Integrated photovoltaic-electrolysis cell

• US 20080073205A1
• Filed: 10/11/2007
• Published: 03/27/2008
• Est. Priority Date: 04/11/2005
• Status: Abandoned Application

• Current Assignee: Midwest Optoelectronics, LLC (Iland Green Technologies SA), University of Toledo
• Original Assignee: MWOE Incorporated, University of Toledo
• Inventors: Adiga, Mahabala, Deng, Xunming, Vijh, Aarohi, Xu, Liwei
• Application Number:
  US11/974,191
• Publication Number:
  US 20080073205A1
• Time in Patent Office: Days
• US Class Current: 204/263
• CPC Class Codes: C25B 9/19 with diaphragms

Abstract

A photovoltaic electrolysis (IPE) cell has a photovoltaic component and an electrolysis component which integrated, through an interconnect design, into a single unit.

Claims

1. An integrated photovoltaic electrolysis (IPE) cell, comprising a photovoltaic component and an electrolysis component integrated, through an interconnect design, into a single unit,

wherein the photovoltaic component is comprised of:

a superstrate or a substrate;

a transparent conducting front electrode;

one or more of photovoltaic junction(s); and

,

an electrically conductive back electrode;

and wherein the electrolysis component is comprised of;

an electrolyte;

an enclosure that confines the electrolyte;

a reduction compartment for hydrogen generation;

an oxidation compartment for oxygen generation;

a cathode that is electrically connected to the negative electrode of the photovoltaic component;

such cathode is either made of or coated with a stable hydrogen generation catalyst material that has low hydrogen evolution overpotential and is electrochemically stable under reduction environment;

an anode that is electrically connected to the positive electrode of the photovoltaic component;

such anode is either made of or coated with a stable oxygen generation catalyst material that has low oxygen evolution overpotential and is electrochemically stable under oxidation environment;

an electrolyte inlet for each or both of the reduction and oxidation compartments;

an outlet for electrolyte and hydrogen in the reduction compartment; and

,

an outlet for electrolyte and oxygen in the oxidation compartment.

2. The integrated photovoltaic electrolysis cell of claim 1, wherein the photovoltaic component is a superstrate-type thin-film photovoltaic cell deposited on a glass superstrate.

3. The integrated photovoltaic electrolysis cell of claim 2, wherein the photovoltaic component is subdivided into a multiple of subcells;

with appropriate dimensions such that the electrical loss in the transparent and conducting front contact is minimal;

an additional scribe is made to bring the positive electrode of the photovoltaic unit cell from the transparent conducting front contact to an electrically isolated contact on a back contact, without shorting the positive and negative electrodes, and with minimized photovoltaic dead area;

the subcells within the photovoltaic unit cell have approximately equal active areas so that a photocurrent generated in each subcell within the unit cell is approximately the same;

a first side of the photovoltaic component, the negative electrodes of some or all photovoltaic unit cells are electrically connected together to a negative contact, which is electrically connected to the cathode of the electrolysis component; and

,

on a second side of the photovoltaic component, the positive electrodes of some or all photovoltaic unit cells are electrically connected together to a positive contact, which is electrically connected to the anode of the electrolysis component;

wherein the electrolysis component is positioned at or near the back of the photovoltaic component in such an orientation that its reduction compartment is on, or close to, the first side; and

the oxidation compartment is on, or close to, the second side for low-loss electrical connections.

4. The integrated photovoltaic electrolysis cell of claim 3, wherein two or more subcells are connected, through appropriate scribes, into a photovoltaic unit cell which has sufficient voltage to drive water electrolysis at or near its maximum power point.

5. The integrated photovoltaic electrolysis cell of claim 3, wherein each subcell is a photovoltaic unit cell.

6. The integrated photovoltaic electrolysis cell of claim 3, wherein the electrolysis component is comprised of:

an alkaline electrolyte;

a membrane that keeps hydrogen and oxygen separated while allowing ions to conduct through;

an electrode spacing between the anode and cathode;

wherein the electrolysis component includes;

an electrolyte inlet for each of the reduction and oxidation compartments, at or near one end (the lower end) of the electrolysis component;

an outlet for electrolyte and hydrogen placed at the upper end of the reduction compartment; and

,

an outlet for electrolyte and oxygen placed at the upper end of the oxidation compartment.

7. The integrated photovoltaic electrolysis cell of claim 6, wherein the electrolysis component has a compact design:

with a length, which is slightly larger than the length of the electrodes, being approximately the same as the length (or width) of the photovoltaic component;

with a width, which is slightly larger than the spacing between the cathode and anode, being substantially smaller than the width (or length) of the photovoltaic component; and

,

with a thickness, which is slightly larger than the width of the electrodes.

8. The integrated photovoltaic electrolysis cell of claim 7, wherein the width is determined using one or more of the following criteria:

the current density on the cathode, during operation under sunlight, is sufficiently small, consequently the overpotential for hydrogen generation is sufficiently small, so that the overall operating voltage of the electrolysis component can be minimized; and

/or

the current density on the anode, during operation under sunlight, is sufficiently small, consequently the overpotential for oxygen generation is sufficiently small, so that the overall operating voltage of the electrolysis component can be minimized.

9. The integrated photovoltaic electrolysis cell of claim 6, wherein the two inlets are combined.

10. The integrated photovoltaic electrolysis cell of claim 2, wherein the photovoltaic component is a superstrate-type thin-film silicon based solar cell deposited on a superstrate, comprising

a superstrate;

a transparent conducting oxide deposited on the superstrate;

one or more of photovoltaic junctions; and

,

an optically reflective and electrically conductive back contact.

11. The integrated photovoltaic electrolysis cell of claim 10, wherein each of the photovoltaic junction(s) is comprised of

an undoped or lightly doped hydrogenated semiconductor material based on amorphous silicon, microcrystalline silicon, nanocrystalline silicon, amorphous germanium, microcrystalline germanium, nanocrystalline germanium, or alloys of two or more of these materials;

a p-type Si-based semiconductor material; and

,

an n-type Si-based semiconductor.

12. The integrated photovoltaic electrolysis cell of claim 1, wherein the photovoltaic component is a substrate-type thin-film photovoltaic cell, deposited on a conducting substrate, having one or more photovoltaic junctions, so that the photovoltage is sufficient to drive water electrolysis.

13. The integrated photovoltaic electrolysis cell of claim 12, wherein the substrate-type thin film photovoltaic cell comprises:

electrical grids applied on top of the transparent conducting front electrode;

wherein spacing of the grids is such that the electrical loss in the transparent and conducting front electrode is minimal;

the electrical grids are electrically connected together and to one electrode of the electrolysis component; and

,

the conducting substrate is electrically connected to the other electrode of the electrolysis component, or itself is the other electrode.

14. The integrated photovoltaic electrolysis cell of claim 12, wherein the electrolysis component is comprised of:

an alkaline electrolyte;

a membrane that keeps hydrogen and oxygen separated while allowing ions to conduct through; and

,

an electrode spacing between the anode and cathode;

wherein the electrolysis component includes;

an electrolyte inlet for each of the reduction and oxidation compartments, at or near one end (the lower end) of the electrolysis component;

an outlet for electrolyte and hydrogen placed at the upper end of the reduction compartment; and

,

an outlet for electrolyte and oxygen placed at the upper end of the oxidation compartment.

15. The integrated photovoltaic electrolysis cell of claim 14, wherein the electrolysis component has a compact design with the following aspects:

with a length, which is slightly larger than the length of the electrodes, being approximately the same as the length (or width) of the photovoltaic component;

with a width, which is slightly larger than the spacing between the cathode and anode, being substantially smaller than the width (or length) of the photovoltaic component; and

,

with a thickness, which is slightly larger than the width of the electrodes.

16. The integrated photovoltaic electrolysis cell of claim 15, wherein the width of the electrode is determined using one or more of the following criteria:

the current density on the cathode, during operation under sunlight, is sufficiently small, consequently the overpotential for hydrogen generation is sufficiently small, so that the overall operating voltage of the electrolysis component can be minimized; and

/or,

the current density on the anode, during operation under sunlight, is sufficiently small, consequently the overpotential for oxygen generation is sufficiently small, so that the overall operating voltage of the electrolysis component can be minimized.

17. The integrated photovoltaic electrolysis cell of claim 16, wherein the two inlets are combined.

18. The integrated photovoltaic electrolysis cell of claim 12, wherein the photovoltaic component is a substrate-type thin-film silicon based solar cell deposited on a stainless substrate, comprising:

a stainless steel substrate;

a reflective and textured metal layer deposited on the stainless steel substrate;

one or more of photovoltaic junction(s) which is comprised of;

an optically transparent and electrically conductive front contact.

19. The integrated photovoltaic electrolysis cell of claim 18, further including a transparent conducting oxide layer serving as a buffer layer.

20. The integrated photovoltaic electrolysis cell of claim 18, wherein each of the photovoltaic junction(s) is comprised of

an undoped or lightly doped hydrogenated semiconductor material based on amorphous silicon, microcrystalline silicon, nanocrystalline silicon, amorphous germanium, microcrystalline germanium, nanocrystalline germanium, or alloys of two or more of these materials;

a p-type Si-based semiconductor material; and

, an n-type Si-based semiconductor.

21. The integrated photovoltaic electrolysis cell of claim 1, wherein the substrate is coated with, or bonded to, a catalyst material.

22. The integrated photovoltaic electrolysis cell of claim 1, wherein the substrate for the photovoltaic component is itself a catalyst.

23. The integrated photovoltaic electrolysis cell of claim 1, wherein the catalyst material comprises a nickel material.

24. The integrated photovoltaic electrolysis cell of claim 1, wherein the substrate material comprises a nickel material.

25. The integrated photovoltaic electrolysis cell of claim 1, wherein the electrode material is nickel-based catalyst or porous nickel-based catalyst.