Detection and identification method for in-transit determination of chemical contraband, decaying animal and vegetable matter, and concealed humans in cargo shipping containers and other secure spaces

• US 20070277589A1
• Filed: 05/31/2006
• Published: 12/06/2007
• Est. Priority Date: 05/31/2006
• Status: Active Grant

• Current Assignee: Charles S. Harden, Joseph C. Harden
• Original Assignee: Charles S. Harden, Joseph C. Harden
• Inventors: Harden, Charles S., Harden, Joseph C.
• Granted Patent: US 7,468,672 B2
• Time in Patent Office: Days
• US Class Current: 73/31.30
• CPC Class Codes: G01N 27/622 Ion mobility spectrometry

Abstract

A chemical analysis method for detecting, identifying and reporting contraband, illegal drugs, explosives, toxic chemicals, decaying animal and vegetable matter, and concealed human beings located in secure spaces such as cargo shipping containers. Chemical analysis results are accumulated and added to effect definitive analyses over extended periods of time while the containers are in transit. Individual containers are equipped with a device employing the method. The analysis method consists of accumulation and addition of analytical chemical instrumentation, measurements of trace quantities of target chemical vapors inside of shipping containers while the containers are in transit. Cumulative and additive spectrometric analyses coupled with increased target chemical concentrations, due to chemical vapor build up over the long periods of time that containers are in transit, result in significantly increased electronic signal-to-noise in spectrometric measurements and increased spectrometric signal strengths that are indicative of the presence of target chemicals.

Claims

1. A method for detection and identification of illegal drugs, explosives, toxic chemicals, decaying animal and vegetable matter, and concealed human beings located in confined spaces of shipping containers, storage containers and other cargo containers and secure spaces, the method comprising the steps of:

providing an analytical chemical detector which has low power requirements and is powered by a battery to operate the detector and to sample the atmosphere within the confined spaces,

disposing the analytical chemical detector in said confined spaces for a period of time wherein there is an accumulation of target chemicals associated with the illegal drugs, explosives, toxic chemicals, decaying animal and vegetable matter, and human effluvia, the analytical chemical detector being sensitive to minute concentrations of the target chemicals,

providing a means for accumulating, adding and processing chemical analysis measurements periodically over said period of time as the target chemicals accumulate to significant concentrations in said confined spaces,

providing digital signal processing algorithms to identify the target chemicals,

providing a means for reporting the presence of the target chemicals to a device located outside of the confined spaces.

2. The method of claim 1, wherein the analytical chemical detector is an ion mobility spectrometry device.

3. The method of claim 1, wherein electronically stored libraries of target chemicals are provided to the analytical chemical detector, said libraries being compared to the samples of the atmosphere taken by the chemical agent detector.

4. The method of claim 3, wherein the libraries include data on vapors emanating from drugs and drug impurities, said vapors including precursors and solvents used during the manufacture of the drugs.

5. The method of claim 3, wherein the libraries include data on vapors emanating from explosives and impurities in explosives such as precursors, decomposition products, and chemical taggants.

6. The method of claim 3, wherein the libraries include data on vapors emanating from toxic chemical compounds used as weapons of mass destruction, chemical warfare agents, and impurities in toxic chemical compounds such as precursors and decomposition products.

7. The method of claim 3, wherein the libraries include data on vapors emanating from decaying animal and vegetable matter.

8. The method of claim 4, wherein the libraries include data on gaseous effluvia emanating from humans.

9. The method of claim 1, further providing means for interfacing the analytical chemical detector to other electronic security systems such as those programmed for determinations of container breach, tracking the container, and communicating contraband detection data to appropriate authorities and databases.

10. The method of claim 1, wherein microgram and nanogram quantities of target chemicals are detected.

11. The method of claim 1, wherein the analytical chemical detector samples the target chemicals which diffuse through the confined spaces.

12. A method for detection and identification of predetermined target chemicals in confined spaces of shipping containers, storage containers and other cargo containers in secure spaces, the method comprising the steps of:

disposing a small, low-powered ion mobility spectrometer in the container, the spectrometer having a library of spectra of the predetermined target chemicals,

obtaining an analysis spectrum of the confined spaces of the container,

storing the analysis spectrum in the memory of the ion mobility spectrometer,

comparing the analysis spectrum with the spectra in the library of the spectrometer, and

providing a report of detection and identification when the spectrum of the sampled confined space corresponds with a spectrum in the library.

13. A method for detection and identification of predetermined target chemicals in confined spaces of shipping containers, storage containers, and other cargo containers and secure spaces, the method comprising the steps of:

disposing a small, low-powered ion mobility spectrometer in the container, the spectrometer having a library of spectra of the predetermined target chemicals,

obtaining an analysis spectrum of the confined spaces of the container,

deconvolving the analysis spectrum and storing it in the memory of the ion mobility spectrometer,

comparing the deconvolved analysis spectrum with the library of the spectrometer, and

providing a report of detection and identification when the deconvolved spectrum of the sampled confined spaces correspond with a spectrum in the library.

14. A method for detection and identification of predetermined target chemicals in confined spaces of refrigerated shipping containers, storage containers and other cargo containers in secure spaces, the method comprising the steps of:

disposing a small, low-powered ion mobility spectrometer in the refrigerated container, the spectrometer having a library of spectra of the predetermined target chemicals,

pre-concentrating vapors of the target chemicals by collecting the vapors on an adsorbing media,

desorbing the collected vapors of the target chemicals into the ion mobility spectrometer,

comparing the analysis spectrum with the spectra in the library of the spectrometer, and

providing a report of detection and identification when the spectrum of the sampled confined space corresponds with a spectrum in the library.

15. The method of claim 14, further comprising coupling a gas chromatograph with the ion mobility spectrometer.