FLEXURALLY RIGID COMPOSITE SHEET

• US 20080160272A1
• Filed: 12/13/2007
• Published: 07/03/2008
• Est. Priority Date: 06/13/2005
• Status: Abandoned Application

• Current Assignee: Quadrant Plastic Composites AG (Aquamit BV)
• Original Assignee: Quadrant Plastic Composites AG (Aquamit BV)
• Inventors: Keilbach, Andreas, Brentrup, Karl-Ludwig
• Application Number:
  US11/955,729
• Publication Number:
  US 20080160272A1
• Time in Patent Office: Days
• US Class Current: 428/215
• CPC Class Codes: B29C 70/24 oriented in at least three directions forming a three dimensional structure
• CPC Class Codes: B29C 70/465 and impregnating by melting a solid material, e.g. sheets, powders of fibres
• CPC Class Codes: B29C 70/506 and impregnating by melting a solid material, e.g. sheet, powder, fibres B29C70/508 takes precedence
• CPC Class Codes: B29K 2023/12 PP, i.e. polypropylene
• CPC Class Codes: B29K 2309/08 Glass
• CPC Class Codes: B32B 2250/03 3 layers
• CPC Class Codes: B32B 2250/20 All layers being fibrous or filamentary
• CPC Class Codes: B32B 2250/40 Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
• CPC Class Codes: B32B 2260/023 Two or more layers
• CPC Class Codes: B32B 2260/046 Synthetic resin
• CPC Class Codes: B32B 2262/0253 Polyolefin fibres vinyl or acrylic copolymers B32B2262/0223 or B32B2262/0246
• CPC Class Codes: B32B 2262/101 Glass fibres
• CPC Class Codes: B32B 2307/546 Flexural strength; Flexion stiffness
• CPC Class Codes: B32B 2307/554 Wear resistance
• CPC Class Codes: B32B 2307/7265 Non-permeable
• CPC Class Codes: B32B 2605/00 Vehicles
• CPC Class Codes: B32B 27/20 using fillers, pigments, thixotroping agents
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 5/26 another layer next to it also being fibrous or filamentary relative arrangement of fibres or filaments of different layers B32B5/12
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified

Abstract

Rigid yet lightweight composite sheets contain a core layer formed by thermal consolidation of a needled non-woven mat of glass fibers and polypropylene fibers, optionally with a melt-bonded polypropylene film on at least one side thereof, sandwiched between layers of GMT. The core contains from 20 to 80 volume percent air voids, whereas the GMT outer layers have a very low or zero void content. The composite sheets may be used for structural panels, for fabricating furniture, and for other uses.

Claims

1. A flexurally rigid composite sheet, comprising a thermally consolidated sandwich structure comprising:

A. one or two outer layers with a thickness of 0.5 to 5 mm comprising glass-fiber reinforced polypropylene with a glass content of 20 to 60 wt-% and an air void content of less than 5 vol-%, and

B. a core layer with a thickness of 2 to 40 mm comprising glass-fiber reinforced polypropylene with a glass content of 35 to 80 wt-% and an air void content of 20 to 80 vol-%,

wherein the core layer has been obtained by dry blending of polypropylene fibers and glass fibers, needling of the blended nonwoven, and heat pressing.

2. The composite sheet of claim 1, wherein the glass fibers in layer A are present as a needled mat of nondirectional fibers with an average length (weight average) of 10 to 100 mm or as a woven fabric or nonwoven fabric needled with directional or nondirectional fibers.

3. The composite sheet of claim 1, wherein the glass fibers in layer B are nondirectional fibers with an average length (weight average) of 10 to 60 mm needled together.

4. The composite sheet of claim 1, having the layer sequence A-B-A.

5. The composite sheet of claim 1, which is provided on one or both sides thereof with a functional layer.

6. The composite sheet of claim 5, wherein at least one functional layer selected from the group consisting of foils, woven textile fabrics and fiber nonwovens.

7. The composite sheet of claim 1, comprising two outer layers A and a plurality of core layers B, at least one core layer B faced with a polypropylene film layer on at least one side thereof prior to consolidation of the sandwich structure.

8. A method for producing a composite sheet of claim 1, comprising:

providing a core layer B prepared by consolidating a needled blend of glass fibers and polypropylene fibers at a temperature higher than the melt temperature of the polypropylene and at a pressure such that the consolidated core layer B has an air void content of 20 to 80 volume percent;

providing two GMT layers A, with at least one core layer B between said two GMT layers A to form a consolidatable sandwich structure;

consolidating said sandwich structure at a temperature greater than the melt temperature of the polypropylene and at a pressure not exceeding about 1.0 bar for a time sufficient to thermally consolidate the sandwich structure, and

cooling the consolidated sandwich structure under pressure to form said rigid composite sheet.

9. The method of claim 8, wherein at least one GMT layer A contains at least one fabric reinforcing layer of unidirectional or bidirectional fibers.

10. The method of claim 8, wherein two or more core layers B are present.

11. The method of claim 8, wherein two or more core layers B are present, at least one core layer B having a polypropylene film melt bonded to at least one surface thereof.

12. The method of claim 8, wherein two or more core layers B are present, and each major surface of each core layer B is melt bonded to a polypropylene film, is adjacent to a melt bonded polypropylene film of an abutting core layer B, or is adjacent to a GMT layer A, prior to consolidation, such that a polypropylene-rich interface will be formed at the major surfaces of core layers B upon consolidation.

13. A method for producing a composite sheet of claim 8, wherein the layers A and B are pressed together discontinuously in a press at temperatures between 180 and 220°

C. for 5 to 50 min.

14. The method claim 8, wherein the core layer B is composed of several single layers stacked on top of each other, each layer having a thickness of 1 to 10 mm.

15. The method of claim 10 wherein said consolidated sandwich structure is consolidated in a press at a temperature of from 180°

C. to 220°

C. at a pressure of about 1.0 bar or less.

16. The method of claim 15, wherein said consolidated sandwich structure is an A-B-B-A composite sheet.

17. The method of claim 8, wherein the consolidated core layer B no longer contains polypropylene fibers.