Absorbent compositions with clay aerogels and methods for forming absorbent compositions

• US 20080132632A1
• Filed: 02/01/2008
• Published: 06/05/2008
• Est. Priority Date: 03/02/2006
• Status: Abandoned Application

• Current Assignee: Case Western Reserve University
• Original Assignee: Case Western Reserve University
• Inventors: Gawyrla, Matthew D., Bandi, Suheel A., Schiraldi, David A.
• Application Number:
  US12/012,248
• Publication Number:
  US 20080132632A1
• Time in Patent Office: Days
• US Class Current: 524/445
• CPC Class Codes: A01K 1/0154 comprising inorganic material
• CPC Class Codes: A01K 1/0155 comprising organic material
• CPC Class Codes: C08K 3/34 Silicon-containing compounds
• CPC Class Codes: C08K 3/346 Clay
• CPC Class Codes: C08K 9/08 Ingredients agglomerated by treatment with a binding agent
• CPC Class Codes: C08L 1/02 Cellulose; Modified cellulose
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: C08L 29/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
• CPC Class Codes: C08L 3/02 Starch; Degradation products thereof, e.g. dextrin
• CPC Class Codes: C08L 5/06 Pectin; Derivatives thereof
• CPC Class Codes: C08L 5/08 Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
• CPC Class Codes: C08L 97/005 Lignin
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N

Abstract

Lightweight, highly absorbent compositions including clay aerogels are suitable for use in the home as well as in industry and have particular suitability for use as animal litter. The compositions can further include components, for example as part of the mixture and/or as a coating on a surface of the clay aerogel component, that have properties, for example, that aid in malodor reduction, clumping, or the like, or combinations thereof. Also, clay aerogel polymer composites, formed from various types of clay and (co)polymers, which are relatively low density materials having myriad applications are disclosed. Numerous methods for preparing the clay aerogel polymer composites are disclosed.

Claims

1. An absorbent composition, comprising:

particles of an absorbent porous clay aerogel comprising one or more of (a) an aerogel component derived from at least a clay and one or more of (i) a (co)polymer and (ii) binder component and (b) a clay aerogel-based porous ceramic derived from at least the aerogel component; and

an additive material in contact with at least one clay aerogel particle and comprising one or more of a clumping agent, an antimicrobial agent, a pH-adjusting agent, a fragrance, a deodorant, an odor-control agent, a coloring agent, a dedusting agent, a urease inhibition agent and a non-aerogel absorbent material.

2. The absorbent composition according to claim 1, wherein the clay aerogel further comprises one or more fibers, wherein when two or more fibers are present the fibers can be the same or different, and wherein the fibers are natural or synthetic or a combination thereof.

3. The absorbent composition according to claim 2, wherein the one or more fibers are present in an amount from about 0.25 to about 1,250 parts per 100 parts by weight of clay in the clay aerogel.

4. The absorbent composition according to claim 3, wherein the one or more fibers are derived from one or more of polyvinyl alcohol, a polymer or (co)polymer possessing a high concentration of pendant carboxylic acids, and a polymer or (co)polymer which contains one or more amide bonds.

5. The absorbent composition according to claim 1, wherein the (co)polymer is present and is a water soluble (co)polymer comprising one or more of starch, plant gum, modified cellulosic, lignin material, chitan, chitosan, pectin, a water soluble and dispersible protein, or derived from two or more same or different monomers comprising an olefin monomer, styrene, isoprene, butadiene, a cyclic olefin, a halogenated monomer, chlorinated isoprene, vinyl fluoride, vinylidene fluoride, acrylic monomer, vinyl acetate, an amine group containing monomer, aliphatic dialcohol, aromatic dialcohol, diamine, diisocyanate, dicarboxylic acid, a difunctional monomer containing one carboxylic acid and either one alcohol or amino group, arylene oxide, arylene sulfide, arylene sulfone, and a monomer having one or more epoxy groups;

or a combination of the water soluble (co)polymer and copolymer derived from two or more same or different monomers.

6. The absorbent composition according to claim 1, wherein the binder component is present and is polyvinyl alcohol, a polymer or copolymer derived from two or more same or different alkylene oxide monomers having from 2 to about 6 carbon atoms, a copolymer derived from at least one alkylene oxide having from 2 to about 6 carbon atoms and an amine, or a polyoxymethylene polymer or copolymer, or a combination thereof.

7. The absorbent composition according to claim 1, wherein the antimicrobial agent is present and comprises a boron-containing compound.

8. The absorbent composition according to claim 1, wherein the clumping agent is present and includes one or more of lignin sulfonate, fibrillated polytetrafluoroethylene, hydroxymethyl cellulose, a carboxymethyl cellulose derivative, a metal salt, guar gum cellulose, xanthan gum, starch, lignin, polyvinyl alcohol, polyacrylic acid, styrene butadiene resins, polystyrene acrylic acid resin and crosslinked polyester.

9. The absorbent composition according to claim 1, wherein the dedusting agent is present and wherein the dedusting agent is one or more of gums, water-soluble polymeric resins, and a gum or natural resin.

10. The absorbent composition according to claim 1, wherein the composition includes one or more of the coloring agent, fragrance and odor control agent.

11. The absorbent composition according to claim 1, wherein the composition includes the urease inhibition agent.

12. The absorbent composition according to claim 1, wherein the composition includes a non-aerogel absorbent material.

13. The absorbent composition according to claim 1, wherein the composition includes activated alumina in an amount from about 0.01 part to about 50 parts by weight based on 100 total parts by weight of the composition.

14. The absorbent composition according to claim 1, wherein the additive material comprises particles dry blended with the clay aerogel particles.

15. The absorbent composition according to claim 1, wherein the additive material is coated on a surface of at least one of the clay aerogel particles.

22. The reinforced clay aerogel according to claim 4, wherein the fibers are derived from a composition comprising one or more of polyvinyl alcohol, poly(acrylic acid), poly(methylacrylic acid), Nylon-6, Nylon-6,6, silk and soy silk, or (co)polymers or combinations thereof.

16. A reinforced clay aerogel, comprising:

one or more of (a) a porous clay aerogel component derived from at least a clay, one or more fibers and one or more of (i) a copolymer and (ii) a binder component and (b) a clay aerogel-based porous ceramic derived from the porous clay aerogel component.

17. The reinforced clay aerogel according to claim 16, wherein when two or more fibers are present, the fibers can be the same or different, wherein the fibers are natural or synthetic or a combination thereof.

18. The reinforced clay aerogel according to claim 16, wherein the one or more fibers are present in an amount from about 0.25 to about 1,250 parts per 100 parts by weight of clay in the clay aerogel.

19. The reinforced clay aerogel according to claim 16, wherein the one or more fibers are derived from one or more of polyvinyl alcohol, a polymer or (co)polymer possessing a high concentration of pendant carboxylic acids, and a polymer or (co)polymer which contains one or more amide bonds.

20. The reinforced clay aerogel according to claim 16, wherein the (co)polymer is present and is a water soluble (co)polymer comprising one or more of starch, plant gum, modified cellulosic, lignin material, chitan, chitosan, pectin, a water soluble and dispersible protein, or derived from two or more same or different monomers comprising an olefin monomer, styrene, isoprene, butadiene, a cyclic olefin, a halogenated monomer, chlorinated isoprene, vinyl fluoride, vinylidene fluoride, acrylic monomer, vinyl acetate, an amine group containing monomer, aliphatic dialcohol, aromatic dialcohol, diamine, diisocyanate, dicarboxylic acid, a difunctional monomer containing one carboxylic acid and either one alcohol or amino group, arylene oxide, arylene sulfide, arylene sulfone, and a monomer having one or more epoxy groups;

or a combination of the water soluble (co)polymer and copolymer derived from two or more same or different monomers.

21. The reinforced clay aerogel according to claim 16, wherein the binder component is present and is polyvinyl alcohol, a polymer or copolymer derived from two or more same or different alkylene oxide monomers having from 2 to about 6 carbon atoms, or a copolymer derived from at least one alkylene oxide having from 2 to about 6 carbon atoms and an amine, a polyoxymethylene polymer or copolymer, or a combination thereof.

23. The reinforced clay aerogel according to claim 19, wherein the fibers are derived from a composition comprising one or more of polyvinyl alcohol, poly(acrylic acid), poly(methylacrylic acid), Nylon-6, Nylon-6,6, silk and soy silk, or (co)polymers or combinations thereof.