Method of Producing a Material of Oxide Superconductor, Method of Producing an Oxide Superconducting Wire, and Superconducting Apparatus

• US 20080020936A1
• Filed: 01/30/2006
• Published: 01/24/2008
• Est. Priority Date: 02/02/2005
• Status: Active Grant

• Current Assignee: Sumitomo Electric Industries Limited (Sumitomo Corporation)
• Original Assignee: Sumitomo Electric Industries Limited (Sumitomo Corporation)
• Inventors: Ayai, Naoki
• Granted Patent: US 7,514,388 B2
• Time in Patent Office: Days
• US Class Current: 505/425
• CPC Class Codes: C01G 1/00 Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general electrolytic production of inorganic compounds C25B1/00
• CPC Class Codes: C01G 1/02 Oxides
• CPC Class Codes: C01G 3/006 Compounds containing, besides copper, two or more other elements, with the exception of oxygen or hydrogen
• CPC Class Codes: C04B 2235/3208 Calcium oxide or oxide-forming salts thereof, e.g. lime
• CPC Class Codes: C04B 2235/3213 Strontium oxides or oxide-forming salts thereof
• CPC Class Codes: C04B 2235/443 Nitrates or nitrites
• CPC Class Codes: C04B 2235/6567 Treatment time
• CPC Class Codes: C04B 2235/661 Multi-step sintering
• CPC Class Codes: C04B 35/4525 also containing lead oxide
• CPC Class Codes: C04B 35/6267 Pyrolysis, carbonisation or auto-combustion reactions
• CPC Class Codes: C04B 35/6268 characterised by the applied pressure or type of atmosphere, e.g. in vacuum, hydrogen or a specific oxygen pressure
• CPC Class Codes: H10N 60/0772 Processes including the use of non-gaseous precursors
• CPC Class Codes: H10N 60/0801 Manufacture or treatment of filaments or composite wires
• CPC Class Codes: Y10T 29/49014 Superconductor

Abstract

A method of producing a material of an oxide superconductor comprises the following steps: (a) in a solution, ionizing a material containing an atom for constituting the oxide superconductor, (b) by removing a solvent by spraying the solution in a first atmosphere, producing a material powder containing the atom for constituting the oxide superconductor, and (c) cooling the material powder in a second atmosphere into which a cooling gas is introduced. In this method, the concentration of carbon dioxide in the second atmosphere is lower than that in the first atmosphere, which contains the removed solvent component. The concentration of nitrogen oxide in the second atmosphere is lower than that in the first atmosphere, which contains the removed solvent component. The concentration of water vapor in the second atmosphere is lower than that in the first atmosphere, which contains the removed solvent component. These specifications enable the method to increase the density and purity of the oxide superconductor.

Claims

1. A method of producing a material of an oxide superconductor, the method comprising the steps of:

(a) in a solution, ionizing a material containing an atom for constituting the oxide superconductor;

(b) by removing a solvent by spraying the solution in a first atmosphere, producing a powder containing the atom for constituting the oxide superconductor; and

(c) cooling the powder in a second atmosphere into which a cooling gas is introduced;

the concentration of carbon dioxide in the second atmosphere being lower than that in the first atmosphere, which contains the removed solvent component;

the concentration of nitrogen oxide in the second atmosphere being lower than that in the first atmosphere, which contains the removed solvent component;

the concentration of water vapor in the second atmosphere being lower than that in the first atmosphere, which contains the removed solvent component.

2. A method of producing a material of an oxide superconductor as defined by claim 1, wherein the step of producing a powder comprises the steps of:

(b1) spraying the solution together with a spraying gas; and

(b2) carrying the solution from the first atmosphere to the second atmosphere by using a carrier gas;

the volume flow rate of the entire gas formed by adding the spraying gas, the carrier gas, and the cooling gas being at least 10,000 times that of the solution.

3. A method of producing a material of an oxide superconductor as defined by claim 1, wherein the step of producing a powder comprises the steps of:

(b1) spraying the solution together with a spraying gas; and

(b2) carrying the solution from the first atmosphere to the second atmosphere by using a carrier gas;

the concentration of the water vapor in the second atmosphere being at most 10 vol.

4. A method of producing a material of an oxide superconductor as defined by claim 1, wherein the step of producing a powder comprises the steps of:

(b1) spraying the solution together with a spraying gas; and

(b2) carrying the solution from the first atmosphere to the second atmosphere by using a carrier gas;

the relationship 0.1 (sec)≦

V/(q₁+q₂)≦

20 (sec) being satisfied,

where q₁ (liter/sec) is the volume flow rate of the first atmosphere'"'"'s gas formed by adding the spraying gas and the carrier gas,

q₂ (liter/sec) is the volume flow rate of the gas generated from the solution, and

V (liter) is the volume of the first atmosphere.

5. A method of producing a material of an oxide superconductor as defined by claim 1, wherein the step of producing a powder comprises the steps of:

(b1) spraying the solution together with a spraying gas; and

(b2) carrying the solution from the first atmosphere to the second atmosphere by using a carrier gas;

each of the spraying gas, the carrier gas, and the cooling gas having a water-vapor concentration of at most 1 vol. %.

6. A method of producing a material of an oxide superconductor as defined by claim 1, wherein the step of producing a powder comprises the steps of:

(b1) spraying the solution together with a spraying gas; and

(b2) carrying the solution from the first atmosphere to the second atmosphere by using a carrier gas;

each of the spraying gas, the carrier gas, and the cooling gas having a carbon dioxide concentration of at most 30 vol. ppm.

7. A method of producing a material of an oxide superconductor as defined by claim 1, the method further comprising a step of heat-treating the powder after the step of cooling the powder.

8. A method of producing a material of an oxide superconductor as defined by claim 7, wherein:

(a) a step is further provided in which the powder is cooled immediately after the heat treatment of it;

(b) both the step of heat-treating the powder and the step of cooling the powder immediately after the heat treatment of it are carried out in a heat-treating apparatus; and

(c) the concentration of water vapor is at most 1 vol. % in each of the following atmospheres;

(c1) the atmosphere in the heat-treating apparatus at the time of the introduction of the powder into the heat-treating apparatus;

(c2) the atmosphere in the heat-treating apparatus at the time of the heat treatment of the powder;

(c3) the atmosphere in the heat-treating apparatus at the time of the cooling of the powder; and

(c4) the atmosphere in the heat-treating apparatus at the time of the taking out of the powder from the heat-treating apparatus.

9. A method of producing a material of an oxide superconductor as defined by claim 7, wherein:

(a) a step is further provided in which the powder is cooled immediately after the heat treatment of it;

(b) both the step of heat-treating the powder and the step of cooling the powder immediately after the heat treatment of it are carried out in a heat-treating apparatus; and

(c) the concentration of carbon dioxide is at most 30 vol. ppm in each of the following atmospheres;

(c1) the atmosphere in the heat-treating apparatus at the time of the introduction of the powder into the heat-treating apparatus;

(c2) the atmosphere in the heat-treating apparatus at the time of the heat treatment of the powder;

(c3) the atmosphere in the heat-treating apparatus at the time of the cooling of the powder; and

(c4) the atmosphere in the heat-treating apparatus at the time of the taking out of the powder from the heat-treating apparatus.

10. A method of producing a material of an oxide superconductor as defined by claim 1, wherein the solution is a nitric acid solution.

11. A method of producing an oxide superconducting wire, the method comprising the steps of:

(a) producing a material of an oxide superconductor by using a method of producing a material of an oxide superconductor, comprising the steps of;

(a1) in a solution, ionizing a material containing an atom for constituting the oxide superconductor;

(a2) by removing a solvent by spraying the solution in a first atmosphere, producing a powder containing the atom for constituting the oxide superconductor; and

(a3) cooling the powder in a second atmosphere into which a cooling gas is introduced;

the concentration of carbon dioxide in the second atmosphere being lower than that in the first atmosphere, which contains the removed solvent component;

the concentration of nitrogen oxide in the second atmosphere being lower than that in the first atmosphere, which contains the removed solvent component;

the concentration of water vapor in the second atmosphere being lower than that in the first atmosphere, which contains the removed solvent component; and

(b) producing an oxide superconducting wire by using the material of the oxide superconductor.

12. An oxide superconducting apparatus, incorporating an oxide superconducting wire produced by a method of producing an oxide superconducting wire the method comprising the steps of:

a) producing a material of an oxide superconductor by using a method of producing a material of an oxide superconductor, comprising the steps of;

a1) in a solution, ionizing a material containing an atom for constituting the oxide superconductor;

a2) by removing a solvent by spraying the solution in a first atmosphere, producing a powder containing the atom for constituting the oxide superconductor; and

a3) cooling the powder in a second atmosphere into which a cooling gas is introduced;

the concentration of carbon dioxide in the second atmosphere being lower than that in the first atmosphere, which contains the removed solvent component;

the concentration of nitrogen oxide in the second atmosphere being lower than that in the first atmosphere, which contains the removed solvent component;

the concentration of water vapor in the second atmosphere being lower than that in the first atmosphere, which contains the removed solvent component; and

(b) producing an oxide superconducting wire by using the material of the oxide superconductor.