POLYESTER RESIN COMPOSITIONS FOR CALENDERING

• US 20080015297A1
• Filed: 08/23/2007
• Published: 01/17/2008
• Est. Priority Date: 03/17/1998
• Status: Active Grant

• Current Assignee: Eastman Chemical Company
• Original Assignee: Eastman Chemical Company
• Inventors: Flynn, Paul, McConnell, Richard, Moolenaar, Hubertus Jacobus, Sanders, Timothy
• Granted Patent: US 7,438,841 B2
• Time in Patent Office: Days
• US Class Current: 524/399
• CPC Class Codes: C08G 63/181 Acids containing aromatic rings
• CPC Class Codes: C08J 2367/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: C08K 5/0008 Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
• CPC Class Codes: C08K 5/098 Metal salts of carboxylic acids
• CPC Class Codes: C08K 5/103 with polyalcohols
• CPC Class Codes: C08K 5/20 Carboxylic acid amides
• CPC Class Codes: C08L 67/00 Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08L77/12; of polyester-imides C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence

Abstract

A polyester resin composition is calendered to produce a film or a sheet. The polyester resin composition is a polyester having a crystallization half time from a molten state of at least 5 minutes combined with an additive for preventing sticking of the polyester to calendering rolls.

Claims

1-32. -32. (canceled)

33. A polyester resin composition for calendering, comprising

(a) a polyester comprising

(i) 100 mole % of terephthalic acid residues as an acid component, and

(ii) 12 to 31 mole % of 1,4-cyclohexanedimenthanol residues and 69 to 88 mole % of ethylene glycol residues as a glycol component;

and

(b) an additive selected from the group consisting of metal salts of organic acids, fatty acids or esters thereof, and glycerol monostearate in an amount sufficient to prevent the polyester from sticking to calender rolls.

34. The polyester resin composition according to claim 33, wherein the metal salts of organic acids are calcium stearate or zinc stearate.

35. The polyester resin composition according to claim 33, wherein the fatty acids or esters thereof are stearic acid, oleic acid, or palmitic acid.

36. The polyester resin composition according to claim 33, wherein the additive is glycerol monostearate.

37. The polyester resin composition according to claim 33, wherein the polyester comprises 100 mole % of terephthalic acid residues, 31 mole % of 1,4-cyclohexanedimethanol residues, and 69 mole % of ethylene glycol residues.

38. The polyester resin composition according to claim 37, wherein the additive is selected from the group consisting of metal salts of organic acids and fatty acids or esters thereof.

39. The polyester resin composition according to claim 33, which comprises from 0.01 to 10 weight percent of the additive.

40. The polyester resin composition according to claim 33, which comprises from 0.5 to 2 weight percent of the additive.

41. A process for manufacturing a polyester film or sheet, comprising

introducing a polyester resin composition in pellet, powder, or molten form between at least two adjacent calender rolls,

wherein the polyester resin composition comprises

(a) a polyester comprising

(i) 100 mole % of terephthalic acid residues as an acid component, and

(ii) 12 to 31 mole % of 1,4-cyclohexanedimenthanol residues and 69 to 88 mole % of ethylene glycol residues as a glycol component;

and

(b) an additive selected from the group consisting of metal salts of organic acids, fatty acids or esters thereof, and glycerol monostearate in an amount sufficient to prevent the polyester from sticking to the calender rolls.

42. The process according to claim 41, wherein the metal salts of organic acids are calcium stearate or zinc stearate.

43. The process according to claim 41, wherein the fatty acids or esters thereof are stearic acid, oleic acid, or palmitic acid.

44. The process according to claim 41, wherein the additive is glycerol monostearate.

45. The process according to claim 41, wherein the polyester comprises 100 mole % of terephthalic acid residues, 31 mole % of 1,4-cyclohexanedimethanol residues, and 69 mole % of ethylene glycol residues.

46. The process according to claim 45, wherein the additive is selected from the group consisting of metal salts of organic acids and fatty acids or esters thereof.

47. The process according to claim 41, wherein the calender rolls are at a temperature of 130°

C. to 250°

C.

48. The process according to claim 41, wherein the calender rolls are at a temperature of 140°

C. to 190°

C.

49. The process according to claim 41, which comprises from 0.01 to 10 weight percent of the additive.

50. The process according to claim 41, which comprises from 0.5 to 2 weight percent of the additive.

51. A calendered film or sheet made from a polyester resin composition comprising

(a) a polyester comprising

(i) 100 mole % of terephthalic acid residues as an acid component, and

(ii) 12 to 31 mole % of 1,4-cyclohexanedimenthanol residues and 69 to 88 mole % of ethylene glycol residues as a glycol component;

and

(b) an additive selected from the group consisting of metal salts of organic acids, fatty acids or esters thereof, and glycerol monostearate in an amount sufficient to prevent the polyester from sticking to calender rolls.

52. The calendered film or sheet according to claim 51, wherein the metal salts of organic acids are calcium stearate or zinc stearate.

53. The calendered film or sheet according to claim 51, wherein the fatty acids or esters thereof are stearic acid, oleic acid, or palmitic acid.

54. The calendered film or sheet according to claim 51, wherein the additive is glycerol monostearate.

55. The calendered film or sheet according to claim 51, wherein the polyester comprises 100 mole % of terephthalic acid residues, 31 mole % of 1,4-cyclohexanedimethanol residues, and 69 mole % of ethylene glycol residues.

56. The calendered film or sheet according to claim 55, wherein the additive is selected from the group consisting of metal salts of organic acids and fatty acids or esters thereof.

57. The calendered film or sheet according to claim 51, which comprises from 0.01 to 10 weight percent of the additive.

58. The calendered film or sheet according to claim 51, which comprises from 0.5 to 2 weight percent of the additive.