from said discharge, said heat exchanger adapted to transfer heat from said products of combustion to a working fluid of a closed Rankine cycle working fluid recirculation loop including a working fluid heater, a working fluid expander, a working fluid condenser and a working fluid pump, with said heat exchanger providing at least a portion of said working fluid heater.

25. An oxy-fuel combustion power generation system with at least partially CO2 recirculating sequestration, comprising in combination:

a combustor having a fuel inlet and an oxidizer inlet;

said combustor adapted to combust the hydrocarbon fuel from said fuel inlet with oxygen from said oxidizer inlet to produce products of combustion including water and carbon dioxide;

an expander adapted to expand the products of combustion and output power from the system;

a condenser adapted to condense water within the products of combustion from a gaseous phase to a liquid phase, said condenser including a liquid outlet for primarily water and a gaseous outlet for primarily carbon dioxide;

a carbon dioxide injector adapted to put CO2 from said condenser into a hydrocarbon fuel reservoir; and

a hydrocarbon fuel well accessing said hydrocarbon fuel reservoir, said hydrocarbon fuel well adapted to remove a combination of hydrocarbon fuel and carbon dioxide from said hydrocarbon fuel reservoir, at least a portion of the carbon dioxide removed by said hydrocarbon fuel well being carbon dioxide put into said hydrocarbon fuel reservoir by said carbon dioxide injector.

26. The system of claim 25 wherein said fuel inlet of said combustor is coupled to a source of fuel including at least a portion of the carbon dioxide with the hydrocarbon fuel at the well, such that the carbon dioxide in the hydrocarbon fuel reservoir and removed therefrom through the hydrocarbon fuel well is at least partially routed into the combustor along with said hydrocarbon fuel at said fuel inlet.

27. The system of claim 26 wherein said source of fuel is adapted to receive a combination of the hydrocarbon fuel and the carbon dioxide from the hydrocarbon fuel well without removal of carbon dioxide therefrom.

28. The system of claim 25 wherein said hydrocarbon fuel is natural gas containing a majority methane.