Photocatalytically Active Coating of a Substrate

• US 20080026161A1
• Filed: 07/15/2004
• Published: 01/31/2008
• Est. Priority Date: 07/16/2003
• Status: Abandoned Application

• Current Assignee: Christoph Weyer, Frank Gross, Reimund Krechan, Stefan Sepeur, Wolfgang Frings
• Original Assignee: Christoph Weyer, Frank Gross, Reimund Krechan, Stefan Sepeur, Wolfgang Frings
• Inventors: Gross, Frank, Krechan, Reimund, Frings, Wolfgang, Weyer, Christoph, Sepeur, Stefan
• Application Number:
  US10/564,559
• Publication Number:
  US 20080026161A1
• Time in Patent Office: Days
• US Class Current: 427/559
• CPC Class Codes: B01J 21/04 Alumina
• CPC Class Codes: B01J 21/063 Titanium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 21/066 Zirconium or hafnium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 23/02 of the alkali- or alkaline earth metals or beryllium
• CPC Class Codes: B01J 23/20 Vanadium, niobium or tantalum
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: B01J 37/0219 the coating containing organic compounds
• CPC Class Codes: B01J 37/0228 in several steps
• CPC Class Codes: B01J 37/344 of electromagnetic wave energy

Abstract

The invention relates to a photocatalytically active coating of a substrate, which is composed of a protective layer and photocatalytically active particles that are applied thereto, the protective layer having no photocatalytic activity. The protective layer preferably contains ZrO₂ and SiO₂.

Claims

1. A photocatalytically active coating of a substrate composed of at least two layers produced by solution chemistry and with at least one first underlayer applied to the substrate and composed of an inorganic polymer, and comprising the metal oxides SiO₂ and ZrO₂ covalently bonded to one another, and at least one second overlayer composed of TiO₂ particles, characterized in that the underlayer comprises less than 0.5% by weight of TiO₂ particles, is pore-free, and comprises SiO₂ and ZrO₂ in a ratio by weight of from 50:

50 to 95;

5.

2. The photocatalytically active coating as claimed in claim 1, characterized in that the inorganic polymer is composed of one or more metal oxides covalently bonded to one another from the group of SiO₂, ZrO₂, AL₂O₃, Nb₂O₃, Ta₂Q₃, CaO.

3. The photocatalytically active coating as claimed in claim 1 characterized in that the underlayer is composed of at least two layers applied in succession of identical or different constitution.

4. The photocatalytically active coating as claimed in claim 1, characterized in that the substrate used comprises one or more polymers selected from the group of PVC, PP, PE, PMMA, PS, PC, polyesters, epoxy materials, polyurethanes, polyisocyanates, SBR, ABS, ASA, NBR, or copolymers composed of acrylonitrile, styrene, butadiene, methacrylate, or isoprene, in each case in the form of homo- or copolymer, in the form of coextrudate, or in the form of polymer blend.

10. A window profile, a door profile, a roller-shutter segment, a window sill, an architectural panel, a door leaf, a gutter, a downpipe, or a plastics or aluminum shell for the covering of window or door frames, with a coating as claimed in claim 1.

5. A process for production of photocatalytically active coatings on a substrate, characterized by the following steps of the process:

a. coating of a substrate with an inorganic polymer by solution chemistry via application of a suspension of the inorganic polymer or its chemical precursors in an organic suspension medium,

b. complete or partial removal of the organic suspension medium, to give an underlayer.

c. application of a dispersion composed of TiO₂ particles in an organic dispersion medium to the underlayer.

d. complete or partial removal of the organic dispersion medium to give an overlayer.

e. heat-treatment of the under- and overlayer at from 20 to 120°

C. for from 10 to 300 sec, with the proviso that the underlayer is composed of an inorganic polymer, comprises less than 0.5% of TiO₂ particles, is pore-free, and comprises SiO₂ and ZrO₂ in a ratio by weight of from 50;

50 to 95;

5.

6. The process as claimed in claim 5, characterized in that the suspension used in step a) of the process comprises the metal oxides SiO₂ and ZrO₂, and also optionally Al₂O₃, Nb₂O₃, Ta₂O₃, CaO, and/or the corresponding alkoxides, chlorides, nitrates, hydroxides, formates, or acetates.

7. The process as claimed in claim 5, characterized in that the organic suspension and dispersion medium comprises ethanol, propanol, isopropanol, isobutanol, n-butanol, glycol, ethylene glycol, propylene glycol, butylene glycol, water, formic acid, and/or acetic acid, alone or in the form of a mixture.

8. The process as claimed in claim 6, characterized in that steps a) and b) of the process are carried out at least twice in succession.

9. The process as claimed in claim 6, characterized in that steps c) and d) of the process are carried out at least twice in succession.