HIGH ACCURACY CONTAMINATION ESTIMATION IN HYDROCARBON SAMPLES USING GC X GC

• US 20080105032A1
• Filed: 10/22/2007
• Published: 05/08/2008
• Est. Priority Date: 10/25/2006
• Status: Active Grant

• Current Assignee: Schlumberger Technology Corporation (Schlumberger NV), Woods Hole Oceanographic Institution
• Original Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Inventors: Raghuraman, Bhavani, Nelson, Robert, Reddy, Christopher, Mullins, Oliver
• Granted Patent: US 7,805,979 B2
• Time in Patent Office: Days
• US Class Current: 73/23.41
• CPC Class Codes: E21B 49/08 Obtaining fluid samples or testing fluids, in boreholes or wells
• CPC Class Codes: G01N 2030/025 Gas chromatography
• CPC Class Codes: G01N 30/463 for multidimensional chromatography
• CPC Class Codes: G01N 33/2823 Raw oil, drilling fluid or polyphasic mixtures
• CPC Class Codes: G01N 33/2835 Specific substances contained in the oils or fuels

Abstract

A method of estimating contamination of oil based mud filtrate in a hydrocarbon sample. The method comprising the steps of obtaining a hydrocarbon sample contaminated with oil based mud filtrate, then analyzing the contaminated hydrocarbon sample using two-dimensional gas chromatography (GC×GC). The method further comprises identifying one or more unique component or tracer in the oil based mud filtrate in the contaminated hydrocarbon sample. Finally, the method comprises of summing the peak volumes of the one or more unique component or tracer, relative to the peak volumes of a clean hydrocarbon sample.

Claims

1. A method of estimating contamination of oil based mud filtrate in a hydrocarbon sample, the method comprising the steps of:

a) obtaining a hydrocarbon sample contaminated with oil based mud filtrate;

b) analyzing the contaminated hydrocarbon sample using two-dimensional gas chromatography (GC×

GC);

c) identifying one or more unique component or tracer in the oil based mud filtrate in the contaminated hydrocarbon sample; and

d) summing the peak volumes of the one or more unique component or tracer, relative to the peak volumes of a clean hydrocarbon sample.

2. The method of claim 1, wherein the oil based mud filtrate is selected from the group consisting of a non-synthetic oil based mud filtrate or a synthetic oil based mud filtrate.

3. The method of claim 1, wherein at least one unique component of the one or more unique component is from the synthetic oil based component.

4. The method of claim 2, wherein at least one tracer of the one or more tracer is added to the non-synthetic oil based mud filtrate.

5. The method of claim 1, wherein the contamination of oil based mud filtrate in the hydrocarbon sample is greater than about 0.1%.

6. The method of claim 1, wherein the contamination of oil based mud filtrate in the hydrocarbon sample is from about 0.1% to about 10%.

7. The method of claim 1, wherein two-dimensional gas chromatography (GC×

GC) has a greater resolving power in identifying one or more unique component and tracer compared to a one-dimensional gas chromatography.

8. The method of claim 1, wherein there are at least two or more dimension separations.

9. The method of claim 1, wherein the GC×

GC involves a first dimension separation using a non-polar phase; and

a second dimension separation using a polar phase.

10. The method of claim 9, wherein non-polar phase separates petroleum compounds by volatility differences;

and the polar phase separates first dimension co-eluters by polarity differences.

11. The method of claim 10, wherein the non-polar phase is a polydimethylsiloxane column;

and the polar phase is a 50% phenyl-substituted polydimethylsiloxane column.

12. The method of clam 1, wherein the unique component or tracer in the oil based mud filtrate is selected from the group consisting of an iso-olefin, a liner alpha olefin, a poly-alpha olefin or ester.

13. The method of claim 12, wherein the iso-olefin is a C₁₆ to C₂₀ alkene.

14. A method of separating and analyzing contamination of drilling fluid in a hydrocarbon sample, the method comprising the steps of:

a) obtaining a hydrocarbon sample contaminated with drilling fluid;

b) analyzing the contaminated hydrocarbon sample using two-dimensional gas chromatography (GC×

GC), wherein the contaminated hydrocarbon sample is subject to two different stationary phase selectivities;

c) identifying one or more unique component or tracer in the drilling fluid in the contaminated hydrocarbon sample; and

d) summing the peak volumes of the one or more unique component or tracer, relative to the peak volumes of a clean hydrocarbon sample.

15. The method of claim 14, wherein the drilling fluid is selected from the group consisting of a non-synthetic oil based mud filtrate or a synthetic oil based mud filtrate.

16. The method of claim 15, wherein the one or more unique component is from the synthetic oil based mud filtrate.

17. The method of claim 15, wherein the method includes at least one tracer of the one or more tracer that is added to the non-synthetic oil based mud filtrate.

18. The method of claim 14, wherein the two different stationary phase selectivities involves a first dimension separation using a non-polar phase;

and a second dimension separation using a polar phase.

19. The method of claim 18, wherein non-polar phase separates petroleum compounds by volatility differences;

and the polar phase separates first dimension co-eluters by polarity differences.

20. The method of claim 19, wherein the non-polar phase is a polydimethylsiloxane column;

and the polar phase is a 50% phenyl-substituted polydimethylsiloxane column.

21. The method of claim 14, wherein the contamination of drilling fluid in the hydrocarbon sample is greater than about 0.1%.

22. The method of clam 14, wherein the unique component or tracer in the drilling fluid is selected from the group consisting of an iso-olefin, a liner alpha olefin, a poly-alpha olefin or ester.

23. The method of claim 22, wherein the iso-olefin is a C₁₆ to C₂₀ alkene.

24. A method of estimating contamination of crude oil in a oil based mud filtrate sample, the method comprising the steps of:

a) obtaining an oil based mud filtrate sample contaminated with crude oil;

b) analyzing the oil based mud filtrate sample using two-dimensional gas chromatography (GC×

GC);

c) identifying one or more unique component or tracer in the crude oil in the contaminated oil based mud filtrate sample; and

d) summing the peak volumes of the one or more unique component or tracer, relative to the peak volumes of the oil based mud filtrate sample.

25. The method of claim 24, wherein the GC×

GC involves a first dimension separation using a non-polar phase; and

a second dimension separation using a polar phase.