Field portable electrochemical sensor for uranium and other actinides

• US 20070221510A1
• Filed: 11/15/2006
• Published: 09/27/2007
• Est. Priority Date: 11/15/2005
• Status: Abandoned Application

• Current Assignee: Boise State University
• Original Assignee: Boise State University
• Inventors: Knowlton, William, Russell, Dale
• Application Number:
  US11/600,663
• Publication Number:
  US 20070221510A1
• Time in Patent Office: Days
• US Class Current: 205/789.500
• CPC Class Codes: G01N 27/414 Ion-sensitive or chemical field-effect transistors, i.e. ISFETS or CHEMFETS

Abstract

An actinyl-selective polymer detects the presence of actinide ions in a solution. An electrode or FET gate surface of a sensor element may be coated or otherwise made to include the actinyl-selective polymer, which preferably includes chelating molecules selective to ions having the general formula MO₂^X, where M represents any metal in the actinide group and X represents 1+, 2+, or any other charge state, including uranium ions (UO₂²⁺), plutonium ions (PuO₂²⁺, PuO₂¹⁺), and thorium ions (ThO₂¹⁺) and others. The chelating polymer is preferably made by first polymerizing a selected monomer and then derivatizing the polymer with a calix[n]arene rings (where n=4-10) compound, resulting in a high density of chelating molecules on the surface of the polymer, where they are accessible to the solutions being testing and cleansing or rejuvenating solutions.

Claims

1. A sensor for uranium and other actinides, comprising:

an actinyl-selective polymer containing chelating molecules selective for actinyl ions;

said actinyl-selective polymer being combined with a sensor element which is adapted to detect changes in the electrical potential or conducting properties of the polymer in the presence of actinyl ions.

2. The sensor of claim 1 wherein the polymer contains chelating molecules selective to ions having the general formula MO₂^X, where M represents a metal in the actinide group and X represents a charge of +1 or +2.

3. The sensor of claim 2 wherein the polymer contains chelating molecules selective to ions selected from the group consisting of:

UO₂²⁺, PuO₂²⁺, PuO₂¹⁺, and ThO₂¹⁺.

4. The sensor of claim 1 wherein the polymer is made by first polymerizing a monomer and then derivatizing the polymer with a calix[n]arene ring (where n=4-10) compound.

5. The sensor of claim 1 wherein said chelating molecules comprise a calix[n]arene ring (where n=4-10) compound.

6. The sensor of claim 1 wherein said chelating molecules comprise a calix[6]arene ring compound.

7. The sensor of claim 1 wherein the sensor element comprises a Metal Oxide Semi-Conductor Field-Effect Transistor (MOSFET).

8. The sensor of claim 1 which comprises multiple sensing elements wherein there is at least one voltametric electrode sensor element and at least one MOSFET sensor element.

9. A method of sensing uranium and other actinides, the method comprising:

providing an actinyl-selective polymer containing chelating molecules selective for actinyl ions;

exposing said polymer to a liquid containing actinyl ions; and

detecting changes in electrical potential or conducting properties of said polymer in the presence of said actinyl ions.

10. The method of claim 9 wherein the polymer contains chelating molecules selective to ions having the general formula MO₂^x, where M represents a metal in the actinide group and X represents a charge of +1 or +2.

11. The method of claim 10 wherein the polymer contains chelating molecules selective to ions selected from the group consisting of:

UO₂²⁺, PuO₂²⁺, PuO₂¹⁺, and ThO₂¹⁺,

12. The method of claim 9 wherein the polymer is made by first polymerizing a monomer and then derivatizing the polymer with a calix[n]arene ring (where n=4-10) compound.

13. The method of claim 9 wherein said chelating molecules comprise a calix[n]arene ring (where n=4-10) compound.

14. The sensor of claim 9 wherein said chelating molecules comprise a calix[6]arene ring compound.

15. The method of claim 9 wherein said actinyl-selective polymer is operatively connected to a sensor element comprising a Metal Oxide Semi-Conductor Field-Effect Transistor (MOSFET) and said MOSFET performs said detecting of changes in electrical potential or conducting properties of said polymer.

16. The method of claim 9 wherein said actinyl-selective polymer is operatively connected to multiple sensing elements wherein there is at least one voltametric electrode sensor element and at least one MOSFET sensor element.

17. The method of claim 16, further comprising using said multiple sensing elements to measure total actinide concentration, to measure concentration of individual actinide species, and to crosscheck accuracy of individual ones of said multiple sensing elements.