FUEL CELL HEAT EXCHANGE SYSTEMS AND METHODS

• US 20080118800A1
• Filed: 10/31/2007
• Published: 05/22/2008
• Est. Priority Date: 11/01/2006
• Status: Active Grant

• Current Assignee: Ceres Intellectual Property Company Limited
• Original Assignee: Ceres Intellectual Property Company Limited
• Inventors: Morgan, Robert, DEVRIENDT, James, Barnard, Paul, Leah, Robert
• Granted Patent: US 8,062,802 B2
• Time in Patent Office: Days
• US Class Current: 429/26
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 2250/20 Fuel cells in motive systems, e.g. vehicle, ship, plane
• CPC Class Codes: H01M 8/04014 Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
• CPC Class Codes: H01M 8/04029 Heat exchange using liquids
• CPC Class Codes: H01M 8/04067 Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
• CPC Class Codes: H01M 8/04156 with product water removal
• CPC Class Codes: H01M 8/0618 Reforming processes, e.g. autothermal, partial oxidation or steam reforming
• CPC Class Codes: H01M 8/0662 Treatment of gaseous reactants or gaseous residues, e.g. cleaning
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02T 90/40 Application of hydrogen technology to transportation, e.g. using fuel cells

Abstract

A system and method are provided for exchanging heat in fuel cell systems (100) in which the anode and cathode off-gases are provided with separated flow paths. In one embodiment, where a fuel cell stack (110) has separate anode and cathode off-gas flow paths, separate anode off-gas from the at least one fuel cell stack (110) and at least one heat transfer fluid are passed through a first heat exchange element (126) to exchange heat between the anode off-gas and the heat transfer fluid. The cathode off-gas exiting the at least one fuel cell stack is then combined with the anode off-gas from the heat exchange element (126) in a burner and burned.

Claims

1. A method of altering the temperature of off-gases exiting at least one fuel cell stack, the at least one fuel cell stack having separate anode and cathode off-gas flow paths, the method comprising:

passing separate anode off-gas from the at least one fuel cell stack and at least one heat transfer fluid through a first heat exchange element to exchange heat between the anode off-gas and the at least one heat transfer fluid;

passing the separate anode off-gas from the first heat exchange element to a burner; and

passing the separate cathode off-gas exiting the at least one fuel cell stack into said burner.

2. A method according to claim 1, wherein the first heat exchange element cools the anode off-gas and heats the at least one heat transfer fluid.

3. A method according to claim 1, further comprising:

burning the combined anode and cathode off-gases to produce burner off-gas; and

passing burner off-gas and the at least one heat transfer fluid through a second heat exchange element to exchange heat between the burner off-gas and the at least one heat transfer fluid.

4. A method according to claim 3, wherein the second heat exchange element cools the burner off-gas and heats the at least one heat transfer fluid.

5. A method according to claim 4, wherein the cooled burner off-gas is output from the second heat exchange element to an exhaust.

6. A method according to claim 3, wherein condensate from the burner off-gas is formed in and output from the second heat exchange element.

7. A method according to claim 3, wherein the second heat exchange element receives the heat transfer fluid after it has been output from the first heat exchange element.

8. A method according to claim 2, wherein condensate from the anode off-gas is formed in and output from the first heat exchange element.

9. A method according to claim 1, wherein the at least one heat exchange fluid is chosen from a group comprising:

water, refrigerant fluid, anti-freeze fluid, mixed fluids, fuel and air.

10. A method according claim 1, wherein the first heat exchange element receives a plurality of heat transfer fluids.

11. A method according to claim 10, further comprising independently controlling the rate of flow of each of the heat transfer fluids to optimize heat exchange to or from the heat transfer fluids.

12. A method according to claim 1, further comprising passing the separate anode off-gas through a further heat exchange element before it is received by the first heat exchange element, the further heat exchange element exchanging heat between the anode off-gas and a flow of fluid.

13. A method according to claim 12, the further heat exchange element cooling the anode off-gas and warming the flow of fluid.

14. A method according to claim 12, wherein the flow of fluid into the further heat exchange element is a flow of cathode side feed gas, which cathode side feed gas subsequently enters the at least one fuel cell stack and exits as the cathode off-gas.

15. A method according to any claim 1, wherein the operating temperature of the fuel cell is between 100°

C. and 1100°

C., 250°

C. and 850°

C., or 450°

C. and 650°

C.

16. A method according to claim 6, wherein condensed water is recycled and used to reform fuel before it enters the fuel cell(s).

17. A fuel cell system, comprising:

at least one fuel cell stack having separate outlets and flow paths for flow of anode and cathode off-gases respectively;

a first heat exchange element coupled to receive anode off-gas which has been output from the at least one fuel cell stack anode off-gas outlet, the first heat exchange element for exchanging heat between the anode off-gas from the at least one fuel cell stack and the at least one heat transfer fluid; and

a burner configured to receive and combine anode off-gas exiting the first heat exchange element and cathode off-gas exiting the at least one fuel cell stack and combust same to produce burner off-gas.

18. A fuel cell system according to claim 17, wherein the first heat exchange element is configured to cool the anode off-gas, and heat the heat transfer fluid.

19. A fuel cell system according to claim 18, the first heat exchange element being for reducing the operating temperature of the burner.

20. A fuel cell system according to claim 17, further comprising a second heat exchange element, coupled to receive the heat transfer fluid and burner off-gas from the burner, the second heat exchange element for exchanging heat between the burner off-gas and the heat transfer fluid.

21. A fuel cell system according to claim 20, wherein the second heat exchange element is configured to cool the burner off-gas and heat the heat transfer fluid.

22. A fuel cell system according to claim 20, wherein the second heat exchange element comprises a condensing heat exchanger.

23. A fuel cell system according to claim 20, wherein the heat exchange fluid flow path is defined by the first heat exchange element followed by the second heat exchange element, for passing heat transfer fluid into, through and out of the first heat exchange element and subsequently into, through and out of the second heat transfer element.

24. A fuel cell system according to claim 20, wherein the second heat exchange element is adapted to receive a plurality of heat transfer fluids.

25. A fuel cell system according to claim 17, wherein the first heat exchange element comprises a condensing heat exchanger.

26. A fuel cell system according claim 17, wherein the first heat transfer exchange element is adapted to receive a plurality of heat transfer fluids.

27. A fuel cell system according to claim 17, further comprising a further heat exchange element coupled between the at least one fuel cell stack anode off-gas outlet and the first heat exchange element, for reducing the temperature of the anode off-gas before it enters the first heat exchange element.

28. A fuel cell system according to claim 27, wherein the further heat exchange element is a gas-gas heat exchanger.

29. A fuel cell system according to claim 27, wherein the first and further heat exchange elements are integrated into a single unit.

30. A fuel cell system according to claim 20, wherein the first and second heat exchange elements are integrated into a single unit.

31. A fuel cell system according to claim 17, wherein the fuel cell is a solid oxide fuel cell.

32. A fuel cell system according to claim 17, wherein the fuel cell is configured to operate at between 100°

C.-1100°

C., 250°

C.-850°

C., or 450°

C.-650°

C.

33. A fuel cell system according to claim 22, wherein the system is configured to recycle water from the condensing heat exchanger(s) and provide the water to a reformer for reforming fuel before it enters the fuel cell(s).

34. A fuel cell system according to claim 17, configured to be operated in a marine environment.

35. A fuel cell system according to claim 17, configured to be operated in an automotive environment.

36. A fuel cell system according to claim 17, configured to be operated in an aeronautical environment.

37. In a fuel cell system having separate anode and cathode off-gas outlets and flow paths from at least one fuel cell stack, a heat exchanger system comprising:

a first condensing heat exchange element coupled to receive anode off-gas from the anode off-gas outlet of the at least one fuel cell stack of the fuel cell system and heat transfer fluid, and output cooled anode off-gas, condensate from the anode off-gas and warmed heat transfer fluid from the first heat exchange element; and

a burner coupled to the first heat exchange element to receive cooled anode off-gas from the first heat exchange element and cathode off-gas exiting the at least one fuel cell stack and combust same to produce burner off-gas.

38. In a fuel cell system having separate anode and cathode off-gas outlets and flow paths from at least one fuel cell stack, a heat exchanger system comprising:

a first condensing heat exchange element coupled to receive anode off-gas from the anode off-gas outlet of the at least one fuel cell stack and heat transfer fluid, and output cooled anode off-gas, condensate from the anode off-gas and warmed heat transfer fluid from the first heat exchange element;

a burner coupled to the first heat exchange element to receive cooled anode off-gas from the first heat exchange element and cathode off-gas exiting the at least one fuel cell stack and combust same to produce burner off-gas; and

a second condensing heat exchange element coupled to receive burner off-gas, and the heat transfer fluid, and output cooled burner off-gas, condensate from the burner off-gas and warmed heat transfer fluid from the second heat exchange element.

39. In a fuel cell system having separate anode and cathode off-gas outlets and flow paths from at least one fuel cell stack, a heat exchanger system comprising:

a first condensing heat exchange element coupled to receive anode off-gas from the anode off-gas outlet of the at least one fuel cell stack and heat transfer fluid, and output cooled anode off-gas, condensate from the anode off-gas and warmed heat transfer fluid from the first heat exchange element;

a burner coupled to the first heat exchange element to receive cooled anode off-gas from the first heat exchange element and cathode off-gas exiting the at least one fuel cell stack and combust same to produce burner off-gas;

a second condensing heat exchange element coupled to receive burner off-gas, and the heat transfer fluid, and output cooled burner off-gas, condensate from the burner off-gas and warmed heat transfer fluid from the second heat exchange element; and

a further heat exchange element coupled in the anode off-gas fluid flow path between at least one fuel cell stack and the first heat exchange element, configured to reduce the temperature of the anode off-gas passing therethrough before it enters the first heat exchange element.

40. In a fuel cell system having separate anode and cathode off-gas outlets and flow paths from at least one fuel cell stack, a heat exchanger system comprising:

a first condensing heat exchange element coupled to receive anode off-gas from the anode off-gas outlet of the at least one fuel cell stack and at least one heat transfer fluid, and output cooled anode off-gas, condensate from the anode off-gas and warmed heat transfer fluid from the first heat exchange element; and

a further heat exchange element coupled in the anode off-gas fluid flow path between at least one fuel cell stack and the first heat exchange element, configured to reduce the temperature of the anode off-gas passing therethrough before it enters the first heat exchange element.

41. A method of altering the temperature of off-gases exiting at least one fuel cell stack, the at least one fuel cell stack having separate anode and cathode off-gas flow paths, the method comprising:

passing separate anode off-gas from the at least one fuel cell stack and heat transfer fluid through a first heat exchange element to exchange heat between the anode off-gas and the heat transfer fluid.

42. In a fuel cell system having separate anode and cathode off-gas outlets and flow paths from at least one fuel cell stack, a heat exchanger system comprising a first condensing heat exchange element coupled to receive anode off-gas from the anode off-gas outlet of the at least one fuel cell stack of the fuel cell system and heat transfer fluid, and output cooled anode off-gas, condensate from the anode off-gas and warmed heat transfer fluid from the first heat exchange element.