FILM WITH IMPROVED DISSOLUTION, COSMETIC PRODUCT

• US 20080081055A1
• Filed: 08/07/2007
• Published: 04/03/2008
• Est. Priority Date: 08/10/2006
• Status: Abandoned Application

• Current Assignee: L'Oreal SA
• Original Assignee: L'Oreal SA
• Inventors: CASSIN, Guillaume
• Application Number:
  US11/834,796
• Publication Number:
  US 20080081055A1
• Time in Patent Office: Days
• US Class Current: 424/401
• CPC Class Codes: A61K 2800/31 Anhydrous
• CPC Class Codes: A61K 2800/87 Application Devices; Containers; Packaging
• CPC Class Codes: A61K 8/0208 Tissues; Wipes; Patches
• CPC Class Codes: A61K 8/0216 Solid or semisolid forms
• CPC Class Codes: A61K 8/73 Polysaccharides
• CPC Class Codes: A61K 8/731 Cellulose; Quaternized cellulose derivatives
• CPC Class Codes: A61K 8/732 Starch; Amylose; Amylopectin; Derivatives thereof
• CPC Class Codes: A61K 8/8135 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers, e.g. vinyl esters (polyvinylacetate)
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61K 8/894 modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
• CPC Class Codes: A61Q 19/008 Preparations for oily skin
• CPC Class Codes: A61Q 19/02 for chemically bleaching or whitening the skin
• CPC Class Codes: A61Q 19/04 for chemically tanning the skin topical sun or radiation screening or tanning preparations A61Q17/04
• CPC Class Codes: A61Q 19/08 Anti-ageing preparations

Abstract

Water-soluble anhydrous film containing (i) at least one water-soluble or water-dispersible film-forming polymer, (ii) at least one polysaccharide thickening agent, (iii) at least one water-soluble or water-dispersible oxyalkylenated polysiloxane and (iv) one or more plasticizers chosen from polyols. The invention also relates to the product obtained by mixing at least one film with an aqueous composition and to a kit for the formulation of a cosmetic product.

Claims

1. A water-soluble anhydrous film comprising (i) at least one water-soluble or water-dispersible film-forming polymer, (ii) at least one polysaccharide thickening agent, (iii) at least one water-soluble or water-dispersible oxyalkylenated polysiloxane and (iv) at least one plasticizer chosen from polyols.

2. The film according to claim 1, wherein said film has a thickness of 10 μ

m to 1000 μ

m.

3. The film according to claim 1, wherein said film comprises 0 to 15′

of water.

4. The film according to claim 1, comprising at least one oxyalkylenated polysiloxane that has a solubility in water, measured at 25°

C., of at least 0.1 gram/litre.

5. The film according to claim 1, comprising at least one oxyalkylenated polysiloxane chosen from the water-soluble silicones of formula (a):

R²₃SiO(R²₂SiO)_p(R²PESiO)_qSiR²₃ 

 

(a)

in which;

the R² radicals, which are identical or different, denote a monovalent hydrocarbon radical chosen from alkyl, aryl and aralkyl radicals having at most 10 carbon atoms;

p varies from 0 to 150;

q varies from 1 to 12;

the polyether group PE has the following formula (b);

—

C_xH_2x(OC₂H₄)_y(OC₃H₆)_zOR³ 

 

(b)

in which;

x varies from 1 to 8;

y is greater than 0;

z is greater than or equal to 0;

the values of y and z being such that the total molecular weight of the polyoxyalkylene portion of the polyether group PE varies from 200 to 10 000;

R³ denotes hydrogen, a C₁-C₈ alkyl group or a C₂-C₈ acyl group.

6. The film according to claim 5, wherein in formula (a) the R² radicals are chosen from C₁-C₄ alkyl groups, hexyl, phenyl and benzyl groups.

7. The film according to claim 5, wherein in formula (a) the R³ radicals are chosen from C₁-C₄ alkyl groups.

8. The film according to claim 1, comprising at least one oxyalkylenated polysiloxane chosen from the water-soluble silicones of formula (a′

);

Me₃SiO(MeSiO)_p(MePESiO)_qSiMe₃ 

 

(a′

)

in which;

p varies from 0 to 150;

q varies from 1 to 12;

Me denotes the methyl radical;

PE denotes;

—

(CH₂)₃(OC₂H₄)_y(OC₃H₆)_zOR³ 

 

(b′

)

in which;

y is greater than 0;

z is greater than or equal to 0;

the values of y and z being such that the total molecular weight of the polyoxyalkylene portion of the polyether group PE varies from 200 to 10 000;

R³ denotes hydrogen or a C₁-C₄ alkyl group.

9. The film according to claim 1, comprising at least one oxyalkylenated polysiloxane chosen from branched silicones of following formula (c):

(MeSiO)_q-2[SiOMe₂)_p/qOPE]_q 

 

(c)

in which;

p varies from 0 to 150;

q varies from 1 to 12;

Me denotes the methyl radical;

PE denotes the group of following formula (d);

—

(OC₂H₄)_y(OC₃H₆)_zR³ 

 

(d)

in which;

y is greater than 0;

z is greater than or equal to 0;

the values of y and z being such that the total molecular weight of the polyoxyalkylene portion of the polyether group PE varies from 200 to 10 000;

R³ denotes a C₁-C₄ alkyl group.

10. The film according to claim 1, wherein the amount of oxyalkylenated polysiloxane(s) ranges from 0.5 to 30% by weight with respect to the total weight of the film.

11. The film according to claim 1, wherein the film-forming polymer has a solubility in water, measured at 25°

C., at least equal to 0.1 gram/litre.

12. The film according to claim 1, wherein the film-forming polymer is chosen from vinyl polymers, cellulose derivatives, starches and their derivatives, optionally modified polymers of natural origin, polymers derived from chitin or from chitosan, protein polymers, acrylic copolymers of phosphorylcholine, anion-cation complexes, and their mixtures.

13. The film according to claim 1, wherein the film-forming polymer is chosen from vinyl polymers, cellulose derivatives and their mixtures.

14. The film according to claim 1, wherein the film-forming polymer is chosen from polyvinyl acetate, hydroxypropylcellulose, hydroxypropylmethylcellulose and their mixtures.

15. The film according to claim 1, wherein the amount of water-soluble film-forming polymer(s) ranges from 10 to 95% by weight with respect to the total weight of the film.

16. The film according to claim 1, wherein the polysaccharide thickening agent is chosen from gum arabic, gum ghatti, gum karaya, locust bean gum, guar gum, tamarin gum, xanthan gum, gellan, pectins, gum tragacanth, agar-agar, alginates, carrageenan, furcelleran, konjac gum, cellulose derivatives, and their mixtures.

17. The film according to claim 1, wherein the polysaccharide thickening agent is chosen from carrageenans.

18. The film according to claim 1, wherein the amount of thickening agent(s) ranges from 0.5 to 40% by weight with respect to the total weight of the film.

19. The film according to claim 1, wherein the amount of polyol plasticizer(s) ranges from 1 to 40% by weight with respect to the total weight of the film.

20. A product obtained by mixing at least one water-soluble anhydrous film according to claim 1 with an aqueous composition.

21. The product according to claim 20, wherein the aqueous composition is a solution or emulsion.

22. The product according to claim 20, wherein the thin film or films and/or the aqueous composition further comprise one or more active principles.

23. Kit for the formulation of a cosmetic product comprising (1) an aqueous composition and (2) at least one water-soluble anhydrous film according to claim 1.

24. The kit according to claim 23, comprising a plurality of identical and/or different water-soluble anhydrous films.