Quantum dot white and colored light-emitting devices

• US 20080174233A1
• Filed: 04/13/2007
• Published: 07/24/2008
• Est. Priority Date: 04/01/1998
• Status: Active Grant

• Current Assignee: Lumileds LLC (Apollo Global Management, Inc.), Massachusetts Institute of Technology
• Original Assignee: Lumileds Lighting US LLC (Apollo Global Management, Inc.), Massachusetts Institute of Technology
• Inventors: Bawendi, Moungi G., Jensen, Klavs F., Moon, Ronald L., Miller, Jeffrey N., Heine, Jason
• Granted Patent: US 7,692,373 B2
• Time in Patent Office: Days
• US Class Current: 313/498
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/565 with zinc cadmium
• CPC Class Codes: C09K 11/883 with zinc or cadmium
• CPC Class Codes: H01L 33/06 within the light emitting region, e.g. quantum confinement structure or tunnel barrier
• CPC Class Codes: H01L 33/502 Wavelength conversion materials
• CPC Class Codes: H01L 33/504 Elements with two or more wavelength conversion materials
• CPC Class Codes: H01S 3/169 Nanoparticles, e.g. doped nanoparticles acting as a gain material
• CPC Class Codes: Y02B 20/00 Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
• CPC Class Codes: Y10S 977/95 Electromagnetic energy

Abstract

A light-emitting device comprising a population of quantum dots (QDs) embedded in a host matrix and a primary light source which causes the QDs to emit secondary light and a method of making such a device. The size distribution of the QDs is chosen to allow light of a particular color to be emitted therefrom. The light emitted from the device may be of either a pure (monochromatic) color, or a mixed (polychromatic) color, and may consist solely of light emitted from the QDs themselves, or of a mixture of light emitted from the QDs and light emitted from the primary source. The QDs desirably are composed of an undoped semiconductor such as CdSe, and may optionally be overcoated to increase photoluminescence.

Claims

1-13. -13. (canceled)

14. A white light emitting device comprising:

a blue primary light source;

a first layer in optical communication with the blue primary light source and comprising quantum dots of a material and size adapted to emit red secondary light; and

a second layer in optical communication with said first layer and said primary light source and comprising quantum dots of a material and size adapted to emit green secondary light.

15. The white light emitting device of claim 14, wherein the quantum dots in the first and second layers each comprise a core and one or more shell layers disposed about the core.

16. The white light emitting device of claim 15, wherein the core comprises a material independently selected from the group comprising CdS, CdSe, CdTe, InP, alloys thereof, and mixtures thereof.

17. The white light emitting device of claim 16, wherein the one or more shell layers comprises a material independently selected from the group comprising ZnS, ZnSe, ZnTe, allows thereof, and mixtures thereof.

18. The white light emitting device of claim 14, wherein the first and second layers both comprise a polymer in which the quantum dots are dispersed.

19. The white light emitting device of claim 15, wherein the quantum dots in the first layer have a size distribution having less than 10% rms deviation in diameter of the core.

20. The white light emitting device of claim 15, wherein the quantum dots in the second layer have a size distribution having less than 10% rms deviation in diameter of the core.

21. The white light emitting device of claim 14, wherein the blue light source comprises a blue LED.

22. The white light emitting device of claim 21, wherein the blue LED comprises AlGaInN.

23. The white light emitting device of claim 14, wherein the quantum dots in both the first and second layers are dispersed in a host matrix selected from the group comprising a liquid, a polymer, an epoxy, a silica, a glass, a silica gel, and combinations thereof.

24. The white light emitting device of claim 23, wherein the quantum dots in both the first and second layers are coated with a material having an affinity for the host matrix.

25. The white light emitting device of claim 14, wherein said second layer is located adjacent to said first layer.

26. The white light emitting device of claim 14, wherein said first layer is located closer to said primary light source than said second layer.

27. A white light emitting device comprising:

a blue primary light source; and

at least a first layer in optical communication with the blue primary light source and comprising a matrix including at least a first population of quantum dots of a material and size adapted to emit red secondary light and a second population of quantum dots of a material and size adapted to emit green secondary light.

28. The white light emitting device of claim 27, wherein the quantum dots in the first and second populations each comprise a core and one or more shell layers disposed about the core.

29. The white light emitting device of claim 28, wherein the core comprises a material independently selected from the group comprising CdS, CdSe, CdTe, InP, alloys thereof, and mixtures thereof.

30. The white light emitting device of claim 29, wherein the one or more shell layers comprises a material independently selected from the group comprising ZnS, ZnSe, ZnTe, alloys thereof, and mixtures thereof.

31. The white light emitting device of claim 27, wherein the matrix comprises a polymer.

32. The white light emitting device of claim 28, wherein the quantum dots in the first population have a size distribution having less than 10% rms deviation in diameter of the core.

33. The white light emitting device of claim 28, wherein the quantum dots of the second population have a size distribution having less than 10% rms deviation in diameter of the core.

34. The white light emitting device of claim 27, wherein the blue light source comprises a blue LED.

35. The white light emitting device of claim 34, wherein the blue LED comprises AlGaInN.

36. The white light emitting device of claim 27, wherein the matrix is selected from the group comprising a liquid, a polymer, an epoxy, a silica, a glass, a silica gel, and combinations thereof.

37. The white light emitting device of claim 36, wherein the quantum dots in both the first and second populations are coated with a material having an affinity for the matrix.