Resin Composition For High-Frequency Electronic And Electric Parts And Shaped Article Thereof

• US 20080113187A1
• Filed: 02/02/2006
• Published: 05/15/2008
• Est. Priority Date: 02/03/2005
• Status: Abandoned Application

• Current Assignee: Asahi Kasei Chemicals Corporation (Asahi Kasei Corporation)
• Original Assignee: Asahi Kasei Chemicals Corporation (Asahi Kasei Corporation)
• Inventors: Toyouchi, Kaoru, Akiyama, Yoshikuni
• Application Number:
  US11/795,101
• Publication Number:
  US 20080113187A1
• Time in Patent Office: Days
• US Class Current: 428/336
• CPC Class Codes: B32B 15/08 of synthetic resin
• CPC Class Codes: B32B 27/20 using fillers, pigments, thixotroping agents
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 71/12 Polyphenylene oxides
• CPC Class Codes: C08L 81/02 Polythioethers; Polythioether-ethers
• CPC Class Codes: H05K 1/024 Dielectric details, e.g. changing the dielectric material around a transmission line
• CPC Class Codes: H05K 1/0333 containing S
• CPC Class Codes: H05K 1/036 Multilayers with layers of different types
• CPC Class Codes: H05K 1/0373 containing additives, e.g. fillers H05K1/036 takes precedence
• CPC Class Codes: H05K 1/056 the metal substrate being covered by an organic insulating layer
• CPC Class Codes: H05K 2201/0209 Inorganic, non-metallic particles
• CPC Class Codes: H05K 2201/0323 Carbon
• CPC Class Codes: Y10T 428/263 Coating layer not in excess of 5 mils thick or equivalent
• CPC Class Codes: Y10T 428/264 Up to 3 mils
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

An object of the present invention is to provide a thermoplastic resin composition, an extruded sheet and a copper clad laminate excellent in processability such as extrusion processability and injection moldabilities, solder heat resistance and mechanical properties such as bending properties, durability and drilling processability and satisfying low dielectric loss necessary for high frequency band telecommunication parts. The present invention relates to a shaped article composed of a resin composition prepared by adding a specific graphite to a resin composition containing (a) a polyarylene sulfide resin and (b) a polyphenylene ether resin as main components, and a multilayer extruded sheet comprising an inner layer of a resin composition prepared by adding a metal oxide to a resin composition containing (a) a polyarylene sulfide resin and (b) a polyphenylene ether resin as main components and an outer layer of a resin composition to which no metal oxide is added. The present invention also relates to a copper-clad laminate prepared by stacking copper foil or copper plating on at least one side or both sides of the shaped article or the multilayer extruded sheet.

Claims

1. A low dielectric loss resin composition for high-frequency electronic and electric parts, having dielectric properties of a dielectric constant of 3 to 10 and a dielectric dissipation factor of 0.007 or less at 1 GHz,

the resin composition being prepared by melt kneading a raw material composition comprising:

(a) 5 to 95% by weight of a polyarylene sulfide resin,

(b) 95 to 5% by weight of a polyphenylene ether resin and

(c) 1 to 20 parts by weight of a styrene copolymer containing at least one functional group of a glycidyl group, an oxazolyl group and an acid anhydride group based on 100 parts by weight of components (a) and b).

2. The resin composition according to claim 1, further comprising (d) 1 to 15 parts by weight of an inorganic filler based on 100 parts by weight of components (a), (b) and (c).

3. The resin composition according to claim 2, wherein component (d) is a non-fibrous inorganic filler.

4. The resin composition according to claim 3, wherein the non-fibrous inorganic filler is graphite having an average particle size of 10 to 100 um.

5. A shaped article prepared by shaping the resin composition according to any one of claims 1 to 4.

6. A high-frequency multilayer sheet comprising an outer layer and an inner layer, wherein the outer layer and the inner layer are each composed of the shaped article according to claim 5.

7. The multilayer sheet according to claim 6, wherein the inner layer is a shaped article prepared by shaping a resin composition comprising

(a) 5 to 95% by weight of a polyarylene sulfide resin,

(b) 95 to 5% by weight of a polyphenylene ether resin

(c) 1 to 20 parts by weight of a styrene copolymer containing at least one functional group of a glycidyl group, an oxazolyl group and an acid anhydride group based on 100 parts by weight of components (a) and (b), and

(d) 1 to 15 parts by weight of an inorganic filler based on 100 parts by weight of components (a) (b) and (c).

8. The multilayer sheet according to claim 6, wherein a raw material composition of the shaped article constituting the inner layer further comprises (e) 10 to 60 parts by weight of a metal oxide based on 100 parts by weight of components (a), (b) and (c).

9. The multilayer sheet according to claim 6, wherein the multilayer sheet has an overall thickness of 0.01 to 5 mm and the outer layer has a thickness of 1/20 to ¼

of the overall thickness of the multilayer sheet.

10. The multilayer sheet according to claim 6, which is a copper-clad laminate.