Fabrication Of Mesoporous Metal Electrodes In Non-Liquid-Crystalline Phase And Its Application

• US 20080096089A1
• Filed: 12/23/2005
• Published: 04/24/2008
• Est. Priority Date: 12/23/2004
• Status: Active Grant

• Current Assignee: Seoul National University R&DB Foundation (Seoul National University)
• Original Assignee: Seoul National University R&DB Foundation (Seoul National University)
• Inventors: Boo, Hankil, Kim, Hee-Chan, Park, Sejin, Lee, Sunyoung, Chung, Taek Dong
• Granted Patent: US 8,343,690 B2
• Time in Patent Office: Days
• US Class Current: 429/523
• CPC Class Codes: C23C 18/08 characterised by the deposition of metallic material
• CPC Class Codes: C25D 3/52 characterised by the organic bath constituents used
• CPC Class Codes: C25D 7/00 Electroplating characterised by the article coated
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A method for the fabrication of a mesoporous metal electrode in a non-liquid crystalline phase was tested. Specifically, there was tested the efficacy of the method for the fabrication of a mesoporous metal electrode which comprises forming the mesoporous metal electrode on a substrate by chemical or electrochemical reduction of a mixture comprising a solvent, a structure-directing agent, and a source of a metal, characterized in that the mixture is maintained in a non-liquid crystal phase. Furthermore, the usefulness of the mesoporous metal electrode thus prepared from the non-liquid crystalline phase was also tested. The mesoporous metal electrode prepared from the non-liquid crystalline phase had a large surface area, and a roughness factor thereof was controlled by charges passed during electroplating. The method made it possible to fabricate the mesoporous metal electrode in the non-liquid crystalline phase, even more flexible than a liquid crystalline phase. The mesoporous metal electrode prepared by the method had randomly distributed mesopores on the surface thereof and retained a large roughness factor. The method was found to be a good alternative to the conventional fabrication of porous platinum films in the liquid crystalline phase. Furthermore, the method was found to be suitably applicable to automatic processes, because the mesoporous metal electrode was prepared in the highly flexible non-liquid crystalline phase. Recovery and recycling of raw materials were also improved. The mesoporous metal electrode prepared by the method can be suitably used for the detection of glucose and proton, and as a cathode or an anode of fuel cells.

Claims

1. A method for the fabrication of a mesoporous metal electrode which comprises chemically or electrochemically reducing a mixture comprising a solvent, a structure-directing agent and a source of a metal to deposit a metal-organic composite onto a substrate to obtain the mesoporous metal electrode, characterized in that the mixture is maintained in a non-liquid crystalline phase, and the deposition of the metal-organic composite onto the substrate is performed in the non-liquid crystalline mixture.

2. The method as set forth in claim 1, comprising the steps of:

(a) maintaining a mixture comprising a solvent, a surfactant and a source of a metal in a non-liquid crystalline phase;

(b) dipping a substrate into the mixture and reducing the mixture to deposit a metal-organic composite onto the substrate;

(c) removing residues on the substrate onto which the metal-organic composite is formed; and

(d) extracting the organic from the metal-organic composite.

3. The method as set forth in claim 1, wherein the mixture is present as an isotropic, non-liquid crystalline phase.

4. The method as set forth in claim 3, wherein the mixture is present either as an isotropic micelle phase or as an isotropic reverse micelle phase.

5. The method as set forth in claim 4, wherein the mixture is present as an isotropic reverse micelle phase.

6. The method as set forth in claim 1, wherein the metal is selected from the group consisting of platinum, ruthenium, gold, nickel, palladium, silver, cobalt, iron, lead, tin and iridium.

7. The method as set forth in claim 1, wherein the deposition of the metal-organic composite onto the substrate is carried out by electroplating.

8. The method as set forth in claim 1, wherein the solvent is water and the structure-directing agent is a surfactant.

9. The method as set forth in claim 1, wherein the structure-directing agent is a non-ionic surfactant.

10. A mesoporous metal electrode fabricated by the method of claim 1, comprising a substrate onto which a thin film having randomly distributed mesopores is formed.

11. The mesoporous metal electrode as set forth in claim 10, being used for the detection of glucose or hydrogen ion, or for a cathode or anode of a fuel cell.