Acrylic Resin Films and Process for Producing the Same

• US 20070243364A1
• Filed: 04/22/2005
• Published: 10/18/2007
• Est. Priority Date: 04/28/2004
• Status: Abandoned Application

• Current Assignee: Toray Industries Incorporated
• Original Assignee: Toray Industries Incorporated
• Inventors: Moriyama, Hideki, Tsukuda, Akimitsu, Horiuchi, Mitsuhiro, Maekawa, Shigetoshi
• Application Number:
  US11/578,789
• Publication Number:
  US 20070243364A1
• Time in Patent Office: Days
• US Class Current: 428/220
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 33/04 Homopolymers or copolymers of esters C08L43/04 takes precedence
• CPC Class Codes: C08L 33/06 of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
• CPC Class Codes: C08L 33/064 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence

Abstract

An acrylic resin film, in which acrylic elastic particles are mixed with an acrylic resin containing glutaric anhydride units, has a total light transmittance of 91% or more, a haze value of 1.5% or less, a folding endurance value (times) of 20 or more, and a heat shrinkage rate of less than 5% at least in either the machine direction or the transverse direction in a heat shrinkage test.

Claims

1. An acrylic resin film made of a material mainly composed of a mixture consisting of 50 to 95 parts by mass of an acrylic resin (A) containing glutaric anhydride units, each represented by the following formula (1), and 5 to 50 parts by mass of acrylic elastic particles (B), with the total amount of the acrylic resin (A) and the acrylic elastic particles (B) as 100 parts by mass, and satisfying the following (i) to (v):

(i) the acrylic resin (A) consists of 50 to 90 parts by mass of methyl methacrylate units and 10 to 50 parts by mass of glutaric anhydride units with the amount of the entire acrylic resin (A) as 100 parts by mass;

(ii) the total light transmittance is 91% or more;

(iii) the haze value is 1.5% or less;

(iv) the folding endurance value (times) is 20 or more;

(v) the heat shrinkage rate in at least either the longitudinal direction or the transverse direction is less than 5% in a heat shrinkage test;

(where R1 and R2 denote, each independently, a hydrogen atom or alkyl group with 1 to 5 carbon atoms.)

2. An acrylic resin film, according to claim 1, which has an elongation at breakage of 10% or more.

3. An acrylic resin film, according to claim 1, wherein the retardation in the plane of the film to light with a wavelength of 590 nm is 10 nm or less.

4. An acrylic resin film, according to claim 1, wherein the retardation in the thickness direction of the film to light with a wavelength of 590

5. An acrylic resin film, according to claim 1, wherein the coefficient of photoelasticity to light with a wavelength of 550 nm is −

2×

10<sup>−

12</sup>/Pa to 2×

10<sup>−

12</sup>/Pa.

6. An acrylic resin film, according to claim 1, which contains 0.01 part by mass to 5 parts by mass of an ultraviolet light absorber, with the total amount of the acrylic resin (A) and the acrylic elastic particles (B) as 100 parts by mass.

7. An acrylic resin film, according to claim 1, wherein the light transmittance of light of 380 nm is 10% or less.

8. An acrylic resin film, according to claim 1, wherein the particle size of the acrylic elastic particles (B) is 50 nm to 400 nm.

9. An acrylic resin film, according to claim 1, wherein each of the acrylic elastic particles (B) consists of an inner layer made of an elastic rubber containing alkyl acrylate units and/or an aromatic vinyl and an outer layer made of a hard polymer mainly composed of an acrylic resin containing glutaric anhydride units;

and the difference between the acrylic elastic particles (B) and the acrylic resin (A) in refractive index is 0.01 or less.

10. An acrylic resin film, according to claim 1, which has a thermal deformation temperature of 110°

C. or higher.

11. An acrylic resin film, according to claim 1, wherein the remaining volatile content is 3 parts by mass or less per 100 parts by mass of the acrylic resin film.

12. An acrylic resin film, according to claim 1, which has a hard coat layer formed at least on one surface of the film, and further has a reflection preventive film formed at least on one surface of the film.

13. An optical filter comprising the acrylic resin film as set forth in claim 1.

14. A polarizing plate protective film, comprising the acrylic resin film as set forth in claim 1.

15. A production method comprising the step of producing the acrylic resin film as set forth in claim 1 using a solution casting method.

16. A method for producing an acrylic resin film, comprising the step of stretching a substantially unstretched acrylic resin film at a temperature in a range from the glass transition temperature (Tg) to {the glass transition temperature (Tg)+50°

C.} to 1.1 to 5.0 times in the longitudinal direction and in the transverse direction.