Processes to make phosphate salt containing products

• US 20080103321A1
• Filed: 10/26/2007
• Published: 05/01/2008
• Est. Priority Date: 10/26/2006
• Status: Abandoned Application

• Current Assignee: Envirofuels LLC
• Original Assignee: Envirofuels LLC
• Inventors: James, Dustin K., Baxter, C. Edward
• Application Number:
  US11/977,760
• Publication Number:
  US 20080103321A1
• Time in Patent Office: Days
• US Class Current: 554/78
• CPC Class Codes: B01J 13/0026 containing a liquid organic phase
• CPC Class Codes: B01J 13/0086 Preparation of sols by physical processes colloid mills B02C
• CPC Class Codes: B01J 27/16 containing oxygen , i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
• CPC Class Codes: B01J 35/23 in a colloidal state
• CPC Class Codes: B01J 35/40 characterised by dimensions, e.g. grain size in a colloidal state B01J35/23; crystallite size B01J35/77
• CPC Class Codes: C10L 1/10 containing additives
• CPC Class Codes: C10L 1/125 water
• CPC Class Codes: C10L 1/1266 nitrogen containing compounds, (e.g. NH3)
• CPC Class Codes: C10L 1/1283 phosphorus, arsenicum, antimonium containing compounds
• CPC Class Codes: C10L 1/1291 Silicon and boron containing compounds
• CPC Class Codes: C10L 1/1616 fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
• CPC Class Codes: C10L 1/1881 carboxylic group attached to an aliphatic carbon atom
• CPC Class Codes: C10L 1/2222 (cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates C10L1/221 takes precedence
• CPC Class Codes: C10L 1/2658 amine salts
• CPC Class Codes: C10L 10/02 for reducing smoke development
• CPC Class Codes: C10L 3/003 Additives for gaseous fuels
• CPC Class Codes: C10L 9/10 by using additives

Abstract

The present invention provides a continuous process for producing an oil based phosphate containing product. The continuous process includes mixing water with at least one base and an orthophosphoric acid to produce a liquid phosphate salt containing solution. This solution is then dried, granulated, and mixed with a base stock hydrocarbon to form the oil based phosphate containing product.

Claims

1. A continuous process for producing an oil based phosphate containing product, the continuous process comprising:

mixing a predetermined amount of water, [Y]OH, [Z]OH, and AcOH in a first mixer to create a base stream, wherein [Y] is a cation and [Z] is selected from the group consisting of NH₄, NHOH and an amine;

mixing the base stream with an orthophosphoric acid using a second mixer to create a liquid phosphate salt containing solution, wherein the orthophosphoric acid is selected from the group consisting of [Y]H₂PO₄, [Y]HPO₄, [NH₄]₂HPO₄, and combinations thereof, wherein [Y] is a cation;

determining pH of the liquid phosphate salt containing solution and comparing the pH of the liquid phosphate salt containing solution to a predetermined liquid phosphate pH value;

providing means for adjusting the pH of the liquid phosphate salt containing solution operable to modify the pH of the liquid phosphate salt containing solution within a preselected range of the predetermined liquid phosphate pH value;

drying and granulating the liquid phosphate salt containing solution to create a water based vapor stream and a substantially water-free solid phosphoric salt product, the substantially water-free solid phosphoric salt product consisting of a plurality of particles and the plurality of particles having a size distribution of particles, a substantial amount of the particles having a diameter smaller than about 100 nanometers;

mixing the substantially water-free solid phosphoric salt product with a base stock hydrocarbon using a high shear mixer to form an oil based phosphate containing product; and

conducting all of the above steps as a continuous process.

2. The continuous process of claim 1, further comprising removing substantially all particles exceeding a predetermined size in diameter as large particles from the substantially water-free solid phosphoric salt product and recycling the large particles into the first mixer.

3. The continuous process of claim 1, further comprising:

determining the phosphorus content of the liquid phosphate salt containing solution using a first p-count analyzer and comparing the phosphorus content of the liquid phosphate salt containing solution to a predetermined liquid phosphate phosphorus value;

providing means for adjusting the phosphorus content of the liquid phosphate salt containing solution operable to modify the phosphorus content of the liquid phosphate salt containing solution within a preselected range of the predetermined liquid phosphate phosphorus value;

determining the phosphorus content of the oil based phosphate containing product using a second p-count analyzer and comparing the phosphorus content of the oil based phosphate containing product to a predetermined oil based phosphorus value; and

providing means for adjusting the phosphorus content of the oil based phosphate containing product operable to modify the phosphorus content of the oil based phosphate containing product within a preselected range of the predetermined oil based phosphorus value.

4. The continuous process of claim 1, wherein the preselected range of the predetermined liquid phosphate pH value is from about 6.0 to about 8.0.

5. The continuous process of claim 1, wherein the preselected range of the predetermined liquid phosphate pH value is from about 6.5 to about 7.5.

6. The continuous process of claim 1, wherein the preselected range of the predetermined liquid phosphate pH value is from about 7.0 to about 7.2.

7. A continuous process for producing an oil based phosphate containing product, the continuous process comprising:

mixing a predetermined amount of water, [Y]OH, [Z]OH, and AcOH in a first mixer to create a base stream, wherein [Y] is a cation and [Z] is selected from the group consisting of NH₄, NHOH and an amine;

mixing the base stream with an orthophosphoric acid using a second mixer to create a liquid phosphate salt containing solution, wherein the orthophosphoric acid is selected from the group consisting of [Y]H₂PO₄, [Y]HPO₄, [NH₄]₂HPO₄, and combinations thereof, wherein [Y] is a cation;

determining pH of the liquid phosphate salt containing solution and comparing the pH of the liquid phosphate salt containing solution to a predetermined liquid phosphate pH value;

providing means for adjusting the pH of the liquid phosphate salt containing solution operable to modify the pH of the liquid phosphate salt containing solution within a preselected range of the predetermined liquid phosphate pH value;

mixing the liquid phosphate salt containing solution with a base stock hydrocarbon using a wet high shear mixer to form an emulsified water-in-oil mixture;

drying the emulsified water-in-oil mixture to create a water based vapor stream and a substantially water-reduced emulsified mixture, wherein the substantially water-reduced emulsified mixture contains an effective amount of water to promote water of hydration;

determining the water content of the substantially water-reduced emulsified mixture using a water content analyzer and comparing the water content of the substantially water-reduced emulsified mixture to a predetermined water value;

providing means for adjusting the water content of the substantially water-reduced emulsified mixture operable to modify the water content of the substantially water-reduced emulsified mixture within a preselected range of the predetermined water value;

grinding the substantially water-reduced emulsified mixture to produce an oil based phosphate containing product, the oil based phosphate containing product consisting of a plurality of particles and the plurality of particles having a size distribution of particles, a substantial amount of the particles having a diameter smaller than about 100 nanometers; and

conducting all of the above steps as a continuous process.

8. The continuous process of claim 7, further comprising:

analyzing the diameters of the plurality of particles of the oil based phosphate containing product using a wet particle analyzer and comparing the diameters of the plurality of particles of the oil based phosphate containing product to a predetermined diameter value; and

providing means for adjusting the diameters of the plurality of particles of the oil based phosphate containing product operable to modify the diameters of the plurality of particles of the oil based phosphate containing product within a preselected range of the predetermined diameter value.

9. The process of claim 7, further comprising:

determining the phosphorus content of the liquid phosphate salt containing solution using a first p-count analyzer and comparing the phosphorus content of the liquid phosphate salt containing solution to a predetermined liquid phosphate phosphorus value;

providing means for adjusting the phosphorus content of the liquid phosphate salt containing solution operable to modify the phosphorus content of the liquid phosphate salt containing solution within a preselected range of the predetermined liquid phosphate phosphorus value;

determining the phosphorus content of the emulsified water-in-oil mixture using a second wet p-count analyzer and comparing the phosphorus content of the emulsified water-in-oil mixture to a predetermined emulsified water-in-oil phosphorus value; and

providing means for adjusting the phosphorus content of the emulsified water-in-oil mixture operable to modify the phosphorus content of the emulsified water-in-oil mixture within a preselected range of the predetermined water-in-oil phosphorus value.

10. The continuous process of claim 7, wherein the preselected range of the predetermined liquid phosphate pH value is from about 6.0 to about 8.0.

11. The continuous process of claim 7, wherein the preselected range of the predetermined liquid phosphate pH value is from about 6.5 to about 7.5.

12. The continuous process of claim 7, wherein the preselected range of the predetermined liquid phosphate pH value is from about 7.0 to about 7.2.

13. A continuous process for producing an oil based phosphate containing product, the continuous process comprising:

mixing a predetermined amount of water with salts in a first mixer to form an intermediate solution, the salts are selected from the group consisting of [Z]₂B₄O₇, [Y]H₂PO₄, [Y]₂HPO₄, [NH₄]₂HPO₄, [X]C₂H₃O₂, [NR₄]₂HPO₄, [Y]₂NH₄PO₄, [Y][NH₄]₂PO₄, and combinations thereof, wherein [Z] is a cation;

wherein [Y] is a cation;

[X] is selected from the group consisting of a cation, NH₄, and combinations thereof; and

R is selected from the group consisting of hydrogen, alkyl groups and combinations thereof;

determining pH of the intermediate mixture and comparing the pH of the intermediate mixture to a predetermined liquid phosphate pH value;

providing means for adjusting the pH of the intermediate mixture operable to modify the pH of the intermediate mixture within a preselected range of the predetermined liquid phosphate pH value;

drying and granulating the intermediate mixture at a temperature within a preset temperature range to create a water based vapor stream and a substantially water-free solid phosphoric salt product, the substantially water-free solid phosphoric salt product consisting of a plurality of particles and the plurality of particles having a size distribution of particles, a substantial amount of the particles having a diameter smaller than about 100 nanometers;

mixing the substantially water-free solid phosphoric salt product with a base stock hydrocarbon using a high shear mixer to form an oil based phosphate containing product; and

conducting all of the above steps as a continuous process.

14. The continuous process of claim 13, further comprising removing any particles exceeding a predetermined size in diameter from the substantially water-free solid phosphoric salt product and recycling into the first mixer.

15. The continuous process of claim 13, further comprising:

determining the phosphorus content of the intermediate solution using a first p-count analyzer and comparing the phosphorus content of the intermediate solution to a predetermined liquid phosphate phosphorus value;

providing means for adjusting the phosphorus content of the intermediate solution operable to modify the phosphorus content of the intermediate solution within a preselected range of the predetermined liquid phosphate phosphorus value;

determining the phosphorus content of the oil based phosphate containing product using a second p-count analyzer and comparing the phosphorus content of the oil based phosphate containing product to a predetermined oil based phosphorus value; and

providing means for adjusting the phosphorus content of the oil based phosphate containing product operable to modify the phosphorus content of the oil based phosphate containing product within a preselected range of the predetermined oil based phosphorus value.

16. A continuous process for producing an oil based phosphate containing product, the continuous process comprising:

mixing a predetermined amount of water with salts to form an intermediate solution, the salts are selected from the group consisting of [Z]₂B₄O₇, [Y]H₂PO₄, [Y]₂HPO₄, [NH₄]₂HPO₄, [X]C₂H₃O₂, [NR₄]₂HPO₄, [Y]₂NH₄PO₄, [Y][NH₄]₂PO₄, and combinations thereof, wherein [Z] is a cation;

wherein [Y] is a cation;

[X] is selected from the group consisting of a cation, NH₄, and combinations thereof; and

R is selected from the group consisting of hydrogen, alkyl groups and combinations thereof;

determining pH of the intermediate mixture and comparing the pH of the intermediate mixture to a predetermined liquid phosphate pH value;

providing means for adjusting the pH of the intermediate mixture operable to modify the pH of the intermediate mixture within a preselected range of the predetermined liquid phosphate pH value;

mixing the intermediate mixture with a base stock hydrocarbon using a wet high shear mixer to form an emulsified water-in-oil mixture;

drying the emulsified water-in-oil mixture at a temperature within a preset temperature range to create a water based vapor stream and a substantially water-reduced emulsified mixture, wherein the substantially water-reduced emulsified mixture contains an effective amount of water to promote water of hydration;

determining the water content of the substantially water-reduced emulsified mixture using a water content analyzer and comparing the water content of the substantially water-reduced emulsified mixture to a predetermined water value;

providing means for adjusting the water content of the substantially water-reduced emulsified mixture operable to modify the water content of the substantially water-reduced emulsified mixture within a preselected range of the predetermined water value;

grinding the substantially water-reduced emulsified mixture to produce an oil based phosphate containing product, the oil based phosphate containing product consisting of a plurality of particles and the plurality of particles having a size distribution of particles, a substantial amount of the particles having a diameter smaller than about 100 nanometers; and

conducting all of the above steps as a continuous process.

17. The continuous process of claim 16, further comprising:

analyzing the diameters of the plurality of particles of the oil based phosphate containing product using a wet particle analyzer and comparing the diameters of the plurality of particles of the oil based phosphate containing product to a predetermined diameter value; and

providing means for adjusting the diameters of the plurality of particles of the oil based phosphate containing product operable to modify the diameters of the plurality of particles of the oil based phosphate containing product within a preselected range of the predetermined diameter value.

18. The continuous process of claim 16, further comprising:

determining the phosphorus content of the intermediate solution using a first p-count analyzer and comparing the phosphorus content of the intermediate solution to a predetermined liquid phosphate phosphorus value;

providing means for adjusting the phosphorus content of the intermediate solution operable to modify the phosphorus content of the intermediate solution within a preselected range of the predetermined liquid phosphate phosphorus value;

determining the phosphorus content of the emulsified water-in-oil mixture using a second wet p-count analyzer and comparing the phosphorus content of the emulsified water-in-oil mixture to a predetermined emulsified water-in-oil phosphorus value; and

providing means for adjusting the phosphorus content of the emulsified water-in-oil mixture operable to modify the phosphorus content of the emulsified water-in-oil mixture within a preselected range of the predetermined water-in-oil phosphorus value.