Fuel cell stack

• US 20070231664A1
• Filed: 03/26/2007
• Published: 10/04/2007
• Est. Priority Date: 03/30/2006
• Status: Abandoned Application

• Current Assignee: Elringklinger AG
• Original Assignee: Elringklinger AG
• Inventors: Fritz, Wolfgang, Schenk, Peter, Zerfass, Hans-Rainer, Diez, Armin
• Application Number:
  US11/728,440
• Publication Number:
  US 20070231664A1
• Time in Patent Office: Days
• US Class Current: 429/442
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 8/0206 Metals or alloys
• CPC Class Codes: H01M 8/0247 characterised by the form characterised by a channel configuration H01M8/0258
• CPC Class Codes: H01M 8/0254 corrugated or undulated
• CPC Class Codes: H01M 8/0271 Sealing or supporting means around electrodes, matrices or membranes
• CPC Class Codes: H01M 8/0273 with sealing or supporting means in the form of a frame
• CPC Class Codes: H01M 8/0297 Arrangements for joining electrodes, reservoir layers, heat exchange units or bipolar separators to each other H01M8/0271 takes precedence
• CPC Class Codes: H01M 8/2425 High-temperature cells with solid electrolytes
• CPC Class Codes: H01M 8/2432 Grouping of unit cells of planar configuration
• CPC Class Codes: H01M 8/247 Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
• CPC Class Codes: H01M 8/2484 characterised by external manifolds
• CPC Class Codes: H01M 8/2485 Arrangements for sealing external manifolds; Arrangements for mounting external manifolds around a stack
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

In order to produce a fuell cell stack which comprises a plurality of fuel cell units succeeding one another in the direction of the pile and wherein each of the fuel cell units comprises a housing incorporating at least one housing part consisting of a metallic material, such that the fuel cell units thereof are of simple construction and also exhibit an adequate electrically insulating effect and adequate mechanical rigidity even at a high operating temperature of the fuel pile, it is proposed that the fuell cell stack should comprise at least one distributor element which comprises at least one gas distribution channel for supplying a fuel gas or an oxidizing agent to a plurality of fuel cell units or for removing an exhaust gas or surplus oxidizing agent from a plurality of fuel cell units, wherein at least one housing part of at least one fuel cell unit is brazed to the at least one distributor element.

Claims

1. A fuell cell stack comprising a plurality of fuel cell units succeeding one another in a direction of the pile, wherein each of the fuel cell units comprises a housing incorporating at least one housing part which consists of a metallic material,

wherein the fuell cell stack comprises at least one distributor element which comprises at least one gas distribution channel for supplying a fuel gas or an oxidizing agent to a plurality of fuel cell units or for removing exhaust gas or surplus oxidizing agent from a plurality of fuel cell units,

wherein at least one housing part of at least one fuel cell unit is brazed to the at least one distributor element.

2. A fuell cell stack in accordance with claim 1, wherein the at least one housing part and the distributor element are brazed to one another by means of a braze material which is electrically insulating at the operating temperature of the fuell cell stack.

3. A fuell cell stack in accordance with claim 1, wherein the at least one housing part is provided with a coating of a ceramic material and is brazed to the at least one distributor element at at least one position that is provided with the ceramic coating.

4. A fuell cell stack in accordance with claim 1, wherein the at least one distributor element is provided with a coating of a ceramic material and is brazed to the at least one housing part at at least one position that is provided with the ceramic coating.

5. A fuell cell stack in accordance with claim 3, wherein the at least one housing part and the at least one distributor element are brazed to one another by means of a metallic braze.

6. A fuell cell stack in accordance with claim 3, wherein the ceramic coating comprises aluminium oxide and/or titanium dioxide and/or zirconium dioxide and/or magnesium oxide.

7. A fuell cell stack in accordance with claim 3, wherein the ceramic coating is produced by a thermal spraying process, in particular by an atmospheric plasma spraying process, by a vacuum plasma spraying process or by a flame spraying process.

8. A fuell cell stack in accordance with claim 3, wherein the at least one housing part and/or the at least one distributor element is formed from a metallic alloy which contains an oxidisable constituent.

9. A fuell cell stack in accordance with claim 8, wherein the metallic alloy contains aluminium and/or zirconium as the oxidisable constituent.

10. A fuell cell stack in accordance with claim 8, wherein the ceramic coating is produced by oxidation of an oxidisable constituent of the metallic alloy.

11. A fuell cell stack in accordance with claim 3, wherein the thickness of the ceramic coating is approximately 20 μ

m to approximately 1,000 μ

m.

12. A fuell cell stack in accordance with claim 3, wherein the at least one housing part is brazed to the at least one distributor element by means of a silver based braze incorporating a copper additive.

13. A fuel cell stack in accordance with claim 3, wherein the at least one housing part is brazed to the at least one distributor element by means of a silver based braze without a copper additive.

14. A fuell cell stack in accordance with claim 13, wherein the silver based braze contains an additive of copper oxide.

15. A fuell cell stack in accordance with claim 3, wherein the at least one housing part is brazed to the at least one distributor element by means of a silver based braze incorporating a titanium additive.

16. A fuell cell stack in accordance with claim 3, wherein the at least one housing part is brazed to the at least one distributor element by means of an active braze.

17. A fuell cell stack in accordance with claim 1, wherein the housing of at least one fuel cell unit comprises at least two housing parts made of a metallic material which are both brazed to the at least one distributor element.

18. A fuell cell stack in accordance with claim 17, wherein the at least two housing parts of the housing of the at least one fuel cell unit are fixed together, preferably by welding and/or brazing.

19. A fuell cell stack in accordance with claim 1, wherein the at least one housing part comprises at least one passage opening, through which, in the assembled state of the fuell cell stack, a cathode electrolyte anode unit of the fuel cell unit is accessible for enabling electrical contact to be made by another fuel cell unit of the fuell cell stack.

20. A fuell cell stack in accordance with claim 1, wherein the at least one housing part comprises a contact field for making electrical contact with a cathode electrolyte anode unit of another fuel cell unit of the fuell cell stack.

21. A fuell cell stack in accordance with claim 1, wherein the at least one housing part is formed from a metal sheet.

22. A fuell cell stack in accordance with claim 1, wherein the at least one housing part is formed from a highly corrosion resistant steel.

23. A fuell cell stack in accordance with claim 1, wherein the at least one housing part does not comprise a passage opening for a fuel gas, an oxidizing agent or an exhaust gas.

24. A fuell cell stack in accordance with claim 1, wherein the housing of at least one fuel cell unit comprises at least one passage opening for a fuel gas, an oxidizing agent or an exhaust gas which is connected to a gas distribution channel in the at least one distributor element.

25. A fuell cell stack in accordance with claim 24, wherein the at least one distributor element comprises at least one gas branch channel which branches off from the at least one gas distribution channel and via which the at least one passage opening in the housing of the at least one fuel cell unit is connected to the at least one gas distribution channel.

26. A fuell cell stack in accordance with claim 24, wherein the at least one passage opening is bounded laterally by at least one region of the housing of the fuel cell unit which comprises a folded edge.

27. A fuell cell stack in accordance with claim 1, wherein the at least one distributor element comprises at least one seating for the at least one housing part which accommodates a boundary region of the housing part.

28. A fuell cell stack in accordance with claim 1, wherein the fuell cell stack comprises at least two distributor elements which each incorporate at least one gas distribution channel, and wherein the at least one housing part of at least one fuel cell unit is brazed on two mutually opposite sides thereof to a respective one of the distributor elements.