Spectacle Lens and Polycarbonate Resin Molding Material for Optical Moldings

• US 20070299168A1
• Filed: 10/28/2005
• Published: 12/27/2007
• Est. Priority Date: 11/05/2004
• Status: Active Grant

• Current Assignee: Teijin Chemicals Ltd. (Teijin Limited)
• Original Assignee: Teijin Chemicals Ltd. (Teijin Limited)
• Inventors: Ariki, Jiro, Tanabe, Seiichi
• Granted Patent: US 7,786,195 B2
• Time in Patent Office: Days
• US Class Current: 524/91
• CPC Class Codes: C08K 2201/014 Additives containing two or more different additives of the same subgroup in C08K
• CPC Class Codes: C08K 5/103 with polyalcohols
• CPC Class Codes: C08K 5/3475 condensed with carbocyclic rings
• CPC Class Codes: C08K 5/49 Phosphorus-containing compounds C08K5/0091 takes precedence
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• CPC Class Codes: G02B 1/041 Lenses

Abstract

A spectacle lens made of a polycarbonate resin composition which comprises (1) 100 parts by weight of a polycarbonate resin, (2) 0.05 to 0.5 part by weight of (A) at least one ultraviolet light absorber selected from the group consisting of 2-(2′-hydroxy-5′-methylphenyl)benzotriazole and 2-(2′-hydroxy-5′-tert-octylphenyl)benzotriazole, (3) 0.01 to 0.3 part by weight of (B) at least one ultraviolet light absorber selected from the group consisting of 2-(3-tert-butyl-5-methyl-2-hydroxyphenyl)-5-chlorobenzotriazole, 2,2′-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-(2H-benzotraizole)-2-ylphenol] and 2-[2-hydroxy-3,5-bis(α,α-dimethylbenzyl)phenyl]-2H-benzotriazole, and (4) 0.01 to 0.5 part by weight of (C) a full ester of a tetravalent to octavalent aliphatic polyhydric alcohol having 5 to 30 carbon atoms and an aliphatic carboxylic acid having 10 to 22 carbon atoms, having an acid value of 4 to 20. According to the present invention, the spectacle lens made of the above polycarbonate resin composition has molding heat resistance which enables it to be kept at a high temperature for a long time when the lens is formed by extrusion compression molding, a small change in hue when heat history such as re-extrusion is applied so as to recycle product waste and excellent releasability.

Claims

1. A spectacle lens made of a polycarbonate resin composition which comprises (1) 100 parts by weight of a polycarbonate resin, (2) 0.05 to 0.5 part by weight of (A) at least one ultraviolet light absorber selected from the group consisting of 2-(2′

-hydroxy-5′

-methylphenyl)benzotriazole and 2-(2′

-hydroxy-5′

-tert-octylphenyl)benzotriazole, (3) 0.01 to 0.3 part by weight of (B) at least one ultraviolet light absorber selected from the group consisting of 2-(3-tert-butyl-5-methyl-2-hydroxyphenyl)-5-chlorobenzotriazole, 2,2′

-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-(2H-benzotriazol)-2-ylphenol] and 2-[2-hydroxy-3,5-bis(α

,α

-dimethylbenzyl)phenyl]-2H-benzotriazole, and (4) 0.01 to 0.5 part by weight of (C) a full ester of a tetravalent to octavalent aliphatic polyhydric alcohol having 5 to 30 carbon atoms and an aliphatic carboxylic acid having 10 to 22 carbon atoms, having an acid value of 4 to 20.

2. The spectacle lens according to claim 1, wherein the weight ratio of the above ultraviolet light absorber (B) to the above ultraviolet light absorber (A) in terms of (B)/(A) is in the range of 0.05 to 4.

3. The spectacle lens according to claim 1, wherein the above ultraviolet light absorber (A) is 2-(2′

-hydroxy-5′

-tert-octylphenyl)benzotriazole and the above ultraviolet light absorber (B) is 2,2′

-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-(2H-benzotriazol-2-ylphenol)].

4. The spectacle lens according to claim 1, wherein the aliphatic carboxylic acid of the above full ester (C) contains a palmitic acid component and a stearic acid component, the total of the area (Sp) of the palmitic acid component and the area (Ss) of the stearic acid component is 80% or more of the total of all the aliphatic carboxylic acid components in its peak area measured by gas chromatograph-mass analysis (GC/MS method), and the area ratio (Ss/Sp) of the both components is 1.3 to 30.

5. The spectacle lens according to claim 1, wherein the above full ester (C) has a 5% weight loss temperature measured by TGA (thermogravimetric analysis) of 250 to 360°

C.

6. The spectacle lens according to claim 1, wherein the above full ester (C) has an acid value of 4 to 18.

7. The spectacle lens according to claim 1, wherein the above full ester (C) is a full ester of pentaerythritol and a mixed aliphatic carboxylic acid of palmitic acid and stearic acid.

8. The spectacle lens according to claim 1, wherein the above full ester (C) is contained in an amount of 0.02 to 0.4 part by weight based on 100 parts by weight of the polycarbonate resin.

9. The spectacle lens according to claim 1 which further contains a phosphorus-based heat stabilizer (d) in an amount of 0.001 to 0.2 part by weight based on 100 parts by weight of the polycarbonate resin.

10. The spectacle lens according to claim 9, wherein the phosphorus-based heat stabilizer (d) is a phosphonite.

11. The spectacle lens according to claim 1 which further contains a bluing agent (e) in an amount of 0.1×

10<sup>−

4</sup> to 6×

10<sup>−

4</sup> part by weight based on 100 parts by weight of the polycarbonate resin.

12. The spectacle lens according to claim 1, wherein the polycarbonate resin contains 2,2-bis(4-hydroxyphenyl)propane as the main dihydric phenol component.

13. The spectacle lens according to claim 1 which further contains a lactone-based heat stabilizer (f) represented by the following formula (1) in an amount of 0.0005 to 0.1 part by weight based on 100 parts by weight of the polycarbonate resin:

14. The spectacle lens according to claim 1 which further contains a hindered phenol-based antioxidant (g) in an amount of 0.001 to 0.1 part by weight based on 100 parts by weight of the polycarbonate resin.

15. A polycarbonate resin molding material for optical moldings, which comprises (1) 100 parts by weight of a polycarbonate resin, (2) 0.05 to 0.5 part by weight of (A) at least one ultraviolet light absorber selected from the group consisting of 2-(2′

-hydroxy-5′

-methylphenyl)benzotriazole and 2-(2′

-hydroxy-5′

-tert-octylphenyl)benzotriazole, (3) 0.01 to 0.3 part by weight of (B) at least one ultraviolet light absorber selected from the group consisting of 2-(3-tert-butyl-5-methyl-2-hydroxyphenyl)-5-chlorobenzotriazole, 2,2′

-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-(2H-benzotriazol)-2-ylphenol] and 2-[2-hydroxy-3,5-bis(α

,α

-dimethylbenzyl)phenyl]-2H-benzotriazole, and (4) 0.01 to 0.5 part by weight of (C) a full ester of a tetravalent to octavalent aliphatic polyhydric alcohol having 5 to 30 carbon atoms and an aliphatic carboxylic acid having 10 to 22 carbon atoms, having an acid value of 4 to 20.

16. A polycarbonate resin molding material for optical moldings, which comprises (1) 100 parts by weight of a polycarbonate resin, (2) 0.05 to 0.5 part by weight of 2-(2′

-hydroxy-5′

-tert-octylphenyl)benzotriazole, (3) 0.01 to 0.3 part by weight of 2,2′

-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-(2H-benzotriazol)-2-ylphenol], (4) 0.01 to 0.5 part by weight of (C) a full ester of pentaerythritol and a mixed aliphatic carboxylic acid of palmitic acid and stearic acid, having an acid value of 4 to 20, and (5) 0.001 to 0.2 part by weight of a phosphorus-based heat stabilizer.